Potential perspectives on the use of poly (vinyl alcohol)/graphene oxide nanocomposite films and its characterization

The aim of this work was to investigate the effect of graphene oxide (GO) nanoparticles on the physicochemical, mechanical, thermal, and biodegradation properties of Polyvinyl alcohol (PVA) films. PVA-based nanocomposite (NC) films were fabricated using solution casting technique by adding a low con...

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Veröffentlicht in:Journal of food measurement & characterization 2024-02, Vol.18 (2), p.1012-1025
Hauptverfasser: Kapila, Karanjit, Kirtania, Sushen, Devi, Lourembam Monika, Saikumar, Akuleti, Badwaik, Laxmikant S, Rather, Muzamil A
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container_issue 2
container_start_page 1012
container_title Journal of food measurement & characterization
container_volume 18
creator Kapila, Karanjit
Kirtania, Sushen
Devi, Lourembam Monika
Saikumar, Akuleti
Badwaik, Laxmikant S
Rather, Muzamil A
description The aim of this work was to investigate the effect of graphene oxide (GO) nanoparticles on the physicochemical, mechanical, thermal, and biodegradation properties of Polyvinyl alcohol (PVA) films. PVA-based nanocomposite (NC) films were fabricated using solution casting technique by adding a low concentration of GO from 0.1 to 0.7%. The tensile strength of the NC films was increased by the addition of GO from 1.40 ± 0.02 MPa to 1.99 ± 0.02 MPa. However, the elongation at break of the NC film was enhanced from 201.02 ± 5.10 to 268.64 ± 5.83% at 0.1–0.3% concentration of GO, and it was decreased with further addition of GO. A considerable improvement in the water vapor permeability was observed at 0.3–0.5% GO, with a value of 6.76 ± 0.06 × 10 − 5 to 6.69 ± 0.08 × 10 − 5 (g/m.hr. Pa) with respect to neat PVA 8.16 ± 0.08 × 10 − 5 (g/m.hr. Pa). Additionally, the use of GO also led to an enhancement in moisture retention capacity, with values ranging from 80.08 to 82.06%. Differential scanning calorimetry (DSC) result revealed a rise in glass transition temperature i.e. 95.62 °C, and maximum enthalpy 50.28 (J/g) at 0.3% GO. Moreover, thermogravimetric analysis (TGA) studies also showed less mass degradation for Poly (vinyl alcohol)/graphene oxide ( PVA/GO) films at higher temperatures compared to PVA film. From scanning electron microscope (SEM) micrographs, minimum surface defects, homogenized mixing, and less agglomeration in the PVA/GO film was observed. This observation was further supported by Fourier-transform infrared spectroscopy (FTIR) data, which indicated a strong hydrogen bonding between the functional groups of GO and PVA polymer chains. Furthermore, the NC films exhibited an effective antibacterial activity against Staphylococcus aureus (gram-positive bacteria). Adversely, there was no inhibition zone observed in neat PVA and its NC films against Escherichia coli (gram-negative bacteria). The incorporation of GO nanofillers was found to reduce the rate of biodegradation of the NC films, as determined in soil burial study. However, improved microorganism degradation was observed in both Bacillus subtilis and Pseudomonas putida bacteria strains. Overall, the acquired results validate the use of GO as an excellent option for the fabrication of biodegradable nanocomposite films that may be used for packaging applications.
