Preparation, Characterization, and Biological Activity of Mixed Schiff Base Ligand Complexes with Amino Acid L-Proline
The present study involves the synthesis and characterization of complexes of [Cr(III), Fe(III), Co(II), and Ni(II)] with Schiff base and L-proline using 4-dimethylaminobenzaldehyde and 4-aminoantipyrine as reactants. The complexes were characterized using various spectroscopic techniques such as in...
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| Veröffentlicht in: | Russian journal of general chemistry 2023-12, Vol.93 (Suppl 4), p.S1016-S1025 |
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| container_issue | Suppl 4 |
| container_start_page | S1016 |
| container_title | Russian journal of general chemistry |
| container_volume | 93 |
| creator | Majeed, N. M. Obaid, S. M. H. Raheema, M. H. Al-Noor, T. H. Al-Ayash, S. R. Abdou, A. |
| description | The present study involves the synthesis and characterization of complexes of [Cr(III), Fe(III), Co(II), and Ni(II)] with Schiff base and L-proline using 4-dimethylaminobenzaldehyde and 4-aminoantipyrine as reactants. The complexes were characterized using various spectroscopic techniques such as infrared and UV-Vis spectroscopy, mass spectrometry, melting point and conductivity measurements. The formulated complexes are [M(L)(Pro)
2
]Cl, where M = Fe(III),Cr(III), and [M(L)(Pro)
2
], where M = Co(II), Ni(II). The ligands Schiff base and L-proline were found to act as bidentate chelating agents. L-Proline coordinates with the amine group’s carboxyl group and nitrogen atom, while Schiff base coordinates through the nitrogen and oxygen atoms. The complexes have been assigned an octahedral geometry based on electronic spectral and magnetic moment studies. Furthermore, the results of the biological activity of the complexes and ligands showed good results against gram-positive and gram-negative bacteria. |
| doi_str_mv | 10.1134/S1070363223170176 |
| format | Article |
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2
]Cl, where M = Fe(III),Cr(III), and [M(L)(Pro)
2
], where M = Co(II), Ni(II). The ligands Schiff base and L-proline were found to act as bidentate chelating agents. L-Proline coordinates with the amine group’s carboxyl group and nitrogen atom, while Schiff base coordinates through the nitrogen and oxygen atoms. The complexes have been assigned an octahedral geometry based on electronic spectral and magnetic moment studies. Furthermore, the results of the biological activity of the complexes and ligands showed good results against gram-positive and gram-negative bacteria.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363223170176</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Amines ; Amino acids ; Biological activity ; Biological effects ; Carboxyl group ; Chelating agents ; Chelation ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Cobalt ; Imines ; Infrared spectroscopy ; Iron ; Ligands ; Magnetic moments ; Mass spectrometry ; Melting points ; Nitrogen ; Oxygen atoms ; Proline ; Schiff bases ; Spectrum analysis ; Trivalent chromium</subject><ispartof>Russian journal of general chemistry, 2023-12, Vol.93 (Suppl 4), p.S1016-S1025</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>COPYRIGHT 2023 Springer</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-8e1a4e3d9e9114ab841ddb44c1afe3e7d9edb9e5210a27451d4e193f6dc0fbf13</citedby><cites>FETCH-LOGICAL-c355t-8e1a4e3d9e9114ab841ddb44c1afe3e7d9edb9e5210a27451d4e193f6dc0fbf13</cites><orcidid>0000-0002-6761-7131 ; 0000-0003-2203-9902 ; 0000-0002-5979-2650 ; 0009-0002-5632-690X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363223170176$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363223170176$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Majeed, N. M.</creatorcontrib><creatorcontrib>Obaid, S. M. H.</creatorcontrib><creatorcontrib>Raheema, M. H.</creatorcontrib><creatorcontrib>Al-Noor, T. H.</creatorcontrib><creatorcontrib>Al-Ayash, S. R.</creatorcontrib><creatorcontrib>Abdou, A.</creatorcontrib><title>Preparation, Characterization, and Biological Activity of Mixed Schiff Base Ligand Complexes with Amino Acid L-Proline</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The present study involves the synthesis and characterization of complexes of [Cr(III), Fe(III), Co(II), and Ni(II)] with Schiff base and L-proline using 4-dimethylaminobenzaldehyde and 4-aminoantipyrine as reactants. The complexes were characterized using various spectroscopic techniques such as infrared and UV-Vis spectroscopy, mass spectrometry, melting point and conductivity measurements. The formulated complexes are [M(L)(Pro)
2
]Cl, where M = Fe(III),Cr(III), and [M(L)(Pro)
2
