Recent advances in multifunctional metal-organic frameworks for lithium metal batteries
In view of novel materials in the field of lithium metal batteries (LMBs), metal-organic frameworks (MOFs) have attracted extensive research interest owing to their controllable pore size, unsaturated metal sites and multifunctional organic groups. A variety of MOFs have been elaborately calculated...
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| Veröffentlicht in: | Science China. Chemistry 2024-03, Vol.67 (3), p.759-773 |
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| container_title | Science China. Chemistry |
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| creator | Li, Jiaqi Weng, Zheng Qin, Zuosu Zhang, Ying Zhang, Ning Liu, Xiaohe Jia, Chuankun Chen, Gen Zhou, Jiang |
| description | In view of novel materials in the field of lithium metal batteries (LMBs), metal-organic frameworks (MOFs) have attracted extensive research interest owing to their controllable pore size, unsaturated metal sites and multifunctional organic groups. A variety of MOFs have been elaborately calculated and synthesized to be applied as separator coating, electrolyte modulators and solid-state electrolyte fillers in LMBs. In this mini-review, we summarize the mechanism of MOFs to limit the migration of anions, improve the Li-ion transference number and prolong the lifespan of LMBs. Suitable pore structure of MOFs can physically restrict the movement of Li
+
. Unsaturated metal sites can adsorb anions by electrostatic interaction. In addition, multifunctional organic functional groups that limit the migration of anions are discussed. Finally, the key challenges and perspectives in the development direction of MOFs-based separators and electrolytes are further elaborated. |
| doi_str_mv | 10.1007/s11426-023-1845-7 |
| format | Article |
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+
. Unsaturated metal sites can adsorb anions by electrostatic interaction. In addition, multifunctional organic functional groups that limit the migration of anions are discussed. Finally, the key challenges and perspectives in the development direction of MOFs-based separators and electrolytes are further elaborated.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-023-1845-7</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Anions ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Controllability ; Electrolytes ; Functional groups ; Ion migration ; Lithium ; Lithium batteries ; Lithium ions ; Materials science ; Metal-organic frameworks ; Mini Reviews ; Modulators ; Pore size ; Separators ; Sulfur</subject><ispartof>Science China. Chemistry, 2024-03, Vol.67 (3), p.759-773</ispartof><rights>Science China Press 2023</rights><rights>Science China Press 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-5677bdf8ee07e28fb44d4e8233a2589dc8445174b7aa0cfa154bc770d780ab53</citedby><cites>FETCH-LOGICAL-c316t-5677bdf8ee07e28fb44d4e8233a2589dc8445174b7aa0cfa154bc770d780ab53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11426-023-1845-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11426-023-1845-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Li, Jiaqi</creatorcontrib><creatorcontrib>Weng, Zheng</creatorcontrib><creatorcontrib>Qin, Zuosu</creatorcontrib><creatorcontrib>Zhang, Ying</creatorcontrib><creatorcontrib>Zhang, Ning</creatorcontrib><creatorcontrib>Liu, Xiaohe</creatorcontrib><creatorcontrib>Jia, Chuankun</creatorcontrib><creatorcontrib>Chen, Gen</creatorcontrib><creatorcontrib>Zhou, Jiang</creatorcontrib><title>Recent advances in multifunctional metal-organic frameworks for lithium metal batteries</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><description>In view of novel materials in the field of lithium metal batteries (LMBs), metal-organic frameworks (MOFs) have attracted extensive research interest owing to their controllable pore size, unsaturated metal sites and multifunctional organic groups. A variety of MOFs have been elaborately calculated and synthesized to be applied as separator coating, electrolyte modulators and solid-state electrolyte fillers in LMBs. In this mini-review, we summarize the mechanism of MOFs to limit the migration of anions, improve the Li-ion transference number and prolong the lifespan of LMBs. Suitable pore structure of MOFs can physically restrict the movement of Li
+
