An Isolable Phosphinogermylyne as a Synthon of One‐Coordinate GeI Radical

Comprehensive Summary Reduction of chlorogermylene MsFluindtBu‐GeCl 1 with potassium graphite (KC8) afforded putative germylyne radical MsFluindtBu‐Ge 2 as confirmed by electron paramagnetic resonance (EPR) spectroscopy. However, it slowly decayed via C—H bond activation at the fluorenyl moiety to y...

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Veröffentlicht in:	Chinese journal of chemistry 2024-04, Vol.42 (7), p.736-742
Hauptverfasser:	Wang, Dongmin, Chen, Haonan, He, Yuhao, Chen, Xiaodan, Zhang, Li, Tan, Gengwen
Format:	Artikel
Sprache:	eng
Schlagworte:	Donor‐acceptor systems Electron paramagnetic resonance Electron spin resonance Germanium Hydrogen bonds Lewis base Phosphinogermylyne Potassium Radical reactions Radicals Room temperature Spectroscopy
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