Study of biomaterial electrolyte based on Peltophorum pterocarpum incorporated with NH4SCN for proton-conducting battery and PEM fuel cell applications
A novel development of biomaterial membrane based on Peltophorum pterocarpum— a flower with various concentrations of ammonium thiocyanate (NH 4 SCN)—is prepared with distilled water as a solvent by using solution casting technique. The prepared membranes are subjected to different characterization...
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| Veröffentlicht in: | Ionics 2024-02, Vol.30 (2), p.913-927 |
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| creator | Muthuselvi, P. Mohanaa Chandra, M. V. Leena Selvasekarapandian, S. Hazaana, S. Aafrin Vignesh, N. Muniraj Naachiyar, R. Meera Babu, M. Kani Ajay |
| description | A novel development of biomaterial membrane based on
Peltophorum pterocarpum—
a flower with various concentrations of ammonium thiocyanate (NH
4
SCN)—is prepared with distilled water as a solvent by using solution casting technique. The prepared membranes are subjected to different characterization techniques such as X-ray diffraction analysis, differential scanning calorimetry, AC impedance analysis, transference number measurement, and linear sweep voltammetry. The crystalline/amorphous nature of the prepared biomaterial membrane is studied by using XRD. The
T
g
values of the prepared membranes are analyzed using differential scanning calorimetry. The highest ionic conductivity is found to be 2.19 × 10
−2
S/cm for 1 g PP with 0.7 M wt% NH
4
SCN by AC impedance analysis. The highest ion-conducting biomaterial membrane of 1 g
Peltophorum pterocarpum
with 0.7 M wt% NH
4
SCN is observed with an electrochemical stability of 2.00 V from LSV. Primary proton battery and proton exchange membrane (PEM) fuel cell are fabricated using the highest ion-conducting biomaterial membrane. The open-circuit voltage (OCV) of primary proton battery is observed to be 1.57 V, and its performance is studied. A single fuel cell is constructed, which exhibits a cell potential of 487 mV. |
| doi_str_mv | 10.1007/s11581-023-05286-3 |
| format | Article |
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Peltophorum pterocarpum—
a flower with various concentrations of ammonium thiocyanate (NH
4
SCN)—is prepared with distilled water as a solvent by using solution casting technique. The prepared membranes are subjected to different characterization techniques such as X-ray diffraction analysis, differential scanning calorimetry, AC impedance analysis, transference number measurement, and linear sweep voltammetry. The crystalline/amorphous nature of the prepared biomaterial membrane is studied by using XRD. The
T
g
values of the prepared membranes are analyzed using differential scanning calorimetry. The highest ionic conductivity is found to be 2.19 × 10
−2
S/cm for 1 g PP with 0.7 M wt% NH
4
SCN by AC impedance analysis. The highest ion-conducting biomaterial membrane of 1 g
Peltophorum pterocarpum
with 0.7 M wt% NH
4
SCN is observed with an electrochemical stability of 2.00 V from LSV. Primary proton battery and proton exchange membrane (PEM) fuel cell are fabricated using the highest ion-conducting biomaterial membrane. The open-circuit voltage (OCV) of primary proton battery is observed to be 1.57 V, and its performance is studied. A single fuel cell is constructed, which exhibits a cell potential of 487 mV.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-023-05286-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Batteries ; Biomedical materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Differential scanning calorimetry ; Distilled water ; Electrochemistry ; Energy Storage ; Fuel cells ; Heat measurement ; Impedance ; Ion currents ; Open circuit voltage ; Optical and Electronic Materials ; Proton exchange membrane fuel cells ; Protons ; Renewable and Green Energy ; Thiocyanates</subject><ispartof>Ionics, 2024-02, Vol.30 (2), p.913-927</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-4d984a516061b863551e1b739e44fa82241b4d6af4d038db48a6a52059e5fcd13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-023-05286-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-023-05286-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Muthuselvi, P. Mohanaa</creatorcontrib><creatorcontrib>Chandra, M. V. Leena</creatorcontrib><creatorcontrib>Selvasekarapandian, S.