Visible‐Light‐Mediated Amide Synthesis in Deep Eutectic Solvents
In the present study, for the first time environmentally friendly deep eutectic solvents (DESs) are used as reaction media to perform an efficient, simple and straightforward photocatalytic amide synthesis at room temperature using thioacids and amines. This method features mild conditions, a broad...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2024-02, Vol.366 (4), p.870-876 |
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| container_title | Advanced synthesis & catalysis |
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| creator | Procopio, Debora Marset, Xavier Guillena, Gabriela Di Gioia, Maria Luisa Ramón, Diego J. |
| description | In the present study, for the first time environmentally friendly deep eutectic solvents (DESs) are used as reaction media to perform an efficient, simple and straightforward photocatalytic amide synthesis at room temperature using thioacids and amines. This method features mild conditions, a broad substrate scope, high yields (≤99%) under ambient conditions with air and moisture tolerance. Moreover, the applied operationally mild reaction conditions tolerate the presence of several different functional group substituents on the amine counterpart. Finally, the developed approach allows the recycling of the reaction medium and catalyst for at least three consecutive cycles without a significant decrease in the reaction yield. |
| doi_str_mv | 10.1002/adsc.202300725 |
| format | Article |
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| source | Wiley Online Library All Journals |
| subjects | Amide Amines Deep Eutectic Solvent Functional groups Photocatalysis Recyclability Room temperature Solvents Substrates Sustainability Synthesis |
| title | Visible‐Light‐Mediated Amide Synthesis in Deep Eutectic Solvents |
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