Palladium‐Catalyzed Synthesis of Bicyclic Derivatives from the Cyclization/1,4‐Difunctionalization of Bromoarenes with Diazo Compounds

A Pd‐catalyzed cyclization/1,4‐difunctionalization of bromoarenes bearing a carbon nucleophile with diazo compounds has been developed. The present reaction proceeds through a π‐benzyl palladium intermediate, whose reactivity is a key for the remarkable 1,4‐selectivity of this reaction, providing fu...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Asian journal of organic chemistry 2024-02, Vol.13 (2), p.n/a
Hauptverfasser:	Kato, Hiroki, Fukuhara, Yuki, Miyazaki, Ryuya, Muto, Kei, Yamaguchi, Junichiro
Format:	Artikel
Sprache:	eng
Schlagworte:	benzyl palladium Chemical synthesis cyclization difunctionalization indan Nucleophiles Palladium tetralin
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!