FeZrN Films with Nanocomposite Structure for Soft Magnetic Applications
The Fe 56.8–72.5 Zr 5.9–11.6 N 13.8–31.6 O 1.2–3.4 films were prepared by magnetron deposition. The metastable structural and phase state, which was formed upon deposition, is represented by either mixed (nanocrystalline αFe(Zr,N) + amorphous) or amorphous structure. During subsequent annealing (300...
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| Veröffentlicht in: | Physics of metals and metallography 2023-12, Vol.124 (14), p.1645-1653 |
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| container_title | Physics of metals and metallography |
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| creator | Sheftel, E. N. Harin, E. V. Tedzhetov, V. A. Usmanova, G. Sh |
| description | The Fe
56.8–72.5
Zr
5.9–11.6
N
13.8–31.6
O
1.2–3.4
films were prepared by magnetron deposition. The metastable structural and phase state, which was formed upon deposition, is represented by either mixed (nanocrystalline αFe(Zr,N) + amorphous) or amorphous structure. During subsequent annealing (300–600°C), it slightly shifts toward the stable state due to partial crystallization of the amorphous phase and precipitation of the secondary phases (Fe
4
N, Fe
3
N, and ZrO
2
). The grain structure of the films (grains 3–12 nm in size) is characterized by thermal stability. The relatively low saturation magnetization
M
s
(870–1400 G) of the films is explained by the presence of the amorphous phase and αFe(Zr,N) solid solution, which remain in the film structure after annealing at all temperatures. The stochastic domain structure is formed in all films under study due to exchange interaction between grains and clusters in the amorphous structure. The strong dependence of the magnetic structure on the phase state and grain structure of the films is demonstrated. The combination of low local magnetic anisotropy and the highest stochastic domain size predetermines the lowest coercive field of the films, which varies in a range of 1 to 50 Oe. |
| doi_str_mv | 10.1134/S0031918X23601336 |
| format | Article |
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56.8–72.5
Zr
5.9–11.6
N
13.8–31.6
O
1.2–3.4
films were prepared by magnetron deposition. The metastable structural and phase state, which was formed upon deposition, is represented by either mixed (nanocrystalline αFe(Zr,N) + amorphous) or amorphous structure. During subsequent annealing (300–600°C), it slightly shifts toward the stable state due to partial crystallization of the amorphous phase and precipitation of the secondary phases (Fe
4
N, Fe
3
N, and ZrO
2
). The grain structure of the films (grains 3–12 nm in size) is characterized by thermal stability. The relatively low saturation magnetization
M
s
(870–1400 G) of the films is explained by the presence of the amorphous phase and αFe(Zr,N) solid solution, which remain in the film structure after annealing at all temperatures. The stochastic domain structure is formed in all films under study due to exchange interaction between grains and clusters in the amorphous structure. The strong dependence of the magnetic structure on the phase state and grain structure of the films is demonstrated. The combination of low local magnetic anisotropy and the highest stochastic domain size predetermines the lowest coercive field of the films, which varies in a range of 1 to 50 Oe.</description><identifier>ISSN: 0031-918X</identifier><identifier>EISSN: 1555-6190</identifier><identifier>DOI: 10.1134/S0031918X23601336</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Amorphous structure ; Anisotropy ; Annealing ; Chemistry and Materials Science ; Coercivity ; Crystallization ; Deposition ; Electrical and Magnetic Properties ; Grain structure ; Iron nitride ; Magnetic anisotropy ; Magnetic saturation ; Magnetic structure ; Magnetization ; Materials Science ; Metallic glasses ; Metallic Materials ; Nanocomposites ; Solid solutions ; Thermal stability ; Zirconium dioxide</subject><ispartof>Physics of metals and metallography, 2023-12, Vol.124 (14), p.1645-1653</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0031-918X, Physics of Metals and Metallography, 2023, Vol. 124, No. 14, pp. 1645–1653. © Pleiades Publishing, Ltd., 2023. ISSN 0031-918X, Physics of Metals and Metallography, 2023. © Pleiades Publishing, Ltd., 2023.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c307t-390fa3f0545de8c297e6b43bf5d22b2181d4d7c7f413cd92fbe38d09049274273</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0031918X23601336$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0031918X23601336$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sheftel, E. N.</creatorcontrib><creatorcontrib>Harin, E. V.</creatorcontrib><creatorcontrib>Tedzhetov, V. A.</creatorcontrib><creatorcontrib>Usmanova, G. Sh</creatorcontrib><title>FeZrN Films with Nanocomposite Structure for Soft Magnetic Applications</title><title>Physics of metals and metallography</title><addtitle>Phys. Metals Metallogr</addtitle><description>The Fe
56.8–72.5
Zr
5.9–11.6
N
13.8–31.6
O
1.2–3.4
films were prepared by magnetron deposition. The metastable structural and phase state, which was formed upon deposition, is represented by either mixed (nanocrystalline αFe(Zr,N) + amorphous) or amorphous structure. During subsequent annealing (300–600°C), it slightly shifts toward the stable state due to partial crystallization of the amorphous phase and precipitation of the secondary phases (Fe
4
N, Fe
3
N, and ZrO
2
). The grain structure of the films (grains 3–12 nm in size) is characterized by thermal stability. The relatively low saturation magnetization
M
s
