ATRP catalysts of tetradentate guanidine ligands - do guanidine donors induce a faster atom transfer?

Tripodal tetradentate N donor ligands stabilise the most active ATRP catalyst systems. Here, we set out to synthesise the new guanidine ligand TMG-4NMe 2 uns-penp, inspired by p -substituted tris(2-pyridylmethyl)amine (TPMA) ligands. The impact of changing pyridine against guanidine donors was exami...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-02, Vol.53 (7), p.2973-299
Hauptverfasser:	Kröckert, Konstantin W, Garg, Felix, Heck, Joshua, Heinz, Michel V, Lange, Justin, Schmidt, Regina, Hoffmann, Alexander, Herres-Pawlis, Sonja
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Catalytic activity Copper Copper compounds Deactivation Density functional theory Ligands Mathematical analysis Molecular structure NMR spectroscopy Pyridines Solid state
Online-Zugang:	Volltext
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