The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases
Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm 3 S 4 and Sm 2 O 2 S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm 2 S 3-X -SmS-Sm 2 O 2 S system is a scientifically interesting task. In this system, 49 samples were synthe...
Gespeichert in:
| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2024-03, Vol.149 (5), p.2057-2073 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2073 |
|---|---|
| container_issue | 5 |
| container_start_page | 2057 |
| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 149 |
| creator | Yurev, Ilya Olegovich Aleksandrovsky, Aleksandr Sergeevich Kamaev, Dmitriy Nikolaevich Polkovnikov, Aleksei Aleksandrovich Grigorchenko, Viktoriya Maksimovna Yarovenko, Aleksandr Aleksandrovich Zelenaya, Anna Eduardovna Parfenova, Mariya Dmitriyevna Andreev, Oleg Valeryevich |
| description | Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm
3
S
4
and Sm
2
O
2
S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm
2
S
3-X
-SmS-Sm
2
O
2
S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm
3
S
4
, SmS, and Sm
2
O
2
S compounds were determined. Eutectic diagrams of Sm
3
S
4
-Sm
2
O
2
S, SmS-Sm
2
O
2
S, SmS-Sm
3
S
4
systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm
3
S
4
, SmS, and Sm
2
O
2
S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm
3
S
4
-SmS-Sm
2
O
2
S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm
2
S
3
→ γ-Sm
2
S
3
polymorphic transition and the dependence of the Sm
2
S
3-X
composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm
2
S
3
sample is Sm
2
S
2.95
. The Sm
10
S
14
O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm
2
S
3-X
-Sm
2
O
2
S system was revisited. Optical band gaps of Sm
10
S
14
O and Sm
2
O
2
S phases were determined. The Sm
10
S
14
O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm
2
O
2
S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures. |
| doi_str_mv | 10.1007/s10973-023-12792-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2937356173</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2937356173</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-c39940893aa2faa66461861b9e5941e48067632fb5311d63819c9fbb9c0e63d13</originalsourceid><addsrcrecordid>eNp9UMtOwzAQtBBIlMIPcLLEtQavnTgxN1Txkir1kCJxs5zEaVM1TfCmh_TrcQkSNw77kHZmNDuE3AK_B86TBwSuE8m4kAxEogU7npEJxGnKhBbqPOwy7ApifkmuELecc605TMh6tXE0a0Qm2SfLmiyUWIqMeld5W_StHygO2LvmkfYb5xu7o3ZvdwPWOKPdxqKjZW3X3jazcChp59vO-b52SNvqRBlBeE0uKrtDd_M7p-Tj5Xk1f2OL5ev7_GnBCgm6D13riKdaWisqa5WKFKQKcu1iHYGLUq4SJUWVxxKgVDIFXegqz3XBnZIlyCm5G3WDka-Dw95s24MPjtEILRMZK0hkQIkRVfgWMfxqOl831g8GuDkFasZATQjU_ARqjoEkRxIG8H7t_J_0P6xvG-l3rg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2937356173</pqid></control><display><type>article</type><title>The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases</title><source>SpringerLink Journals</source><creator>Yurev, Ilya Olegovich ; Aleksandrovsky, Aleksandr Sergeevich ; Kamaev, Dmitriy Nikolaevich ; Polkovnikov, Aleksei Aleksandrovich ; Grigorchenko, Viktoriya Maksimovna ; Yarovenko, Aleksandr Aleksandrovich ; Zelenaya, Anna Eduardovna ; Parfenova, Mariya Dmitriyevna ; Andreev, Oleg Valeryevich</creator><creatorcontrib>Yurev, Ilya Olegovich ; Aleksandrovsky, Aleksandr Sergeevich ; Kamaev, Dmitriy Nikolaevich ; Polkovnikov, Aleksei Aleksandrovich ; Grigorchenko, Viktoriya Maksimovna ; Yarovenko, Aleksandr Aleksandrovich ; Zelenaya, Anna Eduardovna ; Parfenova, Mariya Dmitriyevna ; Andreev, Oleg Valeryevich</creatorcontrib><description>Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm
3
S
4
and Sm
2
O
2
S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm
2
S
3-X
-SmS-Sm
2
O
2
S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm
3
S
4
, SmS, and Sm
2
O
2
S compounds were determined. Eutectic diagrams of Sm
3
S
4
-Sm
2
O
2
S, SmS-Sm
2
O
2
S, SmS-Sm
3
S
4
systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm
3
S
4
, SmS, and Sm
2
O
2
S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm
3
S
4
-SmS-Sm
2
O
2
S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm
2
S
3
→ γ-Sm
2
S
3
polymorphic transition and the dependence of the Sm
2
S
3-X
composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm
2
S
3
sample is Sm
2
S
2.95
. The Sm
10
S
14
O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm
2
S
3-X
-Sm
2
O
2
S system was revisited. Optical band gaps of Sm
10
S
14
O and Sm
2
O
2
S phases were determined. The Sm
10
S
14
O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm
2
O
2
