Development of Solution-Processed Eco-Friendly Cs2SnI6 Double Perovskite Thin-Film Solar Cell
This article reports a simple and efficient solution-processed method for designing stable Cs 2 SnI 6 double perovskite thin film solar cells utilizing Cesium iodide and SnI 4 in a 2:1 ratio. Better crystallinity in a Cs 2 SnI 6 film is typically associated with higher optical absorbance, lower carr...
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| creator | Jaiswal, Nilesh Singh, Vivek Pratap Singh, Chandra Prakash Punetha, Deepak Pandey, Saurabh Kumar |
| description | This article reports a simple and efficient solution-processed method for designing stable Cs 2 SnI 6 double perovskite thin film solar cells utilizing Cesium iodide and SnI 4 in a 2:1 ratio. Better crystallinity in a Cs 2 SnI 6 film is typically associated with higher optical absorbance, lower carrier concentration, more carrier mobility, and improved air and thermal stability. This compound contains Sn, which is in the 4+ oxidation state, which makes it significantly more robust against oxidation. The detailed synthetic difficulties in processing these compounds in solutions are the primary concern of this study. The solar cell parameters, structural, morphological, and, optical properties of prepared Cs 2 SnI 6 thin film were investigated using Netport Oriel12A solar simulator, thin film grazing incidence x-ray diffraction (GI-XRD), field emission scanning electron microscope, energy dispersive X-ray, and photoluminescence spectra (PL-Spectroscopy). Further, utilizing the synthesized Cs 2 SnI 6 thin films as an absorber material, we have fabricated n-i-p configured FTO/TiO 2 /Cs 2 SnI 6 /MoS 2 /Ni/glass in the ambient condition. The current study will also suggest future research directions for increasing the device performance of air-stable Cs 2 SnI 6 perovskite solar cells. |
| doi_str_mv | 10.1109/JPHOTOV.2023.3343559 |
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Better crystallinity in a Cs 2 SnI 6 film is typically associated with higher optical absorbance, lower carrier concentration, more carrier mobility, and improved air and thermal stability. This compound contains Sn, which is in the 4+ oxidation state, which makes it significantly more robust against oxidation. The detailed synthetic difficulties in processing these compounds in solutions are the primary concern of this study. The solar cell parameters, structural, morphological, and, optical properties of prepared Cs 2 SnI 6 thin film were investigated using Netport Oriel12A solar simulator, thin film grazing incidence x-ray diffraction (GI-XRD), field emission scanning electron microscope, energy dispersive X-ray, and photoluminescence spectra (PL-Spectroscopy). Further, utilizing the synthesized Cs 2 SnI 6 thin films as an absorber material, we have fabricated n-i-p configured FTO/TiO 2 /Cs 2 SnI 6 /MoS 2 /Ni/glass in the ambient condition. The current study will also suggest future research directions for increasing the device performance of air-stable Cs 2 SnI 6 perovskite solar cells.</description><identifier>ISSN: 2156-3381</identifier><identifier>EISSN: 2156-3403</identifier><identifier>DOI: 10.1109/JPHOTOV.2023.3343559</identifier><identifier>CODEN: IJPEG8</identifier><language>eng</language><publisher>Piscataway: IEEE</publisher><subject><![CDATA[Absorber ; Carrier density ; Carrier mobility ; Cesium ; Cesium iodides ; Cs<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _2</tex-math> </inline-formula> </named-content>SnI<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _6</tex-math> </inline-formula> </named-content> ; double perovskite ; Field emission microscopy ; morphological ; Morphology ; Optical properties ; Oxidation ; Perovskites ; Photoluminescence ; Photovoltaic cells ; Powders ; Solar cells ; solution-process ; Spectroscopy ; Spectrum analysis ; stable ; Thermal stability ; Thin films ; Titanium dioxide ; Valence]]></subject><ispartof>IEEE journal of photovoltaics, 2024-03, Vol.14 (2), p.265-271</ispartof><rights>Copyright The Institute of Electrical and Electronics Engineers, Inc. (IEEE) 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-4742-1043 ; 0000-0002-5013-6745 ; 0000-0002-5737-2900 ; 0009-0003-7861-730X ; 0000-0001-7206-6023</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/10376173$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>314,776,780,792,27901,27902,54733</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/10376173$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Jaiswal, Nilesh</creatorcontrib><creatorcontrib>Singh, Vivek Pratap</creatorcontrib><creatorcontrib>Singh, Chandra Prakash</creatorcontrib><creatorcontrib>Punetha, Deepak</creatorcontrib><creatorcontrib>Pandey, Saurabh Kumar</creatorcontrib><title>Development of Solution-Processed Eco-Friendly Cs2SnI6 Double Perovskite Thin-Film Solar Cell</title><title>IEEE journal of photovoltaics</title><addtitle>JPHOTOV</addtitle><description>This article reports a simple and efficient solution-processed method for designing stable Cs 2 SnI 6 double perovskite thin film solar cells utilizing Cesium iodide and SnI 4 in a 2:1 ratio. Better crystallinity in a Cs 2 SnI 6 film is typically