Electrical and Structural Properties of Poly (Methyl Methacrylate) Doped Potassium Iodide (KI) Solid Polymer Electrolyte
A high‐conducting salt‐doped polymer electrolyte layer has been created here for use in photocell technologies. The solution casting method is used to produce ion conducting film where poly (methyl methacrylate) (PMMA) is used as the host polymer and potassium iodide (KI) as the dopant. The conducti...
Gespeichert in:
| Veröffentlicht in: | Macromolecular symposia. 2024-02, Vol.413 (1), p.n/a |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 1 |
| container_start_page | |
| container_title | Macromolecular symposia. |
| container_volume | 413 |
| creator | Singh, Ritika Singh, Pramod K. Pandey, Shri Prakash Kakroo, Sunanda Tripathi, Pankaj K. Kumar, Rohit Bajaj, Yashika |
| description | A high‐conducting salt‐doped polymer electrolyte layer has been created here for use in photocell technologies. The solution casting method is used to produce ion conducting film where poly (methyl methacrylate) (PMMA) is used as the host polymer and potassium iodide (KI) as the dopant. The conductivity and amorphic increases of the polymer electrolytes with the addition of salt concentrations helps in the enhancement of the charge transfer properties. Using electrochemical impedance spectroscopy (EIS), ionic conductivity is evaluated where maximum conductivity is 3.99 × 10−6 S cm‐1 at 20 wt% KI concentration. Polarized optical microscopy (POM) shows the reduction in crystallinity by salt doping, while Fourier transforms infrared spectroscopy (FTIR) shows the complexation as well as composite nature of the film. Ionic transference number (tion) measurement shows the predominantly ionic nature of this polymer electrolyte. |
| doi_str_mv | 10.1002/masy.202300095 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2929299697</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2929299697</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1875-ca89743607c1f950a1962b2e86000c095f96845317eadb487ae160afaa9fc8bf3</originalsourceid><addsrcrecordid>eNqFkE1LAzEQhoMoWKtXzwEv7WFrku1-5Fhq1aLFQvXgKaTZBFOyTU2y6P57s67oUeYwM_C88_ECcInRBCNErmvu2wlBJEUI0ewIDHBGcJJShI5jjQhJcJqjU3Dm_a5DaIEH4HNhpAhOC24g31dwE1wjQuNiu3b2IF3Q0kOr4NqaFo5WMry1BnaJC9caHuQY3kSuikDg3uumhktb6UrC0cNyDDfW6OpbXEsH-2WxCfIcnChuvLz4yUPwcrt4nt8nj093y_nsMRG4LLJE8JIW03h3IbCiGeKY5mRLZJnHF0T8U9G8nGYpLiSvttOy4BLniCvOqRLlVqVDcNXPPTj73kgf2M42bh9XMkK7oDktIjXpKeGs904qdnC65q5lGLHOXda5y37djQLaCz60ke0_NFvNNq9_2i-iZn8C</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2929299697</pqid></control><display><type>article</type><title>Electrical and Structural Properties of Poly (Methyl Methacrylate) Doped Potassium Iodide (KI) Solid Polymer Electrolyte</title><source>Wiley Journals</source><creator>Singh, Ritika ; Singh, Pramod K. ; Pandey, Shri Prakash ; Kakroo, Sunanda ; Tripathi, Pankaj K. ; Kumar, Rohit ; Bajaj, Yashika</creator><creatorcontrib>Singh, Ritika ; Singh, Pramod K. ; Pandey, Shri Prakash ; Kakroo, Sunanda ; Tripathi, Pankaj K. ; Kumar, Rohit ; Bajaj, Yashika</creatorcontrib><description>A high‐conducting salt‐doped polymer electrolyte layer has been created here for use in photocell technologies. The solution casting method is used to produce ion conducting film where poly (methyl methacrylate) (PMMA) is used as the host polymer and potassium iodide (KI) as the dopant. The conductivity and amorphic increases of the polymer electrolytes with the addition of salt concentrations helps in the enhancement of the charge transfer properties. Using electrochemical impedance spectroscopy (EIS), ionic conductivity is evaluated where maximum conductivity is 3.99 × 10−6 S cm‐1 at 20 wt% KI concentration. Polarized optical microscopy (POM) shows the reduction in crystallinity by salt doping, while Fourier transforms infrared spectroscopy (FTIR) shows the complexation as well as composite nature of the film. Ionic transference number (tion) measurement shows the predominantly ionic nature of this polymer electrolyte.