Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering

The mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al 2 O 3 -Na 2 O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na 4 Ca 3 (AlO 2 ) 10 was also...

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Veröffentlicht in:International journal of minerals, metallurgy and materials metallurgy and materials, 2020-07, Vol.27 (7), p.924-932
Hauptverfasser: Yu, Hai-yan, Pan, Xiao-lin, Tian, Yong-pan, Tu, Gan-feng
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container_title International journal of minerals, metallurgy and materials
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Pan, Xiao-lin
Tian, Yong-pan
Tu, Gan-feng
description The mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al 2 O 3 -Na 2 O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na 4 Ca 3 (AlO 2 ) 10 was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na 4 Ca 3 (AlO 2 ) 10 , CaOAl 2 O 3 , and 12CaO·7Al 2 O 3 , and the content of Na 4 Ca 3 (AlO 2 ) 10 could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na 4 Ca 3 (AlO 2 ) 10 occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na 4 Ca 3 (AlO 2 ) 10 was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na 4 Ca 3 (AlO 2 ) 10 was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.
doi_str_mv 10.1007/s12613-019-1951-1
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The results indicated that the minerals formed during the sintering process included Na 4 Ca 3 (AlO 2 ) 10 , CaOAl 2 O 3 , and 12CaO·7Al 2 O 3 , and the content of Na 4 Ca 3 (AlO 2 ) 10 could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na 4 Ca 3 (AlO 2 ) 10 occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na 4 Ca 3 (AlO 2 ) 10 was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). 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subjects Aluminum oxide
Calcium
Calcium aluminate
Calcium compounds
Calcium oxide
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Corrosion and Coatings
Crystal growth
Crystal structure
Exothermic reactions
Fourier transforms
Glass
High temperature
Materials Science
Metallic Materials
Metallurgy
Natural Materials
Raman spectra
Sintering
Software
Solid solutions
Surfaces and Interfaces
Temperature
Thin Films
Tribology
Vibration
title Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering
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