Electrospinning of Neat Graphene Nanofibers
Macroscopic assembly of graphene sheets has renovated the preparation of neat carbonaceous fibers with integrating high performance and superior functionalities, beyond the pyrolysis of conventional polymeric precursors. To date, graphene microfibers by the liquid crystalline wet-spinning method hav...
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| Veröffentlicht in: | Advanced fiber materials (Online) 2022-04, Vol.4 (2), p.268-279 |
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| creator | Han, Zhanpo Wang, Jiaqing Liu, Senping Zhang, Qinghua Liu, Yingjun Tan, Yeqiang Luo, Shiyu Guo, Fan Ma, Jingyu Li, Peng Ming, Xin Gao, Chao Xu, Zhen |
| description | Macroscopic assembly of graphene sheets has renovated the preparation of neat carbonaceous fibers with integrating high performance and superior functionalities, beyond the pyrolysis of conventional polymeric precursors. To date, graphene microfibers by the liquid crystalline wet-spinning method have been established. However, how to reliably prepare continuous neat graphene nanofibers remains unknown. Here, we present the electrospinning of neat graphene nanofibers enabled by modulating colossally extensional flow state of graphene oxide liquid crystals. We use polymer with mega molecular weight as transient additives to realize the colossal extensional flow and electrospinning. The neat graphene nanofibers feature high electronic quality and crystallinity and exhibit high electrical conductivity of 2.02 × 10
6
S/m that is to be comparable with single crystal graphite whisker. The electrospinning of graphene nanofibers was extended to prepare large-area fabric with high flexibility and superior specific electrical/thermal conductivities. The electrospinning of graphene nanofibers opens the door to nanofibers of rich two-dimensional sheets and the neat graphene nanofibers may grow to be a new species after conventional carbonaceous nanofibers and whiskers in broad functional applications.
Graphic abstract
Electrospinning of neat graphene nanofibers is realized by achieving the colossal extension flow of GO dispersion with the assistance of mega polymer. Neat graphene nanofibers and fabrics show good continuity, high crystallinity, excellent conductivity and thermal conductivity, having great potentials in extensive applications. |
| doi_str_mv | 10.1007/s42765-021-00105-8 |
| format | Article |
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6
S/m that is to be comparable with single crystal graphite whisker. The electrospinning of graphene nanofibers was extended to prepare large-area fabric with high flexibility and superior specific electrical/thermal conductivities. The electrospinning of graphene nanofibers opens the door to nanofibers of rich two-dimensional sheets and the neat graphene nanofibers may grow to be a new species after conventional carbonaceous nanofibers and whiskers in broad functional applications.
Graphic abstract
Electrospinning of neat graphene nanofibers is realized by achieving the colossal extension flow of GO dispersion with the assistance of mega polymer. Neat graphene nanofibers and fabrics show good continuity, high crystallinity, excellent conductivity and thermal conductivity, having great potentials in extensive applications.</description><identifier>ISSN: 2524-7921</identifier><identifier>EISSN: 2524-793X</identifier><identifier>DOI: 10.1007/s42765-021-00105-8</identifier><language>eng</language><publisher>Singapore: Springer Singapore</publisher><subject>Additives ; Carbon ; Chemistry and Materials Science ; Chinese Materials Conference 2021-Division of Fiber Materials and Composite Technology & The 70th Anniversary of Donghua University ; Conductivity ; Crystallinity ; Electric fields ; Electrical resistivity ; Electrospinning ; Graphene ; Heat conductivity ; Liquid crystals ; Materials Engineering ; Materials Science ; Microfibers ; Molecular weight ; Morphology ; Nanofibers ; Nanoscale Science and Technology ; Polymer Sciences ; Polymers ; Prepolymers ; Pyrolysis ; Renewable and Green Energy ; Research Article ; Rheology ; Single crystals ; Textile composites ; Textile Engineering ; Thermal conductivity</subject><ispartof>Advanced fiber materials (Online), 2022-04, Vol.4 (2), p.268-279</ispartof><rights>Donghua University, Shanghai, China 2021</rights><rights>Donghua University, Shanghai, China 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-f5d9f8a1b9522f8f4c54ebbf741748b7dda69f3f7a44b8a44ee76f20fe85303e3</citedby><cites>FETCH-LOGICAL-c319t-f5d9f8a1b9522f8f4c54ebbf741748b7dda69f3f7a44b8a44ee76f20fe85303e3</cites><orcidid>0000-0001-9282-9753</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s42765-021-00105-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2932254831?