Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol
Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant cha...
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| Veröffentlicht in: | Carbon Letters 2022-08, Vol.32 (5), p.1277-1285 |
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| creator | Yang, Man Chen, Yiyang Wang, Haitao Zou, Yilun Wu, Pingxiu Zou, Jing Jiang, Jizhou |
| description | Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant challenge. Herein, a convenient and sensitive electrochemical sensor is constructed by modifying glassy carbon electrode with cerium dioxide (CeO
2
) nanoparticles anchored graphene (CeO
2
-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO
2
nanoparticles and graphene, the afforded CeO
2
-GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO
2
–GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO
2
–GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials. |
| doi_str_mv | 10.1007/s42823-022-00353-7 |
| format | Article |
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2
) nanoparticles anchored graphene (CeO
2
-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO
2
nanoparticles and graphene, the afforded CeO
2
-GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO
2
–GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO
2
–GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials.</description><identifier>ISSN: 1976-4251</identifier><identifier>EISSN: 2233-4998</identifier><identifier>DOI: 10.1007/s42823-022-00353-7</identifier><language>eng</language><publisher>Singapore: Springer Nature Singapore</publisher><subject>Alcohol ; Bioaccumulation ; Carbon ; Cerium ; Cerium oxides ; Characterization and Evaluation of Materials ; Chemical sensors ; Chemistry and Materials Science ; Chromatography ; Composite materials ; Electrochemistry ; Electrode materials ; Electrodes ; Electrons ; Glassy carbon ; Graphene ; Materials Engineering ; Materials Science ; Microscopy ; Morphology ; Nanocomposites ; Nanomaterials ; Nanoparticles ; Nanotechnology ; Nitrates ; Original Article ; Oxidation ; Pentachlorophenol ; Pesticides ; Preservatives ; Toxicity ; Ultrasonic imaging ; Wood preservatives</subject><ispartof>Carbon Letters, 2022-08, Vol.32 (5), p.1277-1285</ispartof><rights>The Author(s), under exclusive licence to Korean Carbon Society 2022. corrected publication 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c347t-c629a1c291c2bd5e57b3b36eafa94884959d47b7f3f13bbc10e55fba537be9c23</citedby><cites>FETCH-LOGICAL-c347t-c629a1c291c2bd5e57b3b36eafa94884959d47b7f3f13bbc10e55fba537be9c23</cites><orcidid>0000-0002-4710-3555</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2933134327?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,21388,21389,21390,23255,27923,27924,33529,33702,33743,34004,34313,43658,43786,43804,43952,44066,64384,64388,72240</link.rule.ids></links><search><creatorcontrib>Yang, Man</creatorcontrib><creatorcontrib>Chen, Yiyang</creatorcontrib><creatorcontrib>Wang, Haitao</creatorcontrib><creatorcontrib>Zou, Yilun</creatorcontrib><creatorcontrib>Wu, Pingxiu</creatorcontrib><creatorcontrib>Zou, Jing</creatorcontrib><creatorcontrib>Jiang, Jizhou</creatorcontrib><title>Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol</title><title>Carbon Letters</title><addtitle>Carbon Lett</addtitle><description>Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant challenge. Herein, a convenient and sensitive electrochemical sensor is constructed by modifying glassy carbon electrode with cerium dioxide (CeO
2
) nanoparticles anchored graphene (CeO
2
-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO
2
nanoparticles and graphene, the afforded CeO
2
-GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO
2
–GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO
2
–GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials.</description><subject>Alcohol</subject><subject>Bioaccumulation</subject><subject>Carbon</subject><subject>Cerium</subject><subject>Cerium oxides</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical sensors</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Composite materials</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electrons</subject><subject>Glassy carbon</subject><subject>Graphene</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Nitrates</subject><subject>Original Article</subject><subject>Oxidation</subject><subject>Pentachlorophenol</subject><subject>Pesticides</subject><subject>Preservatives</subject><subject>Toxicity</subject><subject>Ultrasonic imaging</subject><subject>Wood