</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/masy.202300095</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Addition polymerization ; Charge transfer ; conductivity ; Electrochemical impedance spectroscopy ; Electrolytes ; Fourier transforms ; FTIR ; Infrared spectroscopy ; Ion currents ; Light microscopy ; Optical microscopy ; polymer electrolyte ; Polymers ; Polymethyl methacrylate ; Polymethylmethacrylate ; Potassium iodide ; Potassium iodides</subject><ispartof>Macromolecular symposia., 2024-02, Vol.413 (1), p.n/a</ispartof><rights>2024 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1875-ca89743607c1f950a1962b2e86000c095f96845317eadb487ae160afaa9fc8bf3</cites><orcidid>0000-0002-3155-6621 ; 0009-0004-0334-6426</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmasy.202300095$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmasy.202300095$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Singh, Ritika</creatorcontrib><creatorcontrib>Singh, Pramod K.</creatorcontrib><creatorcontrib>Pandey, Shri Prakash</creatorcontrib><creatorcontrib>Kakroo, Sunanda</creatorcontrib><creatorcontrib>Tripathi, Pankaj K.</creatorcontrib><creatorcontrib>Kumar, Rohit</creatorcontrib><creatorcontrib>Bajaj, Yashika</creatorcontrib><title>Electrical and Structural Properties of Poly (Methyl Methacrylate) Doped Potassium Iodide (KI) Solid Polymer Electrolyte</title><title>Macromolecular symposia.</title><description>A high‐conducting salt‐doped polymer electrolyte layer has been created here for use in photocell technologies. The solution casting method is used to produce ion conducting film where poly (methyl methacrylate) (PMMA) is used as the host polymer and potassium iodide (KI) as the dopant. The conductivity and amorphic increases of the polymer electrolytes with the addition of salt concentrations helps in the enhancement of the charge transfer properties. Using electrochemical impedance spectroscopy (EIS), ionic conductivity is evaluated where maximum conductivity is 3.99 × 10−6 S cm‐1 at 20 wt% KI concentration. Polarized optical microscopy (POM) shows the reduction in crystallinity by salt doping, while Fourier transforms infrared spectroscopy (FTIR) shows the complexation as well as composite nature of the film. Ionic transference number (tion) measurement shows the predominantly ionic nature of this polymer electrolyte.</description><subject>Addition polymerization</subject><subject>Charge transfer</subject><subject>conductivity</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrolytes</subject><subject>Fourier transforms</subject><subject>FTIR</subject><subject>Infrared spectroscopy</subject><subject>Ion currents</subject><subject>Light microscopy</subject><subject>Optical microscopy</subject><subject>polymer electrolyte</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Polymethylmethacrylate</subject><subject>Potassium iodide</subject><subject>Potassium iodides</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKtXzwEv7WFrku1-5Fhq1aLFQvXgKaTZBFOyTU2y6P57s67oUeYwM_C88_ECcInRBCNErmvu2wlBJEUI0ewIDHBGcJJShI5jjQhJcJqjU3Dm_a5DaIEH4HNhpAhOC24g31dwE1wjQuNiu3b2IF3Q0kOr4NqaFo5WMry1BnaJC9caHuQY3kSuikDg3uumhktb6UrC0cNyDDfW6OpbXEsH-2WxCfIcnChuvLz4yUPwcrt4nt8nj093y_nsMRG4LLJE8JIW03h3IbCiGeKY5mRLZJnHF0T8U9G8nGYpLiSvttOy4BLniCvOqRLlVqVDcNXPPTj73kgf2M42bh9XMkK7oDktIjXpKeGs904qdnC65q5lGLHOXda5y37djQLaCz60ke0_NFvNNq9_2i-iZn8C</recordid><startdate>202402</startdate><enddate>202402</enddate><creator>Singh, Ritika</creator><creator>Singh, Pramod K.</creator><creator>Pandey, Shri Prakash</creator><creator>Kakroo, Sunanda</creator><creator>Tripathi, Pankaj K.