CBe2H5−: Unprecedented 2σ/2π Double Aromaticity and Dynamic Structural Fluxionality in a Planar Tetracoordinate Carbon Cluster

A 14‐electron ternary anionic CBe2H5− cluster containing a planar tetracoordinate carbon (ptC) atom is designed herein. Remarkably, it can be stabilized by only two beryllium atoms with both π‐acceptor/σ‐donor properties and two hydrogen atoms, which means that the conversion from planar methane (tr...

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Veröffentlicht in:	Chemistry : a European journal 2024-03, Vol.30 (15), p.n/a
Hauptverfasser:	Jin, Bo, Yan, Miao, Feng, Lin‐Yan, Miao, Chang‐Qing, Wang, Ying‐Jin
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromaticity Beryllium Carbon Clusters Covalent bonds Dynamic Fluxionality Electronic structure Global Minimum Hydrogen atoms Ligands Molecular motors Molecular Rotor Planar Tetracoordinate Carbon Structural analysis
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