preservatives</subject><issn>1976-4251</issn><issn>2233-4998</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kc1qHSEYhqU00EOSG-hK6Hpax0-P47Ic-geBLJKuRT3fnLGdo1M1ge56B13kDnsldXIC6argh6LP-7h4CXnds7c9Y-pdEXzg0DHOO8ZAQqdekA3nAJ3QenhJNr1W205w2b8il6UE10LANIPthvy-SfN9qhPmo53pknGx2daQIk0j3eE1p9HG1C5r8DOWP78eDtkuE0Z8fPDpuKQSKhZq24oUZ_Q1Jz_hMfhmLBhLynRssx5DDfdI91gbFeKBLhir9dOcclqlab4gZ6OdC14-7efk68cPt7vP3dX1py-791edB6Fq57dc295z3cbtJUrlwMEW7Wi1GAahpd4L5dQIYw_O-Z6hlKOzEpRD7Tmckzcn75LTjzss1XxLdzm2Lw3XAD0I4OqZ-p4y2uKnNNv8TArOBrm6-InyOZWScTRLDkebf5qembUhc2rItIbMY0NmVcMpVBocD_iP9j-pvzYwmSg</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Yang, Man</creator><creator>Chen, Yiyang</creator><creator>Wang, Haitao</creator><creator>Zou, Yilun</creator><creator>Wu, Pingxiu</creator><creator>Zou, Jing</creator><creator>Jiang, Jizhou</creator><general>Springer Nature Singapore</general><general>한국탄소학회</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>KROLR</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M2P</scope><scope>M7S</scope><scope>PATMY</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0002-4710-3555</orcidid></search><sort><creationdate>20220801</creationdate><title>Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol</title><author>Yang, Man ; Chen, Yiyang ; Wang, Haitao ; Zou, Yilun ; Wu, Pingxiu ; Zou, Jing ; Jiang, Jizhou</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c347t-c629a1c291c2bd5e57b3b36eafa94884959d47b7f3f13bbc10e55fba537be9c23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alcohol</topic><topic>Bioaccumulation</topic><topic>Carbon</topic><topic>Cerium</topic><topic>Cerium oxides</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical sensors</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Composite materials</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Electrons</topic><topic>Glassy carbon</topic><topic>Graphene</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Microscopy</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nanotechnology</topic><topic>Nitrates</topic><topic>Original Article</topic><topic>Oxidation</topic><topic>Pentachlorophenol</topic><topic>Pesticides</topic><topic>Preservatives</topic><topic>Toxicity</topic><topic>Ultrasonic imaging</topic><topic>Wood preservatives</topic><toplevel>online_resources</toplevel><creatorcontrib>Yang, Man</creatorcontrib><creatorcontrib>Chen, Yiyang</creatorcontrib><creatorcontrib>Wang, Haitao</creatorcontrib><creatorcontrib>Zou, Yilun</creatorcontrib><creatorcontrib>Wu, Pingxiu</creatorcontrib><creatorcontrib>Zou, Jing</creatorcontrib><creatorcontrib>Jiang, Jizhou</creatorcontrib><collection>CrossRef</collection><collection>Korea Scholar</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Environmental Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Carbon Letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Man</au><au>Chen, Yiyang</au><au>Wang, Haitao</au><au>Zou, Yilun</au><au>Wu, Pingxiu</au><au>Zou, Jing</au><au>Jiang, Jizhou</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol</atitle><jtitle>Carbon Letters</jtitle><stitle>Carbon Lett</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>32</volume><issue>5</issue><spage>1277</spage><epage>1285</epage><pages>1277-1285</pages><issn>1976-4251</issn><eissn>2233-4998</eissn><abstract>Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant challenge. Herein, a convenient and sensitive electrochemical sensor is constructed by modifying glassy carbon electrode with cerium dioxide (CeO
2
) nanoparticles anchored graphene (CeO
2
-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO
2
nanoparticles and graphene, the afforded CeO
2
-GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO
2
–GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO
2
–GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials.</abstract><cop>Singapore</cop><pub>Springer Nature Singapore</pub><doi>10.1007/s42823-022-00353-7</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-4710-3555</orcidid></addata></record> |
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| source | ProQuest Central Essentials; ProQuest Central (Alumni Edition); ProQuest Central Student; ProQuest Central Korea; ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Alcohol Bioaccumulation Carbon Cerium Cerium oxides Characterization and Evaluation of Materials Chemical sensors Chemistry and Materials Science Chromatography Composite materials Electrochemistry Electrode materials Electrodes Electrons Glassy carbon Graphene Materials Engineering Materials Science Microscopy Morphology Nanocomposites Nanomaterials Nanoparticles Nanotechnology Nitrates Original Article Oxidation Pentachlorophenol Pesticides Preservatives Toxicity Ultrasonic imaging Wood preservatives |
| title | Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol |
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