Electrochemistry and band structure of semiconductors (TiO2, SnO2, ZnO): Avoiding pitfalls and textbook errors
This paper reviews selected problems, which appear in literature dealing with TiO 2 , SnO 2 , and ZnO. Some of them have more universal impact to semiconductor electrochemistry. The electronic band structure is a key for understanding fundamental properties and for rational design of applications, b...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2024-03, Vol.28 (3-4), p.829-845 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Kavan, Ladislav |
| description | This paper reviews selected problems, which appear in literature dealing with TiO
2
, SnO
2
, and ZnO. Some of them have more universal impact to semiconductor electrochemistry. The electronic band structure is a key for understanding fundamental properties and for rational design of applications, but the uncertainty of specific values determined experimentally or by theoretical calculations should not be ignored. The inappropriate use of Mott-Schottky plot for characterization of certain semiconductor electrodes is another source of problems. Some other technical and formal issues in research and development of semiconductors are discussed. |
| doi_str_mv | 10.1007/s10008-023-05770-w |
| format | Article |
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| subjects | Analytical Chemistry Band structure of solids Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Energy Storage Physical Chemistry R&D Research & development Review Paper Tin dioxide Titanium dioxide Zinc oxide |
| title | Electrochemistry and band structure of semiconductors (TiO2, SnO2, ZnO): Avoiding pitfalls and textbook errors |
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