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,27923,27924,33743,41487,42556,43804,51318,64384,64388,72240</link.rule.ids></links><search><creatorcontrib>Han, Zhanpo</creatorcontrib><creatorcontrib>Wang, Jiaqing</creatorcontrib><creatorcontrib>Liu, Senping</creatorcontrib><creatorcontrib>Zhang, Qinghua</creatorcontrib><creatorcontrib>Liu, Yingjun</creatorcontrib><creatorcontrib>Tan, Yeqiang</creatorcontrib><creatorcontrib>Luo, Shiyu</creatorcontrib><creatorcontrib>Guo, Fan</creatorcontrib><creatorcontrib>Ma, Jingyu</creatorcontrib><creatorcontrib>Li, Peng</creatorcontrib><creatorcontrib>Ming, Xin</creatorcontrib><creatorcontrib>Gao, Chao</creatorcontrib><creatorcontrib>Xu, Zhen</creatorcontrib><title>Electrospinning of Neat Graphene Nanofibers</title><title>Advanced fiber materials (Online)</title><addtitle>Adv. Fiber Mater</addtitle><description>Macroscopic assembly of graphene sheets has renovated the preparation of neat carbonaceous fibers with integrating high performance and superior functionalities, beyond the pyrolysis of conventional polymeric precursors. To date, graphene microfibers by the liquid crystalline wet-spinning method have been established. However, how to reliably prepare continuous neat graphene nanofibers remains unknown. Here, we present the electrospinning of neat graphene nanofibers enabled by modulating colossally extensional flow state of graphene oxide liquid crystals. We use polymer with mega molecular weight as transient additives to realize the colossal extensional flow and electrospinning. The neat graphene nanofibers feature high electronic quality and crystallinity and exhibit high electrical conductivity of 2.02 × 10
6
S/m that is to be comparable with single crystal graphite whisker. The electrospinning of graphene nanofibers was extended to prepare large-area fabric with high flexibility and superior specific electrical/thermal conductivities. The electrospinning of graphene nanofibers opens the door to nanofibers of rich two-dimensional sheets and the neat graphene nanofibers may grow to be a new species after conventional carbonaceous nanofibers and whiskers in broad functional applications.
Graphic abstract
Electrospinning of neat graphene nanofibers is realized by achieving the colossal extension flow of GO dispersion with the assistance of mega polymer. Neat graphene nanofibers and fabrics show good continuity, high crystallinity, excellent conductivity and thermal conductivity, having great potentials in extensive applications.</description><subject>Additives</subject><subject>Carbon</subject><subject>Chemistry and Materials Science</subject><subject>Chinese Materials Conference 2021-Division of Fiber Materials and Composite Technology & The 70th Anniversary of Donghua University</subject><subject>Conductivity</subject><subject>Crystallinity</subject><subject>Electric fields</subject><subject>Electrical resistivity</subject><subject>Electrospinning</subject><subject>Graphene</subject><subject>Heat conductivity</subject><subject>Liquid crystals</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Microfibers</subject><subject>Molecular weight</subject><subject>Morphology</subject><subject>Nanofibers</subject><subject>Nanoscale Science and Technology</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Prepolymers</subject><subject>Pyrolysis</subject><subject>Renewable and Green Energy</subject><subject>Research Article</subject><subject>Rheology</subject><subject>Single crystals</subject><subject>Textile composites</subject><subject>Textile Engineering</subject><subject>Thermal conductivity</subject><issn>2524-7921</issn><issn>2524-793X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kDFPwzAQhS0EEhX0DzBFYkSB89munRFVpSBVZQGJzXLSc0lVnGCnA_8eQxBsLHc3vPfu6WPsgsM1B9A3SaKeqRKQlwAcVGmO2AQVylJX4uX490Z-yqYp7QAANQdEmLCrxZ6aIXapb0Now7bofLEmNxTL6PpXClSsXeh8W1NM5-zEu32i6c8-Y893i6f5fbl6XD7Mb1dlI3g1lF5tKm8cryuF6I2XjZJU115LrqWp9WbjZpUXXjspa5MHkZ55BE9GCRAkztjlmNvH7v1AabC77hBDfmmxEohKGsGzCkdVk9unSN72sX1z8cNysF9c7MjFZi72m4s12SRGU8risKX4F_2P6xPmoWRi</recordid><startdate>20220401</startdate><enddate>20220401</enddate><creator>Han, Zhanpo</creator><creator>Wang, Jiaqing</creator><creator>Liu, Senping</creator><creator>Zhang, Qinghua</creator><creator>Liu, Yingjun</creator><creator>Tan, Yeqiang</creator><creator>Luo, Shiyu</creator><creator>Guo, Fan</creator><creator>Ma, Jingyu</creator><creator>Li, Peng</creator><creator>Ming, Xin</creator><creator>Gao, Chao</creator><creator>Xu, Zhen</creator><general>Springer Singapore</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0001-9282-9753</orcidid></search><sort><creationdate>20220401</creationdate><title>Electrospinning of Neat Graphene Nanofibers</title><author>Han, Zhanpo ; Wang, Jiaqing ; Liu, Senping ; Zhang, Qinghua ; Liu, Yingjun ; Tan, Yeqiang ; Luo, Shiyu ; Guo, Fan ; Ma, Jingyu ; Li, Peng ; Ming, Xin ; Gao, Chao ; Xu, Zhen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-f5d9f8a1b9522f8f4c54ebbf741748b7dda69f3f7a44b8a44ee76f20fe85303e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Additives</topic><topic>Carbon</topic><topic>Chemistry