</creatorcontrib><creatorcontrib>Hazaana, S. Aafrin</creatorcontrib><creatorcontrib>Vignesh, N. Muniraj</creatorcontrib><creatorcontrib>Naachiyar, R. Meera</creatorcontrib><creatorcontrib>Babu, M. Kani Ajay</creatorcontrib><title>Study of biomaterial electrolyte based on Peltophorum pterocarpum incorporated with NH4SCN for proton-conducting battery and PEM fuel cell applications</title><title>Ionics</title><addtitle>Ionics</addtitle><description>A novel development of biomaterial membrane based on
Peltophorum pterocarpum—
a flower with various concentrations of ammonium thiocyanate (NH
4
SCN)—is prepared with distilled water as a solvent by using solution casting technique. The prepared membranes are subjected to different characterization techniques such as X-ray diffraction analysis, differential scanning calorimetry, AC impedance analysis, transference number measurement, and linear sweep voltammetry. The crystalline/amorphous nature of the prepared biomaterial membrane is studied by using XRD. The
T
g
values of the prepared membranes are analyzed using differential scanning calorimetry. The highest ionic conductivity is found to be 2.19 × 10
−2
S/cm for 1 g PP with 0.7 M wt% NH
4
SCN by AC impedance analysis. The highest ion-conducting biomaterial membrane of 1 g
Peltophorum pterocarpum
with 0.7 M wt% NH
4
SCN is observed with an electrochemical stability of 2.00 V from LSV. Primary proton battery and proton exchange membrane (PEM) fuel cell are fabricated using the highest ion-conducting biomaterial membrane. The open-circuit voltage (OCV) of primary proton battery is observed to be 1.57 V, and its performance is studied. A single fuel cell is constructed, which exhibits a cell potential of 487 mV.</description><subject>Batteries</subject><subject>Biomedical materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Differential scanning calorimetry</subject><subject>Distilled water</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Fuel cells</subject><subject>Heat measurement</subject><subject>Impedance</subject><subject>Ion currents</subject><subject>Open circuit voltage</subject><subject>Optical and Electronic Materials</subject><subject>Proton exchange membrane fuel cells</subject><subject>Protons</subject><subject>Renewable and Green Energy</subject><subject>Thiocyanates</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kctOxCAUhonRxPHyAq5IXKMHSmm7NBNvibdEXRMKVGsYqEBj5kl8XdExceeKs_i__5DzIXRE4YQCNKeJ0rqlBFhFoGatINUWWtBWMAKNgG20gI43pAHe7KK9lN4AhKCsWaDPxzybNQ4D7sewUtnGUTlsndU5BrfOFvcqWYODxw_W5TC9hjiv8FSCQas4lXn0OsQpxAIb_DHmV3x3xR-Xd3gIEU8x5OCJDt7MOo_-pfTlAq-x8gY_nN_iYbYOa-scVtPkRq3yGHw6QDuDcske_r776Pni_Gl5RW7uL6-XZzdEswYy4aZruaqpAEH7VlR1TS3tm6qznA-qZYzTnhuhBm6gak3PWyVUzaDubD1oQ6t9dLzpLR99n23K8i3M0ZeVknXlkJQB8JJim5SOIaVoBznFcaXiWlKQ3wLkRoAsAuSPAFkVqNpAqYT9i41_1f9QX5ufi0g</recordid><startdate>20240201</startdate><enddate>20240201</enddate><creator>Muthuselvi, P. Mohanaa</creator><creator>Chandra, M. V. Leena</creator><creator>Selvasekarapandian, S.