Effect of Silica Nanoparticles and Modified Silica Nanoparticles on the Mechanical and Swelling Properties of EPDM/SBR Blend Nanocomposites

The influences of nanosilica and modified nanosilica on cure, compression set, mechanical and swelling characteristics are studied in blends of ethylene-propylene-diene monomer (EPDM)/styrene-butadiene rubber (SBR). In EPDM/SBR composites, the nanosilica made from rice husk ash (RHA) was utilised as...

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Veröffentlicht in:SILICON 2023-09, Vol.15 (14), p.6033-6046
Hauptverfasser: Ragupathy, K., Prabaharan, G., Pragadish, N., Vishvanathperumal, S.
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container_issue 14
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creator Ragupathy, K.
Prabaharan, G.
Pragadish, N.
Vishvanathperumal, S.
description The influences of nanosilica and modified nanosilica on cure, compression set, mechanical and swelling characteristics are studied in blends of ethylene-propylene-diene monomer (EPDM)/styrene-butadiene rubber (SBR). In EPDM/SBR composites, the nanosilica made from rice husk ash (RHA) was utilised as a reinforcing nanofiller. The interaction between the nanosilica and the EPDM/SBR matrix at the interface is crucial for the production of rubber composites. This study uses bis[3-(triethoxysilyl)propyl] tetrasulfide (TESPT) and polyoxyethylene (20) sorbitan monolaurate (TWEEN-20) as a silica modifier, with the ratio of TESPT to TWEEN-20 maintained at 2:1. The cure and mechanical characteristics, compression set, abrasion and swelling resistance increased with the incorporation of nanosilica and modified nanosilica. By interacting at the interface between silica nanoparticles and the EPDM/SBR rubber matrix, TESPT with the TWEEN-20 modifier exhibits a considerable effect on cure characteristics, mechanical qualities, and swelling resistance.
doi_str_mv 10.1007/s12633-023-02497-1
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subjects Abrasion resistance
Carbon
Chemistry
Chemistry and Materials Science
Environmental Chemistry
Heat resistance
Hydrogen bonds
Inorganic Chemistry
Lasers
Materials Science
Mechanical engineering
Mechanical properties
Nanocomposites
Nanoparticles
Optical Devices
Optics
Organic chemicals
Photonics
Polymer blends
Polymer Sciences
Polyoxyethylene sorbitan monolaurate
Propylene
Rubber
Silicon dioxide
Swelling
VOCs
Volatile organic compounds
title Effect of Silica Nanoparticles and Modified Silica Nanoparticles on the Mechanical and Swelling Properties of EPDM/SBR Blend Nanocomposites
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