Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering
The mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al 2 O 3 -Na 2 O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na 4 Ca 3 (AlO 2 ) 10 was also...
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Veröffentlicht in: | International journal of minerals, metallurgy and materials metallurgy and materials, 2020-07, Vol.27 (7), p.924-932 |
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creator | Yu, Hai-yan Pan, Xiao-lin Tian, Yong-pan Tu, Gan-feng |
description | The mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al
2
O
3
-Na
2
O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na
4
Ca
3
(AlO
2
)
10
was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na
4
Ca
3
(AlO
2
)
10
, CaOAl
2
O
3
, and 12CaO·7Al
2
O
3
, and the content of Na
4
Ca
3
(AlO
2
)
10
could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na
4
Ca
3
(AlO
2
)
10
occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na
4
Ca
3
(AlO
2
)
10
was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na
4
Ca
3
(AlO
2
)
10
was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol. |
doi_str_mv | 10.1007/s12613-019-1951-1 |
format | Article |
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2
O
3
-Na
2
O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na
4
Ca
3
(AlO
2
)
10
was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na
4
Ca
3
(AlO
2
)
10
, CaOAl
2
O
3
, and 12CaO·7Al
2
O
3
, and the content of Na
4
Ca
3
(AlO
2
)
10
could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na
4
Ca
3
(AlO
2
)
10
occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na
4
Ca
3
(AlO
2
)
10
was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na
4
Ca
3
(AlO
2
)
10
was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.</description><identifier>ISSN: 1674-4799</identifier><identifier>EISSN: 1869-103X</identifier><identifier>DOI: 10.1007/s12613-019-1951-1</identifier><language>eng</language><publisher>Beijing: University of Science and Technology Beijing</publisher><subject>Aluminum oxide ; Calcium ; Calcium aluminate ; Calcium compounds ; Calcium oxide ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Corrosion and Coatings ; Crystal growth ; Crystal structure ; Exothermic reactions ; Fourier transforms ; Glass ; High temperature ; Materials Science ; Metallic Materials ; Metallurgy ; Natural Materials ; Raman spectra ; Sintering ; Software ; Solid solutions ; Surfaces and Interfaces ; Temperature ; Thin Films ; Tribology ; Vibration</subject><ispartof>International journal of minerals, metallurgy and materials, 2020-07, Vol.27 (7), p.924-932</ispartof><rights>University of Science and Technology Beijing and Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>University of Science and Technology Beijing and Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-2bab386fa2a7b9d965fbb3ae9eea5bbd0a0bad6d97f79ebfc3f8a4521b4809473</citedby><cites>FETCH-LOGICAL-c316t-2bab386fa2a7b9d965fbb3ae9eea5bbd0a0bad6d97f79ebfc3f8a4521b4809473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12613-019-1951-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2920677162?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21368,27903,27904,33723,41467,42536,43784,51297,64361,64365,72215</link.rule.ids></links><search><creatorcontrib>Yu, Hai-yan</creatorcontrib><creatorcontrib>Pan, Xiao-lin</creatorcontrib><creatorcontrib>Tian, Yong-pan</creatorcontrib><creatorcontrib>Tu, Gan-feng</creatorcontrib><title>Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering</title><title>International journal of minerals, metallurgy and materials</title><addtitle>Int J Miner Metall Mater</addtitle><description>The mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al
2
O
3
-Na
2
O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na
4
Ca
3
(AlO
2
)
10
was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na
4
Ca
3
(AlO
2
)
10
, CaOAl
2
O
3
, and 12CaO·7Al
2
O
3
, and the content of Na
4
Ca
3
(AlO
2
)
10
could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na
4
Ca
3
(AlO
2
)
10
occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na
4
Ca
3
(AlO
2
)
10
was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na
4
Ca
3
(AlO
2
)
10
