Amorphization of SiO2 Thin Films by Using 200 MeV Ag15+ Ions

Effect of swift heavy ions (SHI) on low-k SiO 2 thin films has been investigated. SiO 2 thin films were deposited on pre-cleaned p-Si substrate by using sol-gel spin coating technique. Further, deposited films were annealed at 400 ∘ C to remove structural irregularities. Prepared samples were irradi...

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Veröffentlicht in:SILICON 2019-04, Vol.11 (2), p.1017-1021
Hauptverfasser: Gaikwad, Anil, Mhaisagar, Yogesh, Gupta, Swati, Joshi, Bhavana, Asokan, Kandasami, Mahajan, Ashok
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container_start_page 1017
container_title SILICON
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creator Gaikwad, Anil
Mhaisagar, Yogesh
Gupta, Swati
Joshi, Bhavana
Asokan, Kandasami
Mahajan, Ashok
description Effect of swift heavy ions (SHI) on low-k SiO 2 thin films has been investigated. SiO 2 thin films were deposited on pre-cleaned p-Si substrate by using sol-gel spin coating technique. Further, deposited films were annealed at 400 ∘ C to remove structural irregularities. Prepared samples were irradiated with 200 MeV Ag 15+ ions at different ion fluence such as 5 × 10 11 , 1 × 10 12 and 5 × 10 12 ions/cm 2 . Deposition of SiO 2 was confirmed by using EDAX and FTIR spectroscopy. Increase in ion fluence increases the RMS roughness from 1.49 to 7.79 nm. The transformation of deposited material from polycrystalline to amorphous nature was confirmed from XRD spectra. Increase in SHI fluence decreases the grain size from 181.3 to 74.1 nm for pristine and sample irradiated at 5 × 10 11 ions/cm 2 . Whereas, for sample irradiated with 5 × 10 11 ions/cm 2 fluence doesn’t show crystalline peak at (011). It is observed that SHI irradiation leads to grain agglomeration with decrease in crystal size at higher fluence. Further, conductivity of the samples under study was observed to be decreased with increase in ion fluence. Thus, it is demonstrated that the surface and structural properties of low-k silica thin films can be tailored by controlling the SHI fluence.
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SiO 2 thin films were deposited on pre-cleaned p-Si substrate by using sol-gel spin coating technique. Further, deposited films were annealed at 400 ∘ C to remove structural irregularities. Prepared samples were irradiated with 200 MeV Ag 15+ ions at different ion fluence such as 5 × 10 11 , 1 × 10 12 and 5 × 10 12 ions/cm 2 . Deposition of SiO 2 was confirmed by using EDAX and FTIR spectroscopy. Increase in ion fluence increases the RMS roughness from 1.49 to 7.79 nm. The transformation of deposited material from polycrystalline to amorphous nature was confirmed from XRD spectra. Increase in SHI fluence decreases the grain size from 181.3 to 74.1 nm for pristine and sample irradiated at 5 × 10 11 ions/cm 2 . Whereas, for sample irradiated with 5 × 10 11 ions/cm 2 fluence doesn’t show crystalline peak at (011). It is observed that SHI irradiation leads to grain agglomeration with decrease in crystal size at higher fluence. 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subjects Amorphization
Amorphous materials
Chemistry
Chemistry and Materials Science
Environmental Chemistry
Fluence
Grain size
Heavy ions
Inorganic Chemistry
Irradiation
Lasers
Materials Science
Optical Devices
Optics
Original Paper
Photonics
Polymer Sciences
Silicon dioxide
Silicon substrates
Sol-gel processes
Spectrum analysis
Spin coating
Thin films
title Amorphization of SiO2 Thin Films by Using 200 MeV Ag15+ Ions
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