doi_str_mv 10.1007/s11694-023-02264-1
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PVA-based nanocomposite (NC) films were fabricated using solution casting technique by adding a low concentration of GO from 0.1 to 0.7%. The tensile strength of the NC films was increased by the addition of GO from 1.40 ± 0.02 MPa to 1.99 ± 0.02 MPa. However, the elongation at break of the NC film was enhanced from 201.02 ± 5.10 to 268.64 ± 5.83% at 0.1–0.3% concentration of GO, and it was decreased with further addition of GO. A considerable improvement in the water vapor permeability was observed at 0.3–0.5% GO, with a value of 6.76 ± 0.06 × 10 − 5 to 6.69 ± 0.08 × 10 − 5 (g/m.hr. Pa) with respect to neat PVA 8.16 ± 0.08 × 10 − 5 (g/m.hr. Pa). Additionally, the use of GO also led to an enhancement in moisture retention capacity, with values ranging from 80.08 to 82.06%. Differential scanning calorimetry (DSC) result revealed a rise in glass transition temperature i.e. 95.62 °C, and maximum enthalpy 50.28 (J/g) at 0.3% GO. Moreover, thermogravimetric analysis (TGA) studies also showed less mass degradation for Poly (vinyl alcohol)/graphene oxide ( PVA/GO) films at higher temperatures compared to PVA film. From scanning electron microscope (SEM) micrographs, minimum surface defects, homogenized mixing, and less agglomeration in the PVA/GO film was observed. This observation was further supported by Fourier-transform infrared spectroscopy (FTIR) data, which indicated a strong hydrogen bonding between the functional groups of GO and PVA polymer chains. Furthermore, the NC films exhibited an effective antibacterial activity against Staphylococcus aureus (gram-positive bacteria). Adversely, there was no inhibition zone observed in neat PVA and its NC films against Escherichia coli (gram-negative bacteria). The incorporation of GO nanofillers was found to reduce the rate of biodegradation of the NC films, as determined in soil burial study. 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PVA-based nanocomposite (NC) films were fabricated using solution casting technique by adding a low concentration of GO from 0.1 to 0.7%. The tensile strength of the NC films was increased by the addition of GO from 1.40 ± 0.02 MPa to 1.99 ± 0.02 MPa. However, the elongation at break of the NC film was enhanced from 201.02 ± 5.10 to 268.64 ± 5.83% at 0.1–0.3% concentration of GO, and it was decreased with further addition of GO. A considerable improvement in the water vapor permeability was observed at 0.3–0.5% GO, with a value of 6.76 ± 0.06 × 10 − 5 to 6.69 ± 0.08 × 10 − 5 (g/m.hr. Pa) with respect to neat PVA 8.16 ± 0.08 × 10 − 5 (g/m.hr. Pa). Additionally, the use of GO also led to an enhancement in moisture retention capacity, with values ranging from 80.08 to 82.06%. Differential scanning calorimetry (DSC) result revealed a rise in glass transition temperature i.e. 95.62 °C, and maximum enthalpy 50.28 (J/g) at 0.3% GO. Moreover, thermogravimetric analysis (TGA) studies also showed less mass degradation for Poly (vinyl alcohol)/graphene oxide ( PVA/GO) films at higher temperatures compared to PVA film. From scanning electron microscope (SEM) micrographs, minimum surface defects, homogenized mixing, and less agglomeration in the PVA/GO film was observed. This observation was further supported by Fourier-transform infrared spectroscopy (FTIR) data, which indicated a strong hydrogen bonding between the functional groups of GO and PVA polymer chains. Furthermore, the NC films exhibited an effective antibacterial activity against Staphylococcus aureus (gram-positive bacteria). Adversely, there was no inhibition zone observed in neat PVA and its NC films against Escherichia coli (gram-negative bacteria). The incorporation of GO nanofillers was found to reduce the rate of biodegradation of the NC films, as determined in soil burial study. However, improved microorganism degradation was observed in both Bacillus subtilis and Pseudomonas putida bacteria strains. Overall, the acquired results validate the use of GO as an excellent option for the fabrication of biodegradable nanocomposite films that may be used for packaging applications.