</creator><creator>Hazaana, S. Aafrin</creator><creator>Vignesh, N. Muniraj</creator><creator>Naachiyar, R. Meera</creator><creator>Babu, M. Kani Ajay</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240201</creationdate><title>Study of biomaterial electrolyte based on Peltophorum pterocarpum incorporated with NH4SCN for proton-conducting battery and PEM fuel cell applications</title><author>Muthuselvi, P. Mohanaa ; Chandra, M. V. Leena ; Selvasekarapandian, S. ; Hazaana, S. Aafrin ; Vignesh, N. Muniraj ; Naachiyar, R. Meera ; Babu, M. Kani Ajay</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-4d984a516061b863551e1b739e44fa82241b4d6af4d038db48a6a52059e5fcd13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Batteries</topic><topic>Biomedical materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Differential scanning calorimetry</topic><topic>Distilled water</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Fuel cells</topic><topic>Heat measurement</topic><topic>Impedance</topic><topic>Ion currents</topic><topic>Open circuit voltage</topic><topic>Optical and Electronic Materials</topic><topic>Proton exchange membrane fuel cells</topic><topic>Protons</topic><topic>Renewable and Green Energy</topic><topic>Thiocyanates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Muthuselvi, P. Mohanaa</creatorcontrib><creatorcontrib>Chandra, M. V. Leena</creatorcontrib><creatorcontrib>Selvasekarapandian, S.</creatorcontrib><creatorcontrib>Hazaana, S. Aafrin</creatorcontrib><creatorcontrib>Vignesh, N. Muniraj</creatorcontrib><creatorcontrib>Naachiyar, R. Meera</creatorcontrib><creatorcontrib>Babu, M. Kani Ajay</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Muthuselvi, P. Mohanaa</au><au>Chandra, M. V. Leena</au><au>Selvasekarapandian, S.</au><au>Hazaana, S. Aafrin</au><au>Vignesh, N. Muniraj</au><au>Naachiyar, R. Meera</au><au>Babu, M. Kani Ajay</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of biomaterial electrolyte based on Peltophorum pterocarpum incorporated with NH4SCN for proton-conducting battery and PEM fuel cell applications</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2024-02-01</date><risdate>2024</risdate><volume>30</volume><issue>2</issue><spage>913</spage><epage>927</epage><pages>913-927</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>A novel development of biomaterial membrane based on
Peltophorum pterocarpum—
a flower with various concentrations of ammonium thiocyanate (NH
4
SCN)—is prepared with distilled water as a solvent by using solution casting technique. The prepared membranes are subjected to different characterization techniques such as X-ray diffraction analysis, differential scanning calorimetry, AC impedance analysis, transference number measurement, and linear sweep voltammetry. The crystalline/amorphous nature of the prepared biomaterial membrane is studied by using XRD. The
T
g
values of the prepared membranes are analyzed using differential scanning calorimetry. The highest ionic conductivity is found to be 2.19 × 10
−2
S/cm for 1 g PP with 0.7 M wt% NH
4
SCN by AC impedance analysis. The highest ion-conducting biomaterial membrane of 1 g
Peltophorum pterocarpum
with 0.7 M wt% NH
4
SCN is observed with an electrochemical stability of 2.00 V from LSV. Primary proton battery and proton exchange membrane (PEM) fuel cell are fabricated using the highest ion-conducting biomaterial membrane. The open-circuit voltage (OCV) of primary proton battery is observed to be 1.57 V, and its performance is studied. A single fuel cell is constructed, which exhibits a cell potential of 487 mV.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-023-05286-3</doi><tpages>15</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-7047 |
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| source | SpringerNature Journals |
| subjects | Batteries Biomedical materials Chemistry Chemistry and Materials Science Condensed Matter Physics Differential scanning calorimetry Distilled water Electrochemistry Energy Storage Fuel cells Heat measurement Impedance Ion currents Open circuit voltage Optical and Electronic Materials Proton exchange membrane fuel cells Protons Renewable and Green Energy Thiocyanates |
| title | Study of biomaterial electrolyte based on Peltophorum pterocarpum incorporated with NH4SCN for proton-conducting battery and PEM fuel cell applications |
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