. Unsaturated metal sites can adsorb anions by electrostatic interaction. In addition, multifunctional organic functional groups that limit the migration of anions are discussed. Finally, the key challenges and perspectives in the development direction of MOFs-based separators and electrolytes are further elaborated.</description><subject>Anions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Controllability</subject><subject>Electrolytes</subject><subject>Functional groups</subject><subject>Ion migration</subject><subject>Lithium</subject><subject>Lithium batteries</subject><subject>Lithium ions</subject><subject>Materials science</subject><subject>Metal-organic frameworks</subject><subject>Mini Reviews</subject><subject>Modulators</subject><subject>Pore size</subject><subject>Separators</subject><subject>Sulfur</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kFtLAzEQhYMoWGp_gG8Bn1dz253soxRvUBCk4GPIZpOaupeaZBX_vSkr-OS8zAycc5j5ELqk5JoSAjeRUsGqgjBeUCnKAk7QgsqqzhuQ0zxXIApgNT1Hqxj3JBfnhEG5QK8v1tghYd1-6sHYiP2A-6lL3k2DSX4cdId7m3RXjGGnB2-wC7q3X2N4j9iNAXc-vfmpn0W40SnZ4G28QGdOd9GufvsSbe_vtuvHYvP88LS-3RSG0yoVZQXQtE5aS8Ay6RohWmEl41yzUtatkUKUFEQDWhPjNC1FYwBIC5LopuRLdDXHHsL4MdmY1H6cQj46KlZzoPL4elbRWWXCGGOwTh2C73X4VpSoI0E1E1SZoDoSVJA9bPbErB12Nvwl_2_6ATfHdE8</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Li, Jiaqi</creator><creator>Weng, Zheng</creator><creator>Qin, Zuosu</creator><creator>Zhang, Ying</creator><creator>Zhang, Ning</creator><creator>Liu, Xiaohe</creator><creator>Jia, Chuankun</creator><creator>Chen, Gen</creator><creator>Zhou, Jiang</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240301</creationdate><title>Recent advances in multifunctional metal-organic frameworks for lithium metal batteries</title><author>Li, Jiaqi ; Weng, Zheng ; Qin, Zuosu ; Zhang, Ying ; Zhang, Ning ; Liu, Xiaohe ; Jia, Chuankun ; Chen, Gen ; Zhou, Jiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-5677bdf8ee07e28fb44d4e8233a2589dc8445174b7aa0cfa154bc770d780ab53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Anions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Controllability</topic><topic>Electrolytes</topic><topic>Functional groups</topic><topic>Ion migration</topic><topic>Lithium</topic><topic>Lithium batteries</topic><topic>Lithium ions</topic><topic>Materials science</topic><topic>Metal-organic frameworks</topic><topic>Mini Reviews</topic><topic>Modulators</topic><topic>Pore size</topic><topic>Separators</topic><topic>Sulfur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Jiaqi</creatorcontrib><creatorcontrib>Weng, Zheng</creatorcontrib><creatorcontrib>Qin, Zuosu</creatorcontrib><creatorcontrib>Zhang, Ying</creatorcontrib><creatorcontrib>Zhang, Ning</creatorcontrib><creatorcontrib>Liu, Xiaohe</creatorcontrib><creatorcontrib>Jia, Chuankun</creatorcontrib><creatorcontrib>Chen, Gen</creatorcontrib><creatorcontrib>Zhou, Jiang</creatorcontrib><collection>CrossRef</collection><jtitle>Science China. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Jiaqi</au><au>Weng, Zheng</au><au>Qin, Zuosu</au><au>Zhang, Ying</au><au>Zhang, Ning</au><au>Liu, Xiaohe</au><au>Jia, Chuankun</au><au>Chen, Gen</au><au>Zhou, Jiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent advances in multifunctional metal-organic frameworks for lithium metal batteries</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><date>2024-03-01</date><risdate>2024</risdate><volume>67</volume><issue>3</issue><spage>759</spage><epage>773</epage><pages>759-773</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>In view of novel materials in the field of lithium metal batteries (LMBs), metal-organic frameworks (MOFs) have attracted extensive research interest owing to their controllable pore size, unsaturated metal sites and multifunctional organic groups. A variety of MOFs have been elaborately calculated and synthesized to be applied as separator coating, electrolyte modulators and solid-state electrolyte fillers in LMBs. In this mini-review, we summarize the mechanism of MOFs to limit the migration of anions, improve the Li-ion transference number and prolong the lifespan of LMBs. Suitable pore structure of MOFs can physically restrict the movement of Li
+
. Unsaturated metal sites can adsorb anions by electrostatic interaction. In addition, multifunctional organic functional groups that limit the migration of anions are discussed. Finally, the key challenges and perspectives in the development direction of MOFs-based separators and electrolytes are further elaborated.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-023-1845-7</doi><tpages>15</tpages></addata></record> |
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| subjects | Anions Chemistry Chemistry and Materials Science Chemistry/Food Science Controllability Electrolytes Functional groups Ion migration Lithium Lithium batteries Lithium ions Materials science Metal-organic frameworks Mini Reviews Modulators Pore size Separators Sulfur |
| title | Recent advances in multifunctional metal-organic frameworks for lithium metal batteries |
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