Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study
We synthesized waste biomass-based partly graphitized activated carbon from Samanea saman waste pods (SSWPAC) and used it to remove hazardous dye rhodamine B (Rh B) and metal Cr(VI) from aqueous solution. The prepared adsorbent showed a remarkable surface area of 546.016 m 2 g −1 . The adsorbent wa...
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| Veröffentlicht in: | Biomass conversion and biorefinery 2024-02, Vol.14 (3), p.3535-3550 |
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| container_title | Biomass conversion and biorefinery |
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| creator | Kumbhar, Pramod Patil, Suryakant Narale, Dattatray Sartape, Ashish Jambhale, Chitra Kim, Jin-Hyeok Kolekar, Sanjay |
| description | We synthesized waste biomass-based partly graphitized activated carbon from
Samanea saman
waste pods (SSWPAC) and used it to remove hazardous dye rhodamine B (Rh B) and metal Cr(VI) from aqueous solution. The prepared adsorbent showed a remarkable surface area of 546.016 m
2
g
−1
. The adsorbent was characterized by applying Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy-dispersive x-ray analysis, Raman spectroscopy, and X-ray diffraction. Within 50 min, 99.2% elimination of Rh B dye was observed at pH 2 using 1.0 g L
−1
of the adsorbent, while Cr(VI) removal was 98.3% at pH 2 using 2.5 g L
−1
of the adsorbent within 120 min at room temperature. The correlation coefficient
R
2
favored pseudo-second-order kinetics in kinetic analyses of both adsorption processes. The isotherm experimental values of Rh B and Cr(VI) fits to Freundlich adsorption systems with correlation coefficient
R
2
= 0.998 and 0.999 respectively. The results showed maximum adsorption capacity of SSWPAC for Rh B (101.01 mg g
−1
) and Cr(VI) (64.52 mg g
−1
). The phytotoxicity study exhibited successful removal of these pollutants from the solutions under study. |
| doi_str_mv | 10.1007/s13399-022-02625-8 |
| format | Article |
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Samanea saman
waste pods (SSWPAC) and used it to remove hazardous dye rhodamine B (Rh B) and metal Cr(VI) from aqueous solution. The prepared adsorbent showed a remarkable surface area of 546.016 m
2
g
−1
. The adsorbent was characterized by applying Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy-dispersive x-ray analysis, Raman spectroscopy, and X-ray diffraction. Within 50 min, 99.2% elimination of Rh B dye was observed at pH 2 using 1.0 g L
−1
of the adsorbent, while Cr(VI) removal was 98.3% at pH 2 using 2.5 g L
−1
of the adsorbent within 120 min at room temperature. The correlation coefficient
R
2
favored pseudo-second-order kinetics in kinetic analyses of both adsorption processes. The isotherm experimental values of Rh B and Cr(VI) fits to Freundlich adsorption systems with correlation coefficient
R
2
= 0.998 and 0.999 respectively. The results showed maximum adsorption capacity of SSWPAC for Rh B (101.01 mg g
−1
) and Cr(VI) (64.52 mg g
−1
). The phytotoxicity study exhibited successful removal of these pollutants from the solutions under study.</description><identifier>ISSN: 2190-6815</identifier><identifier>EISSN: 2190-6823</identifier><identifier>DOI: 10.1007/s13399-022-02625-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Activated carbon ; Adsorbents ; Adsorption ; Aqueous solutions ; Biotechnology ; Chromium ; Correlation coefficients ; Dyes ; Emission analysis ; Energy ; Energy dispersive X ray analysis ; Field emission microscopy ; Field emission spectroscopy ; Fourier transforms ; Graphitization ; Infrared analysis ; Infrared spectroscopy ; Isotherms ; Original Article ; Raman spectroscopy ; Renewable and Green Energy ; Rhodamine ; Room temperature ; Spectrum analysis ; X ray analysis</subject><ispartof>Biomass conversion and biorefinery, 2024-02, Vol.14 (3), p.3535-3550</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-9defbecc80ad06d089389869e430fb0a31ac2dbf0066121d44e2ef2f8d68b31f3</citedby><cites>FETCH-LOGICAL-c319t-9defbecc80ad06d089389869e430fb0a31ac2dbf0066121d44e2ef2f8d68b31f3</cites><orcidid>0000-0002-4367-6014</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13399-022-02625-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13399-022-02625-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Kumbhar, Pramod</creatorcontrib><creatorcontrib>Patil, Suryakant</creatorcontrib><creatorcontrib>Narale, Dattatray</creatorcontrib><creatorcontrib>Sartape, Ashish</creatorcontrib><creatorcontrib>Jambhale, Chitra</creatorcontrib><creatorcontrib>Kim, Jin-Hyeok</creatorcontrib><creatorcontrib>Kolekar, Sanjay</creatorcontrib><title>Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study</title><title>Biomass conversion and biorefinery</title><addtitle>Biomass Conv. Bioref</addtitle><description>We synthesized waste biomass-based partly graphitized activated carbon from
Samanea saman
waste pods (SSWPAC) and used it to remove hazardous dye rhodamine B (Rh B) and metal Cr(VI) from aqueous solution. The prepared adsorbent showed a remarkable surface area of 546.016 m
2
g
−1
. The adsorbent was characterized by applying Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy-dispersive x-ray analysis, Raman spectroscopy, and X-ray diffraction. Within 50 min, 99.2% elimination of Rh B dye was observed at pH 2 using 1.0 g L
−1
of the adsorbent, while Cr(VI) removal was 98.3% at pH 2 using 2.5 g L
−1
of the adsorbent within 120 min at room temperature. The correlation coefficient
R
2
favored pseudo-second-order kinetics in kinetic analyses of both adsorption processes. The isotherm experimental values of Rh B and Cr(VI) fits to Freundlich adsorption systems with correlation coefficient
R
2
= 0.998 and 0.999 respectively. The results showed maximum adsorption capacity of SSWPAC for Rh B (101.01 mg g
−1
) and Cr(VI) (64.52 mg g
−1
). The phytotoxicity study exhibited successful removal of these pollutants from the solutions under study.</description><subject>Activated carbon</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Biotechnology</subject><subject>Chromium</subject><subject>Correlation coefficients</subject><subject>Dyes</subject><subject>Emission analysis</subject><subject>Energy</subject><subject>Energy dispersive X ray analysis</subject><subject>Field emission microscopy</subject><subject>Field emission spectroscopy</subject><subject>Fourier transforms</subject><subject>Graphitization</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Isotherms</subject><subject>Original Article</subject><subject>Raman spectroscopy</subject><subject>Renewable and Green Energy</subject><subject>Rhodamine</subject><subject>Room temperature</subject><subject>Spectrum analysis</subject><subject>X ray analysis</subject><issn>2190-6815</issn><issn>2190-6823</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWGr_gKuAGwVHb5I2TdzZ4qNQcKNuQyYPO7UzqclMoTt_urEV3bm43LP4zrmXg9ApgSsCML5OhDEpC6A0D6ejQhygHiUSCi4oO_zVZHSMBiktAYCyMRMMeuhzUoVSJ2ex0bEMDfYhYue9M221cTi6Omz0CgeP4yJYXVeNwxOsG4un8fx1doF9DDXWH50LXcIprLq2Cs0Nfs9gW5lLXKXQLlysd56dCnbb5CCDU9vZ7Qk68nqV3OBn99HL_d3z9LGYPz3MprfzwjAi20Ja50tnjABtgVsQkgkpuHRDBr4EzYg21JYegHNCiR0OHXWeemG5KBnxrI_O9rnrGPK3qVXL0MUmn1RUEimAMMIzRfeUiSGl6Lxax6rWcasIqO-y1b5slctWu7KVyCa2N6UMN28u_kX_4_oCtIqDZA</recordid><startdate>20240201</startdate><enddate>20240201</enddate><creator>Kumbhar, Pramod</creator><creator>Patil, Suryakant</creator><creator>Narale, Dattatray</creator><creator>Sartape, Ashish</creator><creator>Jambhale, Chitra</creator><creator>Kim, Jin-Hyeok</creator><creator>Kolekar, Sanjay</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4367-6014</orcidid></search><sort><creationdate>20240201</creationdate><title>Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study</title><author>Kumbhar, Pramod ; Patil, Suryakant ; Narale, Dattatray ; Sartape, Ashish ; Jambhale, Chitra ; Kim, Jin-Hyeok ; Kolekar, Sanjay</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-9defbecc80ad06d089389869e430fb0a31ac2dbf0066121d44e2ef2f8d68b31f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Activated carbon</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Biotechnology</topic><topic>Chromium</topic><topic>Correlation coefficients</topic><topic>Dyes</topic><topic>Emission analysis</topic><topic>Energy</topic><topic>Energy dispersive X ray analysis</topic><topic>Field emission microscopy</topic><topic>Field emission spectroscopy</topic><topic>Fourier transforms</topic><topic>Graphitization</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Isotherms</topic><topic>Original Article</topic><topic>Raman spectroscopy</topic><topic>Renewable and Green Energy</topic><topic>Rhodamine</topic><topic>Room temperature</topic><topic>Spectrum analysis</topic><topic>X ray analysis</topic><toplevel>online_resources</toplevel><creatorcontrib>Kumbhar, Pramod</creatorcontrib><creatorcontrib>Patil, Suryakant</creatorcontrib><creatorcontrib>Narale, Dattatray</creatorcontrib><creatorcontrib>Sartape, Ashish</creatorcontrib><creatorcontrib>Jambhale, Chitra</creatorcontrib><creatorcontrib>Kim, Jin-Hyeok</creatorcontrib><creatorcontrib>Kolekar, Sanjay</creatorcontrib><collection>CrossRef</collection><jtitle>Biomass conversion and biorefinery</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumbhar, Pramod</au><au>Patil, Suryakant</au><au>Narale, Dattatray</au><au>Sartape, Ashish</au><au>Jambhale, Chitra</au><au>Kim, Jin-Hyeok</au><au>Kolekar, Sanjay</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study</atitle><jtitle>Biomass conversion and biorefinery</jtitle><stitle>Biomass Conv. Bioref</stitle><date>2024-02-01</date><risdate>2024</risdate><volume>14</volume><issue>3</issue><spage>3535</spage><epage>3550</epage><pages>3535-3550</pages><issn>2190-6815</issn><eissn>2190-6823</eissn><abstract>We synthesized waste biomass-based partly graphitized activated carbon from
Samanea saman
waste pods (SSWPAC) and used it to remove hazardous dye rhodamine B (Rh B) and metal Cr(VI) from aqueous solution. The prepared adsorbent showed a remarkable surface area of 546.016 m
2
g
−1
. The adsorbent was characterized by applying Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy-dispersive x-ray analysis, Raman spectroscopy, and X-ray diffraction. Within 50 min, 99.2% elimination of Rh B dye was observed at pH 2 using 1.0 g L
−1
of the adsorbent, while Cr(VI) removal was 98.3% at pH 2 using 2.5 g L
−1
of the adsorbent within 120 min at room temperature. The correlation coefficient
R
2
favored pseudo-second-order kinetics in kinetic analyses of both adsorption processes. The isotherm experimental values of Rh B and Cr(VI) fits to Freundlich adsorption systems with correlation coefficient
R
2
= 0.998 and 0.999 respectively. The results showed maximum adsorption capacity of SSWPAC for Rh B (101.01 mg g
−1
) and Cr(VI) (64.52 mg g
−1
). The phytotoxicity study exhibited successful removal of these pollutants from the solutions under study.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13399-022-02625-8</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0002-4367-6014</orcidid></addata></record> |
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| subjects | Activated carbon Adsorbents Adsorption Aqueous solutions Biotechnology Chromium Correlation coefficients Dyes Emission analysis Energy Energy dispersive X ray analysis Field emission microscopy Field emission spectroscopy Fourier transforms Graphitization Infrared analysis Infrared spectroscopy Isotherms Original Article Raman spectroscopy Renewable and Green Energy Rhodamine Room temperature Spectrum analysis X ray analysis |
| title | Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study |
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