Highly Sensitive Electrochemical Sensor Based on a Solvent-Processing Cobalt Phthalocyanine for Detection of Ascorbic Acid
The development of enzyme-free sensing materials with high performance and low cost is extremely essential in the fields of medicine, food, and chemical engineering. In this work, a solvent-processing film of 2,3,9,10,16,17,23,24-octa-(2,6-dimethylphenoxy) phthalocyaninato cobalt complex-based elect...
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| Veröffentlicht in: | IEEE sensors journal 2024-03, Vol.24 (5), p.5806-5812 |
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| creator | Sun, Yilan Wei, Ying Liu, Yinghui Zang, Xiaofeng Lu, Guang Kong, Xia Huang, Renhe Liu, Qingyun |
| description | The development of enzyme-free sensing materials with high performance and low cost is extremely essential in the fields of medicine, food, and chemical engineering. In this work, a solvent-processing film of 2,3,9,10,16,17,23,24-octa-(2,6-dimethylphenoxy) phthalocyaninato cobalt complex-based electrochemical sensor was prepared on a glassy carbon electrode. The CoPc(OC _{{8}} \text{H}_{{9}} )8 film is demonstrated to be a lamellar structure with a large surface area, which in turn increases the active site of ascorbic acid (AA) redox reactions, and thus presents excellent sensitivity and terrific anti-interference ability for the detection of AA with wide detection range (0.1- 100 ~\mu \text{M} ) and low limit of detection (LOD) (36 nM), and can selectively detect AA in milk and human serum. Because of its outstanding electrocatalytic kinetic characteristics, this present enzyme-free electrochemical sensor has a broad prospect in the application of analytical sensing of AA and it will be helpful for the design and fabrication of high-performance low-cost electrochemical sensor for trace detection of AA. |
| doi_str_mv | 10.1109/JSEN.2024.3351357 |
| format | Article |
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In this work, a solvent-processing film of 2,3,9,10,16,17,23,24-octa-(2,6-dimethylphenoxy) phthalocyaninato cobalt complex-based electrochemical sensor was prepared on a glassy carbon electrode. The CoPc(OC<inline-formula> <tex-math notation="LaTeX">_{{8}} \text{H}_{{9}} </tex-math></inline-formula>)8 film is demonstrated to be a lamellar structure with a large surface area, which in turn increases the active site of ascorbic acid (AA) redox reactions, and thus presents excellent sensitivity and terrific anti-interference ability for the detection of AA with wide detection range (0.1-<inline-formula> <tex-math notation="LaTeX">100 ~\mu \text{M} </tex-math></inline-formula>) and low limit of detection (LOD) (36 nM), and can selectively detect AA in milk and human serum. Because of its outstanding electrocatalytic kinetic characteristics, this present enzyme-free electrochemical sensor has a broad prospect in the application of analytical sensing of AA and it will be helpful for the design and fabrication of high-performance low-cost electrochemical sensor for trace detection of AA.]]></description><identifier>ISSN: 1530-437X</identifier><identifier>EISSN: 1558-1748</identifier><identifier>DOI: 10.1109/JSEN.2024.3351357</identifier><identifier>CODEN: ISJEAZ</identifier><language>eng</language><publisher>New York: IEEE</publisher><subject>Ascorbic acid ; Ascorbic acid (AA) ; Chemical engineering ; Chemical sensors ; Chemicals ; Cobalt ; Cobalt compounds ; cobalt phthalocyanine (CoPc) ; Costs ; electrochemical sensor ; Electrodes ; Enzymes ; Glassy carbon ; Lamellar structure ; Low cost ; Mathematical models ; Redox reactions ; Sensor phenomena and characterization ; Sensors ; solvent-processing ; Solvents</subject><ispartof>IEEE sensors journal, 2024-03, Vol.24 (5), p.5806-5812</ispartof><rights>Copyright The Institute of Electrical and Electronics Engineers, Inc. (IEEE) 