S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-023-12792-z</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Crystallization ; Energy gap ; Enthalpy ; Eutectic composition ; Eutectic temperature ; Heat treatment ; Inorganic Chemistry ; Liquidus ; Measurement Science and Instrumentation ; Melting points ; Microstructural analysis ; Microstructure ; Phase diagrams ; Phase equilibria ; Physical Chemistry ; Polymer Sciences ; Polynomials ; Samarium ; Solid phases ; Strain gauges ; Thermal analysis</subject><ispartof>Journal of thermal analysis and calorimetry, 2024-03, Vol.149 (5), p.2057-2073</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-c39940893aa2faa66461861b9e5941e48067632fb5311d63819c9fbb9c0e63d13</citedby><cites>FETCH-LOGICAL-c319t-c39940893aa2faa66461861b9e5941e48067632fb5311d63819c9fbb9c0e63d13</cites><orcidid>0000-0002-3030-2259</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-023-12792-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-023-12792-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Yurev, Ilya Olegovich</creatorcontrib><creatorcontrib>Aleksandrovsky, Aleksandr Sergeevich</creatorcontrib><creatorcontrib>Kamaev, Dmitriy Nikolaevich</creatorcontrib><creatorcontrib>Polkovnikov, Aleksei Aleksandrovich</creatorcontrib><creatorcontrib>Grigorchenko, Viktoriya Maksimovna</creatorcontrib><creatorcontrib>Yarovenko, Aleksandr Aleksandrovich</creatorcontrib><creatorcontrib>Zelenaya, Anna Eduardovna</creatorcontrib><creatorcontrib>Parfenova, Mariya Dmitriyevna</creatorcontrib><creatorcontrib>Andreev, Oleg Valeryevich</creatorcontrib><title>The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm
3
S
4
and Sm
2
O
2
S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm
2
S
3-X
-SmS-Sm
2
O
2
S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm
3
S
4
, SmS, and Sm
2
O
2
S compounds were determined. Eutectic diagrams of Sm
3
S
4
-Sm
2
O
2
S, SmS-Sm
2
O
2
S, SmS-Sm
3
S
4
systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm
3
S
4
, SmS, and Sm
2
O
2
S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm
3
S
4
-SmS-Sm
2
O
2
S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm
2
S
3
→ γ-Sm
2
S
3
polymorphic transition and the dependence of the Sm
2
S
3-X
composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm
2
S
3
sample is Sm
2
S
2.95
. The Sm
10
S
14
O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm
2
S
3-X
-Sm
2
O
2
S system was revisited. Optical band gaps of Sm
10
S
14
O and Sm
2
O
2
S phases were determined. The Sm
10
S
14
O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm
2
O
2
S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallization</subject><subject>Energy gap</subject><subject>Enthalpy</subject><subject>Eutectic composition</subject><subject>Eutectic temperature</subject><subject>Heat treatment</subject><subject>Inorganic Chemistry</subject><subject>Liquidus</subject><subject>Measurement Science and Instrumentation</subject><subject>Melting points</subject><subject>Microstructural analysis</subject><subject>Microstructure</subject><subject>Phase diagrams</subject><subject>Phase equilibria</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polynomials</subject><subject>Samarium</subject><subject>Solid phases</subject><subject>Strain gauges</subject><subject>Thermal analysis</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQtBBIlMIPcLLEtQavnTgxN1Txkir1kCJxs5zEaVM1TfCmh_TrcQkSNw77kHZmNDuE3AK_B86TBwSuE8m4kAxEogU7npEJxGnKhBbqPOwy7ApifkmuELecc605TMh6tXE0a0Qm2SfLmiyUWIqMeld5W_StHygO2LvmkfYb5xu7o3ZvdwPWOKPdxqKjZW3X3jazcChp59vO-b52SNvqRBlBeE0uKrtDd_M7p-Tj5Xk1f2OL5ev7_GnBCgm6D13riKdaWisqa5WKFKQKcu1iHYGLUq4SJUWVxxKgVDIFXegqz3XBnZIlyCm5G3WDka-Dw95s24MPjtEILRMZK0hkQIkRVfgWMfxqOl831g8GuDkFasZATQjU_ARqjoEkRxIG8H7t_J_0P6xvG-l3rg</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Yurev, Ilya Olegovich</creator><creator>Aleksandrovsky, Aleksandr Sergeevich</creator><creator>Kamaev, Dmitriy Nikolaevich</creator><creator>Polkovnikov, Aleksei Aleksandrovich</creator><creator>Grigorchenko, Viktoriya Maksimovna</creator><creator>Yarovenko, Aleksandr Aleksandrovich</creator><creator>Zelenaya, Anna Eduardovna</creator><creator>Parfenova, Mariya Dmitriyevna</creator><creator>Andreev, Oleg Valeryevich</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-3030-2259</orcidid></search><sort><creationdate>20240301</creationdate><title>The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases</title><author>Yurev, Ilya Olegovich ; Aleksandrovsky, Aleksandr Sergeevich ; Kamaev, Dmitriy Nikolaevich ; Polkovnikov, Aleksei