was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.</description><subject>Aluminum oxide</subject><subject>Calcium</subject><subject>Calcium aluminate</subject><subject>Calcium compounds</subject><subject>Calcium oxide</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Corrosion and Coatings</subject><subject>Crystal growth</subject><subject>Crystal structure</subject><subject>Exothermic reactions</subject><subject>Fourier transforms</subject><subject>Glass</subject><subject>High temperature</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Metallurgy</subject><subject>Natural Materials</subject><subject>Raman spectra</subject><subject>Sintering</subject><subject>Software</subject><subject>Solid solutions</subject><subject>Surfaces and Interfaces</subject><subject>Temperature</subject><subject>Thin Films</subject><subject>Tribology</subject><subject>Vibration</subject><issn>1674-4799</issn><issn>1869-103X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kD9PwzAQxSMEEqXwAdgsMRtsJ7Hjsar4JxWygMRmnRO7dZU4wU6G7nxwEorExHT3dPfu6X5Jck3JLSVE3EXKOE0xoRJTmVNMT5IFLfikSPpxOvVcZDgTUp4nFzHuCeFCELFIvl6cNwEaNATw0Q2u8wh8jWwXWvhRral24F1sUWdRBU3lxhZBM7bOw2BQ1bV9N_o6IufRGkq8aliZ4ldgJYqHOJgW1WNwfot2brvDk-6nvGEMBkXnBzOPLpMzC000V791mbw_3L-tn_CmfHxerza4SikfMNOg04JbYCC0rCXPrdYpGGkM5FrXBIiGmtdSWCGNtlVqC8hyRnVWEJmJdJncHO_2ofscTRzUvhuDnyIVk2xGQjmbtuhxqwpdjMFY1QfXQjgoStQMWx1hqwm2mmErOnnY0RP7-SET_i7_b_oGfyWFQw</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Yu, Hai-yan</creator><creator>Pan, Xiao-lin</creator><creator>Tian, Yong-pan</creator><creator>Tu, Gan-feng</creator><general>University of Science and Technology Beijing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20200701</creationdate><title>Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering</title><author>Yu, Hai-yan ; Pan, Xiao-lin ; Tian, Yong-pan ; Tu, Gan-feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-2bab386fa2a7b9d965fbb3ae9eea5bbd0a0bad6d97f79ebfc3f8a4521b4809473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aluminum oxide</topic><topic>Calcium</topic><topic>Calcium aluminate</topic><topic>Calcium compounds</topic><topic>Calcium oxide</topic><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Corrosion and Coatings</topic><topic>Crystal growth</topic><topic>Crystal structure</topic><topic>Exothermic reactions</topic><topic>Fourier transforms</topic><topic>Glass</topic><topic>High temperature</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Metallurgy</topic><topic>Natural Materials</topic><topic>Raman spectra</topic><topic>Sintering</topic><topic>Software</topic><topic>Solid solutions</topic><topic>Surfaces and Interfaces</topic><topic>Temperature</topic><topic>Thin Films</topic><topic>Tribology</topic><topic>Vibration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Hai-yan</creatorcontrib><creatorcontrib>Pan, Xiao-lin</creatorcontrib><creatorcontrib>Tian, Yong-pan</creatorcontrib><creatorcontrib>Tu, Gan-feng</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>Natural Science Collection (ProQuest)</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>International journal of minerals, metallurgy and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Hai-yan</au><au>Pan, Xiao-lin</au><au>Tian, Yong-pan</au><au>Tu, Gan-feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering</atitle><jtitle>International journal of minerals, metallurgy and materials</jtitle><stitle>Int J Miner Metall Mater</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>27</volume><issue>7</issue><spage>924</spage><epage>932</epage><pages>924-932</pages><issn>1674-4799</issn><eissn>1869-103X</eissn><abstract>The mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al
2
O
3
-Na
2
O system during the high-temperature sintering process were systematically investigated using DSC-TG, XRD, SEM-EDS, FTIR, and Raman spectra, and the crystal structure of Na
4
Ca
3
(AlO
2
)
10
was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na
4
Ca
3
(AlO
2
)
10
, CaOAl
2
O
3
, and 12CaO·7Al
2
O
3
, and the content of Na
4
Ca
3
(AlO
2
)
10
could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na
4
Ca
3
(AlO
2
)
10
occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na
4
Ca
3
(AlO
2
)
10
was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na
4
Ca
3
(AlO
2
)
10
was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.</abstract><cop>Beijing</cop><pub>University of Science and Technology Beijing</pub><doi>10.1007/s12613-019-1951-1</doi><tpages>9</tpages></addata></record> |
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issn | 1674-4799 1869-103X |
language | eng |
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source | Springer Nature - Complete Springer Journals; ProQuest Central UK/Ireland; Alma/SFX Local Collection; ProQuest Central |
subjects | Aluminum oxide Calcium Calcium aluminate Calcium compounds Calcium oxide Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Corrosion and Coatings Crystal growth Crystal structure Exothermic reactions Fourier transforms Glass High temperature Materials Science Metallic Materials Metallurgy Natural Materials Raman spectra Sintering Software Solid solutions Surfaces and Interfaces Temperature Thin Films Tribology Vibration |
title | Mineral transition and formation mechanism of calcium aluminate compounds in CaO-Al2O3-Na2O system during high-temperature sintering |
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