A logical explanation of structurally unfit X-ray diffraction peaks in nanoferroelectrics

In the present paper we suggest the cause and solution of some unidentified X-ray diffraction (XRD) peaks in ferroelectric nanoparticles. Indeed, a relationship between the structurally unfit XRD peaks and domains in the ferroelectric nanoparticles is suggested. BaTiO 3 , PbTiO 3 and Sr 0.5 Ba 0.5 N...

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Veröffentlicht in:Bulletin of materials science 2018-02, Vol.41 (1), p.24, Article 24
Hauptverfasser: Dudhe, C M, Sakhare, B K, Panchbhai, S S, Khambadkar, S J, Dhoke, N V, Chaudhari, C P, Palikundwar, U A
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container_issue 1
container_start_page 24
container_title Bulletin of materials science
container_volume 41
creator Dudhe, C M
Sakhare, B K
Panchbhai, S S
Khambadkar, S J
Dhoke, N V
Chaudhari, C P
Palikundwar, U A
description In the present paper we suggest the cause and solution of some unidentified X-ray diffraction (XRD) peaks in ferroelectric nanoparticles. Indeed, a relationship between the structurally unfit XRD peaks and domains in the ferroelectric nanoparticles is suggested. BaTiO 3 , PbTiO 3 and Sr 0.5 Ba 0.5 Nb 2 O 6 nanoparticles were used as trial samples. Diffraction of X-rays by domain grating was considered for the occurrence of unfit peaks. It was found that domain widths corresponding to some structurally unfit minor peaks of all three trail samples show good agreement to the values estimated from the transmission electron microscopy images. The study can be used to estimate the width of nanodomains (within 5–10 Å) in ferroelectric nanoparticles. Thus, the study seems to be highly important for the advancement of nanoferroelectricity.
doi_str_mv 10.1007/s12034-017-1528-4
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subjects Barium titanates
Chemistry and Materials Science
Engineering
Ferroelectric materials
Ferroelectricity
Ferroelectrics
Fourier transforms
Information storage
Materials Science
Nanoparticles
Single crystals
X-ray diffraction
X-rays
title A logical explanation of structurally unfit X-ray diffraction peaks in nanoferroelectrics
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