</description><subject>Agglomerated defects</subject><subject>Antibacterial activity</subject><subject>antibacterial properties</subject><subject>Bacillus subtilis</subject><subject>Bacteria</subject><subject>biodegradability</subject><subject>Biodegradation</subject><subject>Bonding strength</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coliforms</subject><subject>Differential scanning calorimetry</subject><subject>E coli</subject><subject>Electron microscopes</subject><subject>Elongation</subject><subject>Engineering</subject><subject>Enthalpy</subject><subject>Escherichia coli</subject><subject>Fabrication</subject><subject>Food Science</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Glass transition temperature</subject><subject>Gram-negative bacteria</subject><subject>Gram-positive bacteria</subject><subject>Graphene</subject><subject>graphene oxide</subject><subject>High temperature</subject><subject>hydrogen</subject><subject>Hydrogen bonding</subject><subject>Infrared spectroscopy</subject><subject>Micrography</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Original Paper</subject><subject>Permeability</subject><subject>Photomicrographs</subject><subject>Polymers</subject><subject>Polyvinyl alcohol</subject><subject>Pseudomonas putida</subject><subject>Retention capacity</subject><subject>Scanning electron microscopy</subject><subject>soil</subject><subject>Soil permeability</subject><subject>Staphylococcus aureus</subject><subject>Surface defects</subject><subject>Tensile strength</subject><subject>Thermogravimetric analysis</subject><subject>thermogravimetry</subject><subject>Transition temperatures</subject><subject>Water vapor</subject><issn>2193-4126</issn><issn>2193-4134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kU1rGzEQhpeSQo2TP9CToBf3sI1G0n7oWEw-CoH00J6FVp6NZWRpK2lNnF9ftQ4J5JCDGB2e92WGp6o-A_0GlHaXCaCVoqaMl8daUcOHasFA8loAF2cvf9Z-qi5S2lFKATohWr6o5p8ho89WOzJhTBOabA-YSPAkb5HMCUkYyRTckawO1h8d0c6EbXBfLx-inrboC_BoN0i89sGE_RSSzUhG6_aJaL8hNiditjpqkzHaJ51t8OfVx1G7hBfPc1n9vr76tb6t7-5vfqy_39WGNyzXHQyCDtiwpht7GAAp17KRfdfJUXBZjmcS-27oheyN4XrDdG_YICVwKTkavqxWp94phj8zpqz2Nhl0TnsMc1IcGt6WEioK-uUNugtz9GU7xSQDJkCytlDsRJkYUoo4qinavY5HBVT9k6FOMlSRof7LUFBC_BRKBfYPGF-r30n9BcLujMI</recordid><startdate>20240201</startdate><enddate>20240201</enddate><creator>Kapila, Karanjit</creator><creator>Kirtania, Sushen</creator><creator>Devi, Lourembam Monika</creator><creator>Saikumar, Akuleti</creator><creator>Badwaik, Laxmikant S</creator><creator>Rather, Muzamil A</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X2</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M0K</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0002-6709-3462</orcidid><orcidid>https://orcid.org/0000-0001-9089-5968</orcidid><orcidid>https://orcid.org/0000-0001-8103-6328</orcidid><orcidid>https://orcid.org/0000-0003-4926-5117</orcidid><orcidid>https://orcid.org/0000-0002-4642-7531</orcidid><orcidid>https://orcid.org/0000-0002-9315-8581</orcidid></search><sort><creationdate>20240201</creationdate><title>Potential perspectives on the use of poly (vinyl alcohol)/graphene oxide nanocomposite films and its characterization</title><author>Kapila, Karanjit ; Kirtania, Sushen ; Devi, Lourembam Monika ; Saikumar, Akuleti ; Badwaik, Laxmikant S ; Rather, Muzamil A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-71b40be5257f81b1e03a9598779f43910029e87b8498cc3ad2a8c2b9913993ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Agglomerated defects</topic><topic>Antibacterial activity</topic><topic>antibacterial properties</topic><topic>Bacillus subtilis</topic><topic>Bacteria</topic><topic>biodegradability</topic><topic>Biodegradation</topic><topic>Bonding strength</topic><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coliforms</topic><topic>Differential scanning calorimetry</topic><topic>E coli</topic><topic>Electron microscopes</topic><topic>Elongation</topic><topic>Engineering</topic><topic>Enthalpy</topic><topic>Escherichia coli</topic><topic>Fabrication</topic><topic>Food Science</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Glass transition temperature</topic><topic>Gram-negative bacteria</topic><topic>Gram-positive bacteria</topic><topic>Graphene</topic><topic>graphene oxide</topic><topic>High temperature</topic><topic>hydrogen</topic><topic>Hydrogen