(870–1400 G) of the films is explained by the presence of the amorphous phase and αFe(Zr,N) solid solution, which remain in the film structure after annealing at all temperatures. The stochastic domain structure is formed in all films under study due to exchange interaction between grains and clusters in the amorphous structure. The strong dependence of the magnetic structure on the phase state and grain structure of the films is demonstrated. The combination of low local magnetic anisotropy and the highest stochastic domain size predetermines the lowest coercive field of the films, which varies in a range of 1 to 50 Oe.</description><subject>Amorphous structure</subject><subject>Anisotropy</subject><subject>Annealing</subject><subject>Chemistry and Materials Science</subject><subject>Coercivity</subject><subject>Crystallization</subject><subject>Deposition</subject><subject>Electrical and Magnetic Properties</subject><subject>Grain structure</subject><subject>Iron nitride</subject><subject>Magnetic anisotropy</subject><subject>Magnetic saturation</subject><subject>Magnetic structure</subject><subject>Magnetization</subject><subject>Materials Science</subject><subject>Metallic glasses</subject><subject>Metallic Materials</subject><subject>Nanocomposites</subject><subject>Solid solutions</subject><subject>Thermal stability</subject><subject>Zirconium dioxide</subject><issn>0031-918X</issn><issn>1555-6190</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LxDAQxYMouK5-AG8Bz13zr01zXBZ3Fdb1UAXxUtI0WbO0TU1SxG9vlwoeROYwMO_9ZoYHwDVGC4wpuy0Qoljg_JXQDGFKsxMww2maJhkW6BTMjnJy1M_BRQgHhBhjGZ2BzVq_-R1c26YN8NPGd7iTnVOu7V2wUcMi-kHFwWtonIeFMxE-yn2no1Vw2feNVTJa14VLcGZkE_TVT5-Dl_Xd8-o-2T5tHlbLbaIo4jGhAhlJDUpZWutcEcF1VjFambQmpCI4xzWrueKGYapqQUylaV4jgZggnBFO5-Bm2tt79zHoEMuDG3w3niyJoDzHCAs6uhaTay8bXdrOuOilGqvWrVWu08aO8yXPU8ZyIsgI4AlQ3oXgtSl7b1vpv0qMymPA5Z-AR4ZMTBi93V7731f-h74BBKl7nw</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Sheftel, E. N.</creator><creator>Harin, E. V.</creator><creator>Tedzhetov, V. A.</creator><creator>Usmanova, G. Sh</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20231201</creationdate><title>FeZrN Films with Nanocomposite Structure for Soft Magnetic Applications</title><author>Sheftel, E. N. ; Harin, E. V. ; Tedzhetov, V. A. ; Usmanova, G. Sh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c307t-390fa3f0545de8c297e6b43bf5d22b2181d4d7c7f413cd92fbe38d09049274273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Amorphous structure</topic><topic>Anisotropy</topic><topic>Annealing</topic><topic>Chemistry and Materials Science</topic><topic>Coercivity</topic><topic>Crystallization</topic><topic>Deposition</topic><topic>Electrical and Magnetic Properties</topic><topic>Grain structure</topic><topic>Iron nitride</topic><topic>Magnetic anisotropy</topic><topic>Magnetic saturation</topic><topic>Magnetic structure</topic><topic>Magnetization</topic><topic>Materials Science</topic><topic>Metallic glasses</topic><topic>Metallic Materials</topic><topic>Nanocomposites</topic><topic>Solid solutions</topic><topic>Thermal stability</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sheftel, E. N.</creatorcontrib><creatorcontrib>Harin, E. V.</creatorcontrib><creatorcontrib>Tedzhetov, V. A.</creatorcontrib><creatorcontrib>Usmanova, G. Sh</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Physics of metals and metallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sheftel, E. N.</au><au>Harin, E. V.</au><au>Tedzhetov, V. A.</au><au>Usmanova, G. Sh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>FeZrN Films with Nanocomposite Structure for Soft Magnetic Applications</atitle><jtitle>Physics of metals and metallography</jtitle><stitle>Phys. Metals Metallogr</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>124</volume><issue>14</issue><spage>1645</spage><epage>1653</epage><pages>1645-1653</pages><issn>0031-918X</issn><eissn>1555-6190</eissn><abstract>The Fe
56.8–72.5
Zr
5.9–11.6
N
13.8–31.6
O
1.2–3.4
films were prepared by magnetron deposition. The metastable structural and phase state, which was formed upon deposition, is represented by either mixed (nanocrystalline αFe(Zr,N) + amorphous) or amorphous structure. During subsequent annealing (300–600°C), it slightly shifts toward the stable state due to partial crystallization of the amorphous phase and precipitation of the secondary phases (Fe
4
N, Fe
3
N, and ZrO
2
). The grain structure of the films (grains 3–12 nm in size) is characterized by thermal stability. The relatively low saturation magnetization
M
s
(870–1400 G) of the films is explained by the presence of the amorphous phase and αFe(Zr,N) solid solution, which remain in the film structure after annealing at all temperatures. The stochastic domain structure is formed in all films under study due to exchange interaction between grains and clusters in the amorphous structure. The strong dependence of the magnetic structure on the phase state and grain structure of the films is demonstrated. The combination of low local magnetic anisotropy and the highest stochastic domain size predetermines the lowest coercive field of the films, which varies in a range of 1 to 50 Oe.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0031918X23601336</doi><tpages>9</tpages></addata></record> |
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| ispartof | Physics of metals and metallography, 2023-12, Vol.124 (14), p.1645-1653 |
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| language | eng |
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| source | SpringerLink Journals |
| subjects | Amorphous structure Anisotropy Annealing Chemistry and Materials Science Coercivity Crystallization Deposition Electrical and Magnetic Properties Grain structure Iron nitride Magnetic anisotropy Magnetic saturation Magnetic structure Magnetization Materials Science Metallic glasses Metallic Materials Nanocomposites Solid solutions Thermal stability Zirconium dioxide |
| title | FeZrN Films with Nanocomposite Structure for Soft Magnetic Applications |
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