Near-infrared spectral downshifting in Sr(3−x)(VO4)2:xNd3+ phosphor

In this study, the spectral downshifting (DS) from ultraviolet (UV) light to near-infrared (NIR) radiation in Sr 3 (VO 4 ) 2 :Nd 3 + phosphor is reported. The prepared materials were characterized by X-ray powder diffraction (XRD) and photoluminescence (PL) properties along with steady state lumines...

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Veröffentlicht in:Bulletin of materials science 2016-12, Vol.39 (7), p.1625-1629
Hauptverfasser: Sawala, N S, Koparkar, K A, Bajaj, N S, Omanwar, S K
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container_title Bulletin of materials science
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creator Sawala, N S
Koparkar, K A
Bajaj, N S
Omanwar, S K
description In this study, the spectral downshifting (DS) from ultraviolet (UV) light to near-infrared (NIR) radiation in Sr 3 (VO 4 ) 2 :Nd 3 + phosphor is reported. The prepared materials were characterized by X-ray powder diffraction (XRD) and photoluminescence (PL) properties along with steady state luminescence time decay curves were studied, which confirmed the energy transfer (ET) from VO 4 3 − ions to Nd 3 + ions. The DS phenomenon by phosphor was observed, which involved emission of NIR photons (1075 and 1064 nm) and visible photons (506 nm) from absorbed UV photons at 349 nm. The theoretical energy transfer efficiency (ETE) was calculated with the help of steady state luminescence time decay curves and the maximum ET efficiency approached up to 41.33%. The crystalline silicon (c-Si) cell has maximum efficiency in NIR region of solar spectrum due to an energy band gap of 1.12 eV. Sr 3 (VO 4 ) 2 :Nd 3 + can be potentially used as a NIR DC phosphor for c-Si solar cells.
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subjects Chemistry and Materials Science
Crystal structure
Decay
Efficiency
Energy
Energy bands
Energy gap
Energy transfer
Engineering
Fluorides
Infrared spectra
Luminescence
Materials Science
Near infrared radiation
Phosphors
Photoluminescence
Photons
Photovoltaic cells
Silicon
Solar cells
Steady state
X ray powder diffraction
X-rays
title Near-infrared spectral downshifting in Sr(3−x)(VO4)2:xNd3+ phosphor
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