Wastewater Pollution Prevention for volatile organic compounds (Benzene, Toluene, Ethylbenzene, and Xylene) using cloud point extraction and regeneration of surfactant by evaporation

The aim of this work was the cloud point extraction (CPE) of volatile organic compounds, namely benzene, toluene, ethylbenzene, and p -xylene (BTEX), from aqueous solutions using the readily biodegradable nonionic surfactant PONPE 7.5. Binary water/surfactant and pseudo-binary (in the presence of so...

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Veröffentlicht in:Euro-Mediterranean journal for environmental integration 2022-03, Vol.7 (1), p.1-12
Hauptverfasser: Ghouas, Halima, Haddou, Boumediene, Canselier, Jean Paul, Gourdon, Christophe
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Haddou, Boumediene
Canselier, Jean Paul
Gourdon, Christophe
description The aim of this work was the cloud point extraction (CPE) of volatile organic compounds, namely benzene, toluene, ethylbenzene, and p -xylene (BTEX), from aqueous solutions using the readily biodegradable nonionic surfactant PONPE 7.5. Binary water/surfactant and pseudo-binary (in the presence of solute) phase diagrams were plotted. The extraction results for four quantities—Extraction efficiency ( E ), residual concentrations of solute and surfactant in the dilute phase ( X s,w and X t,w , respectively), and volume fraction of coacervate at equilibrium ( Ф c )—were expressed as functions of the wt.% surfactant and the temperature. The effect of sodium sulfate and cetyltrimethylammonium bromide (CTAB) addition was also studied, and the possibility of recycling the surfactant was demonstrated. The results obtained for each parameter upon applying CPE to remove BTEX were represented on three-dimensional diagrams using response surface methodology (RSM). We sought the optimal tradeoff between the parameters that govern CPE efficiency according to the initial concentration of surfactant and the temperature. E was found to increase with surfactant concentration and hydrocarbon alkylation degree in the following order: B  
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E was found to increase with surfactant concentration and hydrocarbon alkylation degree in the following order: B  &lt;  T  &lt;  E  &lt;  X , with respective maximum values of 75, 83, 90, and 95%, without the addition of sodium sulfate or CTAB. 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E was found to increase with surfactant concentration and hydrocarbon alkylation degree in the following order: B  &lt;  T  &lt;  E  &lt;  X , with respective maximum values of 75, 83, 90, and 95%, without the addition of sodium sulfate or CTAB. The concentration of the solute in the coacervate increased as the temperature, surfactant or additive concentration, and degree of alkylation of the aromatic solute increased.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s41207-022-00292-9</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-9277-2187</orcidid></addata></record>
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subjects Alkylation
Aquatic Pollution
Aqueous solutions
Atmospheric Protection/Air Quality Control/Air Pollution
Benzene
Biodegradation
Cetyltrimethylammonium bromide
Earth and Environmental Science
Earth Sciences
Electrolytes
Environmental Chemistry
Environmental Management
Environmental Science and Engineering
Ethyl benzene
Ethylbenzene
Evaporation
Hydrocarbons
Organic compounds
p-Xylene
Parameters
Phase diagrams
Pollutants
Pollution abatement
Pollution prevention
Response surface methodology
Review Article
Sodium
Sodium sulfate
Sulfates
Surfactants
Toluene
VOCs
Volatile organic compounds
Waste Management/Waste Technology
Waste Water Technology
Wastewater pollution
Water Management
Water Pollution Control
Xylene
title Wastewater Pollution Prevention for volatile organic compounds (Benzene, Toluene, Ethylbenzene, and Xylene) using cloud point extraction and regeneration of surfactant by evaporation
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