Preparation and performance of hexacyanoferrate impregnated cotton pads for 137Cs analysis in seawater

An anthropogenic radionuclide 137Cs always be a concern because very easy to spread in the air and dissolves in water. The small concentration of 137Cs in aquatic environments motivated us to develop methods for reducing sample volume and increasing detection levels. Impregnated hexacyanoferrate fil...

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Veröffentlicht in:AIP conference proceedings 2024-02, Vol.2967 (1)
Hauptverfasser: Yahya, M. N., Makmur, M., Prihatiningsih, W. R., Putra, D. I. Permana, Priasetyono, Y., Suseno, H., Sudarmadji, A.
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container_title AIP conference proceedings
container_volume 2967
creator Yahya, M. N.
Makmur, M.
Prihatiningsih, W. R.
Putra, D. I. Permana
Priasetyono, Y.
Suseno, H.
Sudarmadji, A.
description An anthropogenic radionuclide 137Cs always be a concern because very easy to spread in the air and dissolves in water. The small concentration of 137Cs in aquatic environments motivated us to develop methods for reducing sample volume and increasing detection levels. Impregnated hexacyanoferrate filters are very convenient to be used in various places because they do not require chemical preparation. Based on previous research, the impregnated processes were performed by circulating solution into filter water for a certain time. Since that impregnated filter was not perfectly coated on the surface filter, sampling procedure was conducted using a pair of impregnated filters to determine the collected efficiency. Furthermore, in this paper, an experiment was carried out by modifying the filter using impregnated hexacyanoferrate cotton pad. Visualization using SEM has been carried out, to ensure cotton pad completely impregnated by hexacyanoferrates. Furthermore, absorption performance was carried out using a tracer 137Cs in a low level activity concentration. The result of this experiment indicates impregnation processes on cotton pad perfectly covered surface and penetrated into inner layer although was only effective in water samples with a pH
doi_str_mv 10.1063/5.0192971
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N. ; Makmur, M. ; Prihatiningsih, W. R. ; Putra, D. I. Permana ; Priasetyono, Y. ; Suseno, H. ; Sudarmadji, A.</creator><contributor>Wisnubroto, Djarot Sulistio ; Syaifudin, Mukh ; Antariksawan, Anhar Riza ; Santoso, Muhayatun ; Yusuf, Muhammad ; Mulyani, Emy</contributor><creatorcontrib>Yahya, M. N. ; Makmur, M. ; Prihatiningsih, W. R. ; Putra, D. I. Permana ; Priasetyono, Y. ; Suseno, H. ; Sudarmadji, A. ; Wisnubroto, Djarot Sulistio ; Syaifudin, Mukh ; Antariksawan, Anhar Riza ; Santoso, Muhayatun ; Yusuf, Muhammad ; Mulyani, Emy</creatorcontrib><description>An anthropogenic radionuclide 137Cs always be a concern because very easy to spread in the air and dissolves in water. The small concentration of 137Cs in aquatic environments motivated us to develop methods for reducing sample volume and increasing detection levels. Impregnated hexacyanoferrate filters are very convenient to be used in various places because they do not require chemical preparation. Based on previous research, the impregnated processes were performed by circulating solution into filter water for a certain time. Since that impregnated filter was not perfectly coated on the surface filter, sampling procedure was conducted using a pair of impregnated filters to determine the collected efficiency. Furthermore, in this paper, an experiment was carried out by modifying the filter using impregnated hexacyanoferrate cotton pad. Visualization using SEM has been carried out, to ensure cotton pad completely impregnated by hexacyanoferrates. Furthermore, absorption performance was carried out using a tracer 137Cs in a low level activity concentration. The result of this experiment indicates impregnation processes on cotton pad perfectly covered surface and penetrated into inner layer although was only effective in water samples with a pH &lt;9. Meanwhile the hexacyanoferrate was not affected by temperature dependence but influence by sampling duration. Additionally, 65% of total activity 137Cs had been adsorbed on the first layer and dropped drastically on second layer until 9 layers. This method can perform on single hexacyanoferrate impregnated cotton pad cartridge filter and had been tested using natural seawater.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/5.0192971</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Aquatic environment ; Cesium 137 ; Cesium isotopes ; Cotton ; Human influences ; Low level ; Radioisotopes ; Seawater ; Temperature dependence ; Water circulation ; Water purification ; Water sampling</subject><ispartof>AIP conference proceedings, 2024-02, Vol.2967 (1)</ispartof><rights>Author(s)</rights><rights>2024 Author(s). 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Since that impregnated filter was not perfectly coated on the surface filter, sampling procedure was conducted using a pair of impregnated filters to determine the collected efficiency. Furthermore, in this paper, an experiment was carried out by modifying the filter using impregnated hexacyanoferrate cotton pad. Visualization using SEM has been carried out, to ensure cotton pad completely impregnated by hexacyanoferrates. Furthermore, absorption performance was carried out using a tracer 137Cs in a low level activity concentration. The result of this experiment indicates impregnation processes on cotton pad perfectly covered surface and penetrated into inner layer although was only effective in water samples with a pH &lt;9. Meanwhile the hexacyanoferrate was not affected by temperature dependence but influence by sampling duration. Additionally, 65% of total activity 137Cs had been adsorbed on the first layer and dropped drastically on second layer until 9 layers. 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Permana</au><au>Priasetyono, Y.</au><au>Suseno, H.</au><au>Sudarmadji, A.</au><au>Wisnubroto, Djarot Sulistio</au><au>Syaifudin, Mukh</au><au>Antariksawan, Anhar Riza</au><au>Santoso, Muhayatun</au><au>Yusuf, Muhammad</au><au>Mulyani, Emy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and performance of hexacyanoferrate impregnated cotton pads for 137Cs analysis in seawater</atitle><jtitle>AIP conference proceedings</jtitle><date>2024-02-15</date><risdate>2024</risdate><volume>2967</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>An anthropogenic radionuclide 137Cs always be a concern because very easy to spread in the air and dissolves in water. The small concentration of 137Cs in aquatic environments motivated us to develop methods for reducing sample volume and increasing detection levels. Impregnated hexacyanoferrate filters are very convenient to be used in various places because they do not require chemical preparation. Based on previous research, the impregnated processes were performed by circulating solution into filter water for a certain time. Since that impregnated filter was not perfectly coated on the surface filter, sampling procedure was conducted using a pair of impregnated filters to determine the collected efficiency. Furthermore, in this paper, an experiment was carried out by modifying the filter using impregnated hexacyanoferrate cotton pad. Visualization using SEM has been carried out, to ensure cotton pad completely impregnated by hexacyanoferrates. Furthermore, absorption performance was carried out using a tracer 137Cs in a low level activity concentration. 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subjects Aquatic environment
Cesium 137
Cesium isotopes
Cotton
Human influences
Low level
Radioisotopes
Seawater
Temperature dependence
Water circulation
Water purification
Water sampling
title Preparation and performance of hexacyanoferrate impregnated cotton pads for 137Cs analysis in seawater
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