], where M = Co(II), Ni(II). The ligands Schiff base and L-proline were found to act as bidentate chelating agents. L-Proline coordinates with the amine group’s carboxyl group and nitrogen atom, while Schiff base coordinates through the nitrogen and oxygen atoms. The complexes have been assigned an octahedral geometry based on electronic spectral and magnetic moment studies. Furthermore, the results of the biological activity of the complexes and ligands showed good results against gram-positive and gram-negative bacteria.</description><subject>Amines</subject><subject>Amino acids</subject><subject>Biological activity</subject><subject>Biological effects</subject><subject>Carboxyl group</subject><subject>Chelating agents</subject><subject>Chelation</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Cobalt</subject><subject>Imines</subject><subject>Infrared spectroscopy</subject><subject>Iron</subject><subject>Ligands</subject><subject>Magnetic moments</subject><subject>Mass spectrometry</subject><subject>Melting points</subject><subject>Nitrogen</subject><subject>Oxygen atoms</subject><subject>Proline</subject><subject>Schiff bases</subject><subject>Spectrum analysis</subject><subject>Trivalent chromium</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kVtLAzEQhRdR8PoDfAv46momyd4ea_EGFQX1eUmTSTuy3dRk1eqvN6WCDyJ5yHDO-WZCJsuOgZ8BSHX-CLzispRCSKg4VOVWtgclr3MpC76d6mTna38324_xhXPgvBR72ftDwKUOeiDfn7LxPJVmwEBfP4ruLbsg3_kZGd2xkRnonYZP5h27oxVa9mjm5By70BHZhGbr_Ngvlh2uMLIPGuZstKDeJ5Ism-QPwXfU42G243QX8ejnPsiery6fxjf55P76djya5EYWxZDXCFqhtA02AEpPawXWTpUyoB1KrJJhpw0WArgWlSrAKoRGutIa7qYO5EF2sum7DP71DePQvvi30KeRrWhEWQJXok6ps01qpjtsqXd-SN-QjsUFGd-jo6SPqloUVcNlkwDYACb4GAO6dhloocNnC7xd76P9s4_EiA0TU7afYfh9yv_QN9z9jHA</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Majeed, N. M.</creator><creator>Obaid, S. M. H.</creator><creator>Raheema, M. H.</creator><creator>Al-Noor, T. H.</creator><creator>Al-Ayash, S. R.</creator><creator>Abdou, A.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6761-7131</orcidid><orcidid>https://orcid.org/0000-0003-2203-9902</orcidid><orcidid>https://orcid.org/0000-0002-5979-2650</orcidid><orcidid>https://orcid.org/0009-0002-5632-690X</orcidid></search><sort><creationdate>20231201</creationdate><title>Preparation, Characterization, and Biological Activity of Mixed Schiff Base Ligand Complexes with Amino Acid L-Proline</title><author>Majeed, N. M. ; Obaid, S. M. H. ; Raheema, M. H. ; Al-Noor, T. H. ; Al-Ayash, S. R. ; Abdou, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-8e1a4e3d9e9114ab841ddb44c1afe3e7d9edb9e5210a27451d4e193f6dc0fbf13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Amines</topic><topic>Amino acids</topic><topic>Biological activity</topic><topic>Biological effects</topic><topic>Carboxyl group</topic><topic>Chelating agents</topic><topic>Chelation</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Cobalt</topic><topic>Imines</topic><topic>Infrared spectroscopy</topic><topic>Iron</topic><topic>Ligands</topic><topic>Magnetic moments</topic><topic>Mass spectrometry</topic><topic>Melting points</topic><topic>Nitrogen</topic><topic>Oxygen atoms</topic><topic>Proline</topic><topic>Schiff bases</topic><topic>Spectrum analysis</topic><topic>Trivalent chromium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Majeed, N. M.</creatorcontrib><creatorcontrib>Obaid, S. M. H.</creatorcontrib><creatorcontrib>Raheema, M. H.</creatorcontrib><creatorcontrib>Al-Noor, T. H.</creatorcontrib><creatorcontrib>Al-Ayash, S. R.</creatorcontrib><creatorcontrib>Abdou, A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Majeed, N. M.</au><au>Obaid, S. M. H.</au><au>Raheema, M. H.</au><au>Al-Noor, T. H.</au><au>Al-Ayash, S. R.</au><au>Abdou, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation, Characterization, and Biological Activity of Mixed Schiff Base Ligand Complexes with Amino Acid L-Proline</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>93</volume><issue>Suppl 4</issue><spage>S1016</spage><epage>S1025</epage><pages>S1016-S1025</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The present study involves the synthesis and characterization of complexes of [Cr(III), Fe(III), Co(II), and Ni(II)] with Schiff base and L-proline using 4-dimethylaminobenzaldehyde and 4-aminoantipyrine as reactants. The complexes were characterized using various spectroscopic techniques such as infrared and UV-Vis spectroscopy, mass spectrometry, melting point and conductivity measurements. The formulated complexes are [M(L)(Pro)
2
]Cl, where M = Fe(III),Cr(III), and [M(L)(Pro)
2
], where M = Co(II), Ni(II). The ligands Schiff base and L-proline were found to act as bidentate chelating agents. L-Proline coordinates with the amine group’s carboxyl group and nitrogen atom, while Schiff base coordinates through the nitrogen and oxygen atoms. The complexes have been assigned an octahedral geometry based on electronic spectral and magnetic moment studies. Furthermore, the results of the biological activity of the complexes and ligands showed good results against gram-positive and gram-negative bacteria.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363223170176</doi><orcidid>https://orcid.org/0000-0002-6761-7131</orcidid><orcidid>https://orcid.org/0000-0003-2203-9902</orcidid><orcidid>https://orcid.org/0000-0002-5979-2650</orcidid><orcidid>https://orcid.org/0009-0002-5632-690X</orcidid></addata></record> |
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| subjects | Amines Amino acids Biological activity Biological effects Carboxyl group Chelating agents Chelation Chemical properties Chemistry Chemistry and Materials Science Chemistry/Food Science Cobalt Imines Infrared spectroscopy Iron Ligands Magnetic moments Mass spectrometry Melting points Nitrogen Oxygen atoms Proline Schiff bases Spectrum analysis Trivalent chromium |
| title | Preparation, Characterization, and Biological Activity of Mixed Schiff Base Ligand Complexes with Amino Acid L-Proline |
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