Synthesis, Mechanical and Optical Features of Dy2O3 Doped Lead Alkali Borosilicate Glasses

Characterizations of the prepared pseudo penta-glass system 60 PbO – (40-x) SiO 2 – x (0.1 Li 2 O – 0.86 B 2 O 3 – 0.04 Dy 2 O 3 ) with 0 ≤ x ≤ 30 mol% were performed in terms of the ultrasonic and spectroscopic techniques. The increase of (0.1 Li 2 O – 0.86 B 2 O 3 – 0.04 Dy 2 O 3 ) content causes...

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Veröffentlicht in:SILICON 2019-08, Vol.11 (4), p.1853-1861
Hauptverfasser: Shaaban, Kh. S., Ali, Atif Mossad, Saddeek, Y. B., Aly, K. A., Dahshan, Alaa, Amin, S. A.
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container_issue 4
container_start_page 1853
container_title SILICON
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creator Shaaban, Kh. S.
Ali, Atif Mossad
Saddeek, Y. B.
Aly, K. A.
Dahshan, Alaa
Amin, S. A.
description Characterizations of the prepared pseudo penta-glass system 60 PbO – (40-x) SiO 2 – x (0.1 Li 2 O – 0.86 B 2 O 3 – 0.04 Dy 2 O 3 ) with 0 ≤ x ≤ 30 mol% were performed in terms of the ultrasonic and spectroscopic techniques. The increase of (0.1 Li 2 O – 0.86 B 2 O 3 – 0.04 Dy 2 O 3 ) content causes borate structural variations such as the transformation of [BO 3 ] to [BO 4 ] structural units and enhancement of the compactness of the glasses. These physical parameters play an important role in modifying the mechanical and the optical properties of the lead silicate glasses. The improvement of the mechanical properties is indicated from the increment of the density, the ultrasonic velocities, the elastic moduli (experimentally determined and theoretically computed) and the glass transition temperature. The borate structural variations along with the presence of Dy 2 O 3 decrease both the UV transmission and the optical energy gap, increase the refractive index and created several transitions at different wavelengths.
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The improvement of the mechanical properties is indicated from the increment of the density, the ultrasonic velocities, the elastic moduli (experimentally determined and theoretically computed) and the glass transition temperature. 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subjects Boron oxides
Borosilicate glass
Chemistry
Chemistry and Materials Science
Energy gap
Environmental Chemistry
Glass transition temperature
Inorganic Chemistry
Lasers
Lead oxides
Lead silicate
Lithium oxides
Materials Science
Mechanical properties
Modulus of elasticity
Optical Devices
Optical properties
Optics
Original Paper
Oxygen
Parameter modification
Photonics
Physical properties
Physics
Polymer Sciences
Radiation
Refractivity
Science
Silicon
Silicon dioxide
title Synthesis, Mechanical and Optical Features of Dy2O3 Doped Lead Alkali Borosilicate Glasses
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