associated with higher optical absorbance, lower carrier concentration, more carrier mobility, and improved air and thermal stability. This compound contains Sn, which is in the 4+ oxidation state, which makes it significantly more robust against oxidation. The detailed synthetic difficulties in processing these compounds in solutions are the primary concern of this study. The solar cell parameters, structural, morphological, and, optical properties of prepared Cs 2 SnI 6 thin film were investigated using Netport Oriel12A solar simulator, thin film grazing incidence x-ray diffraction (GI-XRD), field emission scanning electron microscope, energy dispersive X-ray, and photoluminescence spectra (PL-Spectroscopy). Further, utilizing the synthesized Cs 2 SnI 6 thin films as an absorber material, we have fabricated n-i-p configured FTO/TiO 2 /Cs 2 SnI 6 /MoS 2 /Ni/glass in the ambient condition. The current study will also suggest future research directions for increasing the device performance of air-stable Cs 2 SnI 6 perovskite solar cells.</description><subject>Absorber</subject><subject>Carrier density</subject><subject>Carrier mobility</subject><subject>Cesium</subject><subject>Cesium iodides</subject><subject><![CDATA[Cs<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _2</tex-math> </inline-formula> </named-content>SnI<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _6</tex-math> </inline-formula> </named-content>]]></subject><subject>double perovskite</subject><subject>Field emission microscopy</subject><subject>morphological</subject><subject>Morphology</subject><subject>Optical properties</subject><subject>Oxidation</subject><subject>Perovskites</subject><subject>Photoluminescence</subject><subject>Photovoltaic cells</subject><subject>Powders</subject><subject>Solar cells</subject><subject>solution-process</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>stable</subject><subject>Thermal stability</subject><subject>Thin films</subject><subject>Titanium dioxide</subject><subject>Valence</subject><issn>2156-3381</issn><issn>2156-3403</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNo1T1FrwjAYDGODifMf-BDYc12-pE3ax1F1OgQF3d5Gac1XFhcbl7SC_34dbncPdw_HHUfIGNgEgGVPr5vFerd-n3DGxUSIWCRJdkMGHBIZiZiJ238vUrgnoxAOrIdkiZTxgHxM8YzWnY7YtNTVdOts1xrXRBvv9hgCajrbu2juDTbaXmge-LZZSjp1XWWRbtC7c_gyLdLdp2miubHH347S0xytfSB3dWkDjv50SN7ms12-iFbrl2X-vIoMZ3EbcbavRIocFAIXcVZh3P9QGhTomisQjGleKaagTLCUoopTKaXO6lJXgKDFkDxee0_efXcY2uLgOt_0kwXPeiZppnifGl9TBhGLkzfH0l8KYEJJUEL8AAkCX00</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Jaiswal, Nilesh</creator><creator>Singh, Vivek Pratap</creator><creator>Singh, Chandra Prakash</creator><creator>Punetha, Deepak</creator><creator>Pandey, Saurabh Kumar</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. 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Better crystallinity in a Cs 2 SnI 6 film is typically associated with higher optical absorbance, lower carrier concentration, more carrier mobility, and improved air and thermal stability. This compound contains Sn, which is in the 4+ oxidation state, which makes it significantly more robust against oxidation. The detailed synthetic difficulties in processing these compounds in solutions are the primary concern of this study. The solar cell parameters, structural, morphological, and, optical properties of prepared Cs 2 SnI 6 thin film were investigated using Netport Oriel12A solar simulator, thin film grazing incidence x-ray diffraction (GI-XRD), field emission scanning electron microscope, energy dispersive X-ray, and photoluminescence spectra (PL-Spectroscopy). Further, utilizing the synthesized Cs 2 SnI 6 thin films as an absorber material, we have fabricated n-i-p configured FTO/TiO 2 /Cs 2 SnI 6 /MoS 2 /Ni/glass in the ambient condition. The current study will also suggest future research directions for increasing the device performance of air-stable Cs 2 SnI 6 perovskite solar cells.</abstract><cop>Piscataway</cop><pub>IEEE</pub><doi>10.1109/JPHOTOV.2023.3343559</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-4742-1043</orcidid><orcidid>https://orcid.org/0000-0002-5013-6745</orcidid><orcidid>https://orcid.org/0000-0002-5737-2900</orcidid><orcidid>https://orcid.org/0009-0003-7861-730X</orcidid><orcidid>https://orcid.org/0000-0001-7206-6023</orcidid></addata></record> |
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| subjects | Absorber Carrier density Carrier mobility Cesium Cesium iodides Cs<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _2</tex-math> </inline-formula> </named-content>SnI<named-content xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" content-type="math" xlink:type="simple"> <inline-formula> <tex-math notation="LaTeX"> _6</tex-math> </inline-formula> </named-content> double perovskite Field emission microscopy morphological Morphology Optical properties Oxidation Perovskites Photoluminescence Photovoltaic cells Powders Solar cells solution-process Spectroscopy Spectrum analysis stable Thermal stability Thin films Titanium dioxide Valence |
| title | Development of Solution-Processed Eco-Friendly Cs2SnI6 Double Perovskite Thin-Film Solar Cell |
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