and Materials Science</topic><topic>Chinese Materials Conference 2021-Division of Fiber Materials and Composite Technology & The 70th Anniversary of Donghua University</topic><topic>Conductivity</topic><topic>Crystallinity</topic><topic>Electric fields</topic><topic>Electrical resistivity</topic><topic>Electrospinning</topic><topic>Graphene</topic><topic>Heat conductivity</topic><topic>Liquid crystals</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Microfibers</topic><topic>Molecular weight</topic><topic>Morphology</topic><topic>Nanofibers</topic><topic>Nanoscale Science and Technology</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Prepolymers</topic><topic>Pyrolysis</topic><topic>Renewable and Green Energy</topic><topic>Research Article</topic><topic>Rheology</topic><topic>Single crystals</topic><topic>Textile composites</topic><topic>Textile Engineering</topic><topic>Thermal conductivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Han, Zhanpo</creatorcontrib><creatorcontrib>Wang, Jiaqing</creatorcontrib><creatorcontrib>Liu, Senping</creatorcontrib><creatorcontrib>Zhang, Qinghua</creatorcontrib><creatorcontrib>Liu, Yingjun</creatorcontrib><creatorcontrib>Tan, Yeqiang</creatorcontrib><creatorcontrib>Luo, Shiyu</creatorcontrib><creatorcontrib>Guo, Fan</creatorcontrib><creatorcontrib>Ma, Jingyu</creatorcontrib><creatorcontrib>Li, Peng</creatorcontrib><creatorcontrib>Ming, Xin</creatorcontrib><creatorcontrib>Gao, Chao</creatorcontrib><creatorcontrib>Xu, Zhen</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><jtitle>Advanced fiber materials (Online)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Han, Zhanpo</au><au>Wang, Jiaqing</au><au>Liu, Senping</au><au>Zhang, Qinghua</au><au>Liu, Yingjun</au><au>Tan, Yeqiang</au><au>Luo, Shiyu</au><au>Guo, Fan</au><au>Ma, Jingyu</au><au>Li, Peng</au><au>Ming, Xin</au><au>Gao, Chao</au><au>Xu, Zhen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrospinning of Neat Graphene Nanofibers</atitle><jtitle>Advanced fiber materials (Online)</jtitle><stitle>Adv. Fiber Mater</stitle><date>2022-04-01</date><risdate>2022</risdate><volume>4</volume><issue>2</issue><spage>268</spage><epage>279</epage><pages>268-279</pages><issn>2524-7921</issn><eissn>2524-793X</eissn><abstract>Macroscopic assembly of graphene sheets has renovated the preparation of neat carbonaceous fibers with integrating high performance and superior functionalities, beyond the pyrolysis of conventional polymeric precursors. To date, graphene microfibers by the liquid crystalline wet-spinning method have been established. However, how to reliably prepare continuous neat graphene nanofibers remains unknown. Here, we present the electrospinning of neat graphene nanofibers enabled by modulating colossally extensional flow state of graphene oxide liquid crystals. We use polymer with mega molecular weight as transient additives to realize the colossal extensional flow and electrospinning. The neat graphene nanofibers feature high electronic quality and crystallinity and exhibit high electrical conductivity of 2.02 × 10
6
S/m that is to be comparable with single crystal graphite whisker. The electrospinning of graphene nanofibers was extended to prepare large-area fabric with high flexibility and superior specific electrical/thermal conductivities. The electrospinning of graphene nanofibers opens the door to nanofibers of rich two-dimensional sheets and the neat graphene nanofibers may grow to be a new species after conventional carbonaceous nanofibers and whiskers in broad functional applications.
Graphic abstract
Electrospinning of neat graphene nanofibers is realized by achieving the colossal extension flow of GO dispersion with the assistance of mega polymer. Neat graphene nanofibers and fabrics show good continuity, high crystallinity, excellent conductivity and thermal conductivity, having great potentials in extensive applications.</abstract><cop>Singapore</cop><pub>Springer Singapore</pub><doi>10.1007/s42765-021-00105-8</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-9282-9753</orcidid></addata></record> |
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| subjects | Additives Carbon Chemistry and Materials Science Chinese Materials Conference 2021-Division of Fiber Materials and Composite Technology & The 70th Anniversary of Donghua University Conductivity Crystallinity Electric fields Electrical resistivity Electrospinning Graphene Heat conductivity Liquid crystals Materials Engineering Materials Science Microfibers Molecular weight Morphology Nanofibers Nanoscale Science and Technology Polymer Sciences Polymers Prepolymers Pyrolysis Renewable and Green Energy Research Article Rheology Single crystals Textile composites Textile Engineering Thermal conductivity |
| title | Electrospinning of Neat Graphene Nanofibers |
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