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c294t-44eafb94bf672a32c9463acccbc3afe1f91cdf64adef9e1ae0d9da736e59a2ff3</citedby><cites>FETCH-LOGICAL-c294t-44eafb94bf672a32c9463acccbc3afe1f91cdf64adef9e1ae0d9da736e59a2ff3</cites><orcidid>0000-0003-3695-9005</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/10400434$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>314,776,780,792,27903,27904,54736</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/10400434$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Sun, Yilan</creatorcontrib><creatorcontrib>Wei, Ying</creatorcontrib><creatorcontrib>Liu, Yinghui</creatorcontrib><creatorcontrib>Zang, Xiaofeng</creatorcontrib><creatorcontrib>Lu, Guang</creatorcontrib><creatorcontrib>Kong, Xia</creatorcontrib><creatorcontrib>Huang, Renhe</creatorcontrib><creatorcontrib>Liu, Qingyun</creatorcontrib><title>Highly Sensitive Electrochemical Sensor Based on a Solvent-Processing Cobalt Phthalocyanine for Detection of Ascorbic Acid</title><title>IEEE sensors journal</title><addtitle>JSEN</addtitle><description><![CDATA[The development of enzyme-free sensing materials with high performance and low cost is extremely essential in the fields of medicine, food, and chemical engineering. In this work, a solvent-processing film of 2,3,9,10,16,17,23,24-octa-(2,6-dimethylphenoxy) phthalocyaninato cobalt complex-based electrochemical sensor was prepared on a glassy carbon electrode. The CoPc(OC<inline-formula> <tex-math notation="LaTeX">_{{8}} \text{H}_{{9}} </tex-math></inline-formula>)8 film is demonstrated to be a lamellar structure with a large surface area, which in turn increases the active site of ascorbic acid (AA) redox reactions, and thus presents excellent sensitivity and terrific anti-interference ability for the detection of AA with wide detection range (0.1-<inline-formula> <tex-math notation="LaTeX">100 ~\mu \text{M} </tex-math></inline-formula>) and low limit of detection (LOD) (36 nM), and can selectively detect AA in milk and human serum. Because of its outstanding electrocatalytic kinetic characteristics, this present enzyme-free electrochemical sensor has a broad prospect in the application of analytical sensing of AA and it will be helpful for the design and fabrication of high-performance low-cost electrochemical sensor for trace detection of AA.]]></description><subject>Ascorbic acid</subject><subject>Ascorbic acid (AA)</subject><subject>Chemical engineering</subject><subject>Chemical sensors</subject><subject>Chemicals</subject><subject>Cobalt</subject><subject>Cobalt compounds</subject><subject>cobalt phthalocyanine (CoPc)</subject><subject>Costs</subject><subject>electrochemical sensor</subject><subject>Electrodes</subject><subject>Enzymes</subject><subject>Glassy carbon</subject><subject>Lamellar structure</subject><subject>Low cost</subject><subject>Mathematical models</subject><subject>Redox reactions</subject><subject>Sensor phenomena and characterization</subject><subject>Sensors</subject><subject>solvent-processing</subject><subject>Solvents</subject><issn>1530-437X</issn><issn>1558-1748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNpNkE1LAzEQhhdRsFZ_gOAh4Hlrvna3OdZarSJaqIK3kM1O2pTtpibbQv31Zm0PnmZgnvcdeJLkmuABIVjcvcwnbwOKKR8wlhGWFSdJj2TZMCUFH552O8MpZ8XXeXIRwgpjIoqs6CU_U7tY1ns0hybY1u4ATWrQrXd6CWurVf13cR7dqwAVcg1SaO7qHTRtOosUhGCbBRq7UtUtmi3bpaqd3qvGNoBMzD1AG_tsDDqDRkE7X1qNRtpWl8mZUXWAq-PsJ5-Pk4_xNH19f3oej15TTQVvU85BmVLw0uQFVYxqwXOmtNalZsoAMYLoyuRcVWAEEAW4EpUqWA6ZUNQY1k9uD70b7763EFq5clvfxJeSCkazIvbRSJEDpb0LwYORG2_Xyu8lwbJTLDvFslMsj4pj5uaQsQDwj-cYc8bZL8noeyY</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Sun, Yilan</creator><creator>Wei, Ying</creator><creator>Liu, Yinghui</creator><creator>Zang, Xiaofeng</creator><creator>Lu, Guang</creator><creator>Kong, Xia</creator><creator>Huang, Renhe</creator><creator>Liu, Qingyun</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. (IEEE)</general><scope>97E</scope><scope>RIA</scope><scope>RIE</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-3695-9005</orcidid></search><sort><creationdate>20240301</creationdate><title>Highly Sensitive Electrochemical Sensor Based on a Solvent-Processing Cobalt Phthalocyanine for Detection of Ascorbic Acid</title><author>Sun, Yilan ; Wei, Ying ; Liu, Yinghui ; Zang, Xiaofeng ; Lu, Guang ; Kong, Xia ; Huang, Renhe ; Liu, Qingyun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c294t-44eafb94bf672a32c9463acccbc3afe1f91cdf64adef9e1ae0d9da736e59a2ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ascorbic acid</topic><topic>Ascorbic acid (AA)</topic><topic>Chemical engineering</topic><topic>Chemical sensors</topic><topic>Chemicals</topic><topic>Cobalt</topic><topic>Cobalt compounds</topic><topic>cobalt phthalocyanine (CoPc)</topic><topic>Costs</topic><topic>electrochemical sensor</topic><topic>Electrodes</topic><topic>Enzymes</topic><topic>Glassy carbon</topic><topic>Lamellar structure</topic><topic>Low cost</topic><topic>Mathematical models</topic><topic>Redox reactions</topic><topic>Sensor phenomena and characterization</topic><topic>Sensors</topic><topic>solvent-processing</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Yilan</creatorcontrib><creatorcontrib>Wei, Ying</creatorcontrib><creatorcontrib>Liu, Yinghui</creatorcontrib><creatorcontrib>Zang, Xiaofeng</creatorcontrib><creatorcontrib>Lu, Guang</creatorcontrib><creatorcontrib>Kong, Xia</creatorcontrib><creatorcontrib>Huang, Renhe</creatorcontrib><creatorcontrib>Liu, Qingyun</creatorcontrib><collection>IEEE All-Society Periodicals Package (ASPP) 2005-present</collection><collection>IEEE All-Society Periodicals Package (ASPP) 1998-Present</collection><collection>IEEE Electronic Library (IEL)</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>IEEE sensors journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Sun, Yilan</au><au>Wei, Ying</au><au>Liu, Yinghui</au><au>Zang, Xiaofeng</au><au>Lu, Guang</au><au>Kong, Xia</au><au>Huang, Renhe</au><au>Liu, Qingyun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Sensitive Electrochemical Sensor Based on a Solvent-Processing Cobalt Phthalocyanine for Detection of Ascorbic Acid</atitle><jtitle>IEEE sensors journal</jtitle><stitle>JSEN</stitle><date>2024-03-01</date><risdate>2024</risdate><volume>24</volume><issue>5</issue><spage>5806</spage><epage>5812</epage><pages>5806-5812</pages><issn>1530-437X</issn><eissn>1558-1748</eissn><coden>ISJEAZ</coden><abstract><![CDATA[The development of enzyme-free sensing materials with high performance and low cost is extremely essential in the fields of medicine, food, and chemical engineering. In this work, a solvent-processing film of 2,3,9,10,16,17,23,24-octa-(2,6-dimethylphenoxy) phthalocyaninato cobalt complex-based electrochemical sensor was prepared on a glassy carbon electrode. The CoPc(OC<inline-formula> <tex-math notation="LaTeX">_{{8}} \text{H}_{{9}} </tex-math></inline-formula>)8 film is demonstrated to be a lamellar structure with a large surface area, which in turn increases the active site of ascorbic acid (AA) redox reactions, and thus presents excellent sensitivity and terrific anti-interference ability for the detection of AA with wide detection range (0.1-<inline-formula> <tex-math notation="LaTeX">100 ~\mu \text{M} </tex-math></inline-formula>) and low limit of detection (LOD) (36 nM), and can selectively detect AA in milk and human serum. Because of its outstanding electrocatalytic kinetic characteristics, this present enzyme-free electrochemical sensor has a broad prospect in the application of analytical sensing of AA and it will be helpful for the design and fabrication of high-performance low-cost electrochemical sensor for trace detection of AA.]]></abstract><cop>New York</cop><pub>IEEE</pub><doi>10.1109/JSEN.2024.3351357</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-3695-9005</orcidid></addata></record> |
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| subjects | Ascorbic acid Ascorbic acid (AA) Chemical engineering Chemical sensors Chemicals Cobalt Cobalt compounds cobalt phthalocyanine (CoPc) Costs electrochemical sensor Electrodes Enzymes Glassy carbon Lamellar structure Low cost Mathematical models Redox reactions Sensor phenomena and characterization Sensors solvent-processing Solvents |
| title | Highly Sensitive Electrochemical Sensor Based on a Solvent-Processing Cobalt Phthalocyanine for Detection of Ascorbic Acid |
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