bonding</topic><topic>Infrared spectroscopy</topic><topic>Micrography</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Original Paper</topic><topic>Permeability</topic><topic>Photomicrographs</topic><topic>Polymers</topic><topic>Polyvinyl alcohol</topic><topic>Pseudomonas putida</topic><topic>Retention capacity</topic><topic>Scanning electron microscopy</topic><topic>soil</topic><topic>Soil permeability</topic><topic>Staphylococcus aureus</topic><topic>Surface defects</topic><topic>Tensile strength</topic><topic>Thermogravimetric analysis</topic><topic>thermogravimetry</topic><topic>Transition temperatures</topic><topic>Water vapor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kapila, Karanjit</creatorcontrib><creatorcontrib>Kirtania, Sushen</creatorcontrib><creatorcontrib>Devi, Lourembam Monika</creatorcontrib><creatorcontrib>Saikumar, Akuleti</creatorcontrib><creatorcontrib>Badwaik, Laxmikant S</creatorcontrib><creatorcontrib>Rather, Muzamil A</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Agricultural Science Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science &amp; 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PVA-based nanocomposite (NC) films were fabricated using solution casting technique by adding a low concentration of GO from 0.1 to 0.7%. The tensile strength of the NC films was increased by the addition of GO from 1.40 ± 0.02 MPa to 1.99 ± 0.02 MPa. However, the elongation at break of the NC film was enhanced from 201.02 ± 5.10 to 268.64 ± 5.83% at 0.1–0.3% concentration of GO, and it was decreased with further addition of GO. A considerable improvement in the water vapor permeability was observed at 0.3–0.5% GO, with a value of 6.76 ± 0.06 × 10 − 5 to 6.69 ± 0.08 × 10 − 5 (g/m.hr. Pa) with respect to neat PVA 8.16 ± 0.08 × 10 − 5 (g/m.hr. Pa). Additionally, the use of GO also led to an enhancement in moisture retention capacity, with values ranging from 80.08 to 82.06%. Differential scanning calorimetry (DSC) result revealed a rise in glass transition temperature i.e. 95.62 °C, and maximum enthalpy 50.28 (J/g) at 0.3% GO. Moreover, thermogravimetric analysis (TGA) studies also showed less mass degradation for Poly (vinyl alcohol)/graphene oxide ( PVA/GO) films at higher temperatures compared to PVA film. From scanning electron microscope (SEM) micrographs, minimum surface defects, homogenized mixing, and less agglomeration in the PVA/GO film was observed. This observation was further supported by Fourier-transform infrared spectroscopy (FTIR) data, which indicated a strong hydrogen bonding between the functional groups of GO and PVA polymer chains. Furthermore, the NC films exhibited an effective antibacterial activity against Staphylococcus aureus (gram-positive bacteria). Adversely, there was no inhibition zone observed in neat PVA and its NC films against Escherichia coli (gram-negative bacteria). The incorporation of GO nanofillers was found to reduce the rate of biodegradation of the NC films, as determined in soil burial study. 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2193-4134
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subjects Agglomerated defects
Antibacterial activity
antibacterial properties
Bacillus subtilis
Bacteria
biodegradability
Biodegradation
Bonding strength
Calorimetry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Coliforms
Differential scanning calorimetry
E coli
Electron microscopes
Elongation
Engineering
Enthalpy
Escherichia coli
Fabrication
Food Science
Fourier transform infrared spectroscopy
Fourier transforms
Functional groups
Glass transition temperature
Gram-negative bacteria
Gram-positive bacteria
Graphene
graphene oxide
High temperature
hydrogen
Hydrogen bonding
Infrared spectroscopy
Micrography
Nanocomposites
Nanoparticles
Original Paper
Permeability
Photomicrographs
Polymers
Polyvinyl alcohol
Pseudomonas putida
Retention capacity
Scanning electron microscopy
soil
Soil permeability
Staphylococcus aureus
Surface defects
Tensile strength
Thermogravimetric analysis
thermogravimetry
Transition temperatures
Water vapor
title Potential perspectives on the use of poly (vinyl alcohol)/graphene oxide nanocomposite films and its characterization
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