Enantioselective Synthesis of Planar‐Chiral Sulfur‐Containing Cyclophanes by Chiral Sulfide Catalyzed Electrophilic Sulfenylation of Arenes

An efficient catalytic asymmetric electrophilic sulfenylation reaction for the synthesis of planar‐chiral sulfur‐containing cyclophanes has been developed for the first time. This was achieved by using a new Lewis base catalyst and a new ortho‐trifluoromethyl‐substituted sulfenylating reagent. Using...

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Veröffentlicht in:	Angewandte Chemie 2024-03, Vol.136 (10), p.n/a
Hauptverfasser:	Zhu, Deng, Mu, Tong, Li, Ze‐Long, Luo, Hui‐Yun, Cao, Ren‐Fei, Xue, Xiao‐Song, Chen, Zhi‐Min
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysts Chemical synthesis Density functional theory Electrophilic sulfenylation Enantiomers Lewis base Lewis base catalysis Organosulfur chemistry Planar-chiral cyclophanes Reagents Substrates Sulfur π-π interaction
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