[2 + 2] cycloaddition and its photomechanical effects on 1D coordination polymers with reversible amide bonds and coordination site regulation
Photo-responsive materials can convert light energy into mechanical energy, with great application potential in biomedicine, flexible electronic devices, and bionic systems. We combined reversible amide bonds, coordination site regulation, and coordination polymer (CP) self-assembly to synthesize tw...
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| Veröffentlicht in: | Chemical science (Cambridge) 2024-03, Vol.15 (11), p.3971-3979 |
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| creator | Wang, Lei Qiao, Si-Bo Chen, Yan-Ting Ma, Xun Wei, Wei-Ming Zhang, Jun Du, Lin Zhao, Qi-Hua |
| description | Photo-responsive materials can convert light energy into mechanical energy, with great application potential in biomedicine, flexible electronic devices, and bionic systems. We combined reversible amide bonds, coordination site regulation, and coordination polymer (CP) self-assembly to synthesize two 1D photo-responsive CPs. Obvious photomechanical behavior was observed under UV irradiation. By combining the CPs with PVA, the mechanical stresses were amplified and macroscopic driving behavior was realized. In addition, two cyclobutane amide derivatives and a pair of cyclobutane carboxyl isomers were isolated through coordination bond destruction and amide bond hydrolysis. Therefore, photo-actuators and supramolecular synthesis in smart materials may serve as important clues.
Photo-responsive materials can convert light energy into mechanical energy, with great application potential in biomedicine, flexible electronic devices, and bionic systems. |
| doi_str_mv | 10.1039/d3sc06098e |
| format | Article |
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Photo-responsive materials can convert light energy into mechanical energy, with great application potential in biomedicine, flexible electronic devices, and bionic systems.</description><subject>Actuators</subject><subject>Bionics</subject><subject>Chemistry</subject><subject>Coordination polymers</subject><subject>Cycloaddition</subject><subject>Cyclobutane</subject><subject>Self-assembly</subject><subject>Smart materials</subject><subject>Ultraviolet radiation</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdksFvFCEUxonR2Kb24l1D4sXYrAJvhmFOxmxbNWniQT0ZM2HgTZeGgRVmavaf8G-W3a2rlQsP3u99-cgHIU85e80ZtG8sZMMkaxU-IMeCVXwha2gfHmrBjshpzjesLABei-YxOQJVqUYAOya_vgl6RsV3ajbGR22tm1wMVAdL3ZTpehWnOKJZ6eCM9hSHAU25Lwg_pybGZF3Qu5F19JsRU6Y_3bSiCW9L7XqPVI_OIu1jsHmne28quwkLfD373fkJeTRon_H0bj8hXy8vviw_LK4-vf-4fHe1MKDUtEBUla4Y6zU0_aBrCRXTXLGqttIUjxIl40r0httamgGE0bKVpmES-mbQCCfk7V53PfcjWoNhStp36-RGnTZd1K673wlu1V3H246zFupG1EXh5Z1Cij9mzFM3umzQex0wzrkTba1Ey0Bt0Rf_oTdxTqG8b0tJ1lQAbaFe7SmTYs4Jh4Mbzrpt1N05fF7uor4o8PN__R_QP8EW4NkeSNkcun__CvwGZrGwrg</recordid><startdate>20240313</startdate><enddate>20240313</enddate><creator>Wang, Lei</creator><creator>Qiao, Si-Bo</creator><creator>Chen, Yan-Ting</creator><creator>Ma, Xun</creator><creator>Wei, Wei-Ming</creator><creator>Zhang, Jun</creator><creator>Du, Lin</creator><creator>Zhao, Qi-Hua</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-8165-1793</orcidid><orcidid>https://orcid.org/0000-0003-3525-3182</orcidid></search><sort><creationdate>20240313</creationdate><title>[2 + 2] cycloaddition and its photomechanical effects on 1D coordination polymers with reversible amide bonds and coordination site regulation</title><author>Wang, Lei ; Qiao, Si-Bo ; Chen, Yan-Ting ; Ma, Xun ; Wei, Wei-Ming ; Zhang, Jun ; Du, Lin ; Zhao, Qi-Hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c388t-ee84a400ba37bfa56340a18045d6ceff6e60182bc1d56cf32ca696c7063b7fae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Actuators</topic><topic>Bionics</topic><topic>Chemistry</topic><topic>Coordination polymers</topic><topic>Cycloaddition</topic><topic>Cyclobutane</topic><topic>Self-assembly</topic><topic>Smart materials</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Lei</creatorcontrib><creatorcontrib>Qiao, Si-Bo</creatorcontrib><creatorcontrib>Chen, Yan-Ting</creatorcontrib><creatorcontrib>Ma, Xun</creatorcontrib><creatorcontrib>Wei, Wei-Ming</creatorcontrib><creatorcontrib>Zhang, Jun</creatorcontrib><creatorcontrib>Du, Lin</creatorcontrib><creatorcontrib>Zhao, Qi-Hua</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Lei</au><au>Qiao, Si-Bo</au><au>Chen, Yan-Ting</au><au>Ma, Xun</au><au>Wei, Wei-Ming</au><au>Zhang, Jun</au><au>Du, Lin</au><au>Zhao, Qi-Hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[2 + 2] cycloaddition and its photomechanical effects on 1D coordination polymers with reversible amide bonds and coordination site regulation</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2024-03-13</date><risdate>2024</risdate><volume>15</volume><issue>11</issue><spage>3971</spage><epage>3979</epage><pages>3971-3979</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Photo-responsive materials can convert light energy into mechanical energy, with great application potential in biomedicine, flexible electronic devices, and bionic systems. We combined reversible amide bonds, coordination site regulation, and coordination polymer (CP) self-assembly to synthesize two 1D photo-responsive CPs. Obvious photomechanical behavior was observed under UV irradiation. By combining the CPs with PVA, the mechanical stresses were amplified and macroscopic driving behavior was realized. In addition, two cyclobutane amide derivatives and a pair of cyclobutane carboxyl isomers were isolated through coordination bond destruction and amide bond hydrolysis. Therefore, photo-actuators and supramolecular synthesis in smart materials may serve as important clues.
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| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Actuators Bionics Chemistry Coordination polymers Cycloaddition Cyclobutane Self-assembly Smart materials Ultraviolet radiation |
| title | [2 + 2] cycloaddition and its photomechanical effects on 1D coordination polymers with reversible amide bonds and coordination site regulation |
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