Aleksandrovich ; Grigorchenko, Viktoriya Maksimovna ; Yarovenko, Aleksandr Aleksandrovich ; Zelenaya, Anna Eduardovna ; Parfenova, Mariya Dmitriyevna ; Andreev, Oleg Valeryevich</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-c39940893aa2faa66461861b9e5941e48067632fb5311d63819c9fbb9c0e63d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallization</topic><topic>Energy gap</topic><topic>Enthalpy</topic><topic>Eutectic composition</topic><topic>Eutectic temperature</topic><topic>Heat treatment</topic><topic>Inorganic Chemistry</topic><topic>Liquidus</topic><topic>Measurement Science and Instrumentation</topic><topic>Melting points</topic><topic>Microstructural analysis</topic><topic>Microstructure</topic><topic>Phase diagrams</topic><topic>Phase equilibria</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polynomials</topic><topic>Samarium</topic><topic>Solid phases</topic><topic>Strain gauges</topic><topic>Thermal analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yurev, Ilya Olegovich</creatorcontrib><creatorcontrib>Aleksandrovsky, Aleksandr Sergeevich</creatorcontrib><creatorcontrib>Kamaev, Dmitriy Nikolaevich</creatorcontrib><creatorcontrib>Polkovnikov, Aleksei Aleksandrovich</creatorcontrib><creatorcontrib>Grigorchenko, Viktoriya Maksimovna</creatorcontrib><creatorcontrib>Yarovenko, Aleksandr Aleksandrovich</creatorcontrib><creatorcontrib>Zelenaya, Anna Eduardovna</creatorcontrib><creatorcontrib>Parfenova, Mariya Dmitriyevna</creatorcontrib><creatorcontrib>Andreev, Oleg Valeryevich</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yurev, Ilya Olegovich</au><au>Aleksandrovsky, Aleksandr Sergeevich</au><au>Kamaev, Dmitriy Nikolaevich</au><au>Polkovnikov, Aleksei Aleksandrovich</au><au>Grigorchenko, Viktoriya Maksimovna</au><au>Yarovenko, Aleksandr Aleksandrovich</au><au>Zelenaya, Anna Eduardovna</au><au>Parfenova, Mariya Dmitriyevna</au><au>Andreev, Oleg Valeryevich</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2024-03-01</date><risdate>2024</risdate><volume>149</volume><issue>5</issue><spage>2057</spage><epage>2073</epage><pages>2057-2073</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm
3
S
4
and Sm
2
O
2
S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm
2
S
3-X
-SmS-Sm
2
O
2
S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm
3
S
4
, SmS, and Sm
2
O
2
S compounds were determined. Eutectic diagrams of Sm
3
S
4
-Sm
2
O
2
S, SmS-Sm
2
O
2
S, SmS-Sm
3
S
4
systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm
3
S
4
, SmS, and Sm
2
O
2
S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm
3
S
4
-SmS-Sm
2
O
2
S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm
2
S
3
→ γ-Sm
2
S
3
polymorphic transition and the dependence of the Sm
2
S
3-X
composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm
2
S
3
sample is Sm
2
S
2.95
. The Sm
10
S
14
O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm
2
S
3-X
-Sm
2
O
2
S system was revisited. Optical band gaps of Sm
10
S
14
O and Sm
2
O
2
S phases were determined. The Sm
10
S
14
O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm
2
O
2
S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10973-023-12792-z</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0002-3030-2259</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2024-03, Vol.149 (5), p.2057-2073 |
| issn | 1388-6150 1588-2926 |
| language | eng |
| recordid | cdi_proquest_journals_2937356173 |
| source | SpringerLink Journals |
| subjects | Analytical Chemistry Chemistry Chemistry and Materials Science Crystallization Energy gap Enthalpy Eutectic composition Eutectic temperature Heat treatment Inorganic Chemistry Liquidus Measurement Science and Instrumentation Melting points Microstructural analysis Microstructure Phase diagrams Phase equilibria Physical Chemistry Polymer Sciences Polynomials Samarium Solid phases Strain gauges Thermal analysis |
| title | The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T01%3A54%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20Sm2S3-X-SmS-Sm2O2S%20refractory%20system:%20thermal%20analysis,%20phase%20diagram,%20and%20properties%20of%20the%20phases&rft.jtitle=Journal%20of%20thermal%20analysis%20and%20calorimetry&rft.au=Yurev,%20Ilya%20Olegovich&rft.date=2024-03-01&rft.volume=149&rft.issue=5&rft.spage=2057&rft.epage=2073&rft.pages=2057-2073&rft.issn=1388-6150&rft.eissn=1588-2926&rft_id=info:doi/10.1007/s10973-023-12792-z&rft_dat=%3Cproquest_cross%3E2937356173%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2937356173&rft_id=info:pmid/&rfr_iscdi=true |