</creator><creator>Kumar, Rohit</creator><creator>Bajaj, Yashika</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3155-6621</orcidid><orcidid>https://orcid.org/0009-0004-0334-6426</orcidid></search><sort><creationdate>202402</creationdate><title>Electrical and Structural Properties of Poly (Methyl Methacrylate) Doped Potassium Iodide (KI) Solid Polymer Electrolyte</title><author>Singh, Ritika ; Singh, Pramod K. ; Pandey, Shri Prakash ; Kakroo, Sunanda ; Tripathi, Pankaj K. ; Kumar, Rohit ; Bajaj, Yashika</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1875-ca89743607c1f950a1962b2e86000c095f96845317eadb487ae160afaa9fc8bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Addition polymerization</topic><topic>Charge transfer</topic><topic>conductivity</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrolytes</topic><topic>Fourier transforms</topic><topic>FTIR</topic><topic>Infrared spectroscopy</topic><topic>Ion currents</topic><topic>Light microscopy</topic><topic>Optical microscopy</topic><topic>polymer electrolyte</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Polymethylmethacrylate</topic><topic>Potassium iodide</topic><topic>Potassium iodides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Ritika</creatorcontrib><creatorcontrib>Singh, Pramod K.</creatorcontrib><creatorcontrib>Pandey, Shri Prakash</creatorcontrib><creatorcontrib>Kakroo, Sunanda</creatorcontrib><creatorcontrib>Tripathi, Pankaj K.</creatorcontrib><creatorcontrib>Kumar, Rohit</creatorcontrib><creatorcontrib>Bajaj, Yashika</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Ritika</au><au>Singh, Pramod K.</au><au>Pandey, Shri Prakash</au><au>Kakroo, Sunanda</au><au>Tripathi, Pankaj K.</au><au>Kumar, Rohit</au><au>Bajaj, Yashika</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrical and Structural Properties of Poly (Methyl Methacrylate) Doped Potassium Iodide (KI) Solid Polymer Electrolyte</atitle><jtitle>Macromolecular symposia.</jtitle><date>2024-02</date><risdate>2024</risdate><volume>413</volume><issue>1</issue><epage>n/a</epage><issn>1022-1360</issn><eissn>1521-3900</eissn><abstract>A high‐conducting salt‐doped polymer electrolyte layer has been created here for use in photocell technologies. The solution casting method is used to produce ion conducting film where poly (methyl methacrylate) (PMMA) is used as the host polymer and potassium iodide (KI) as the dopant. The conductivity and amorphic increases of the polymer electrolytes with the addition of salt concentrations helps in the enhancement of the charge transfer properties. Using electrochemical impedance spectroscopy (EIS), ionic conductivity is evaluated where maximum conductivity is 3.99 × 10−6 S cm‐1 at 20 wt% KI concentration. Polarized optical microscopy (POM) shows the reduction in crystallinity by salt doping, while Fourier transforms infrared spectroscopy (FTIR) shows the complexation as well as composite nature of the film. Ionic transference number (tion) measurement shows the predominantly ionic nature of this polymer electrolyte.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/masy.202300095</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-3155-6621</orcidid><orcidid>https://orcid.org/0009-0004-0334-6426</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1360 |
| ispartof | Macromolecular symposia., 2024-02, Vol.413 (1), p.n/a |
| issn | 1022-1360 1521-3900 |
| language | eng |
| recordid | cdi_proquest_journals_2929299697 |
| source | Wiley Journals |
| subjects | Addition polymerization Charge transfer conductivity Electrochemical impedance spectroscopy Electrolytes Fourier transforms FTIR Infrared spectroscopy Ion currents Light microscopy Optical microscopy polymer electrolyte Polymers Polymethyl methacrylate Polymethylmethacrylate Potassium iodide Potassium iodides |
| title | Electrical and Structural Properties of Poly (Methyl Methacrylate) Doped Potassium Iodide (KI) Solid Polymer Electrolyte |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T02%3A58%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrical%20and%20Structural%20Properties%20of%20Poly%20(Methyl%20Methacrylate)%20Doped%20Potassium%20Iodide%20(KI)%20Solid%20Polymer%20Electrolyte&rft.jtitle=Macromolecular%20symposia.&rft.au=Singh,%20Ritika&rft.date=2024-02&rft.volume=413&rft.issue=1&rft.epage=n/a&rft.issn=1022-1360&rft.eissn=1521-3900&rft_id=info:doi/10.1002/masy.202300095&rft_dat=%3Cproquest_cross%3E2929299697%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2929299697&rft_id=info:pmid/&rfr_iscdi=true |