Study of perovskite CH3NH3PbI3 thin films under thermal exposure
Methyl-ammonium lead iodide-based perovskite materials have been extensively studied for applications in solar cells, which have reached high efficiencies of about 24% in the laboratory. However, being a hybrid (organic–inorganic) material, methyl-ammonium lead iodide can be affected by climatic con...
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| Veröffentlicht in: | Bulletin of materials science 2021-06, Vol.44 (2), p.83, Article 83 |
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| creator | Sanchez-Diaz, Jesus Torres, Jeevan de la Torre, Jorge Esparza, Diego Rivas, Jesús Manuel |
| description | Methyl-ammonium lead iodide-based perovskite materials have been extensively studied for applications in solar cells, which have reached high efficiencies of about 24% in the laboratory. However, being a hybrid (organic–inorganic) material, methyl-ammonium lead iodide can be affected by climatic conditions, such as humidity, light and temperature. While perovskite films have been synthesized, and annealing as part of the fabrication process has been reported, there have been, however, relatively few studies on the effects of temperature when the films, after synthesis, have been intentionally exposed to different temperatures. In this work, a study of the behaviour of perovskite films (MAPbI
3
) has been conducted exposing the films to different temperatures (25, 40, 50, 60 and 70°C) in small greenhouses. Homogeneous perovskite films were deposited by the anti-solvent method. The films were characterized by field-emission scanning electron microscopy, X-ray diffraction and optical absorption. The effects of temperature on film morphology, grain size and light absorbance are reported. |
| doi_str_mv | 10.1007/s12034-021-02400-x |
| format | Article |
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3
) has been conducted exposing the films to different temperatures (25, 40, 50, 60 and 70°C) in small greenhouses. Homogeneous perovskite films were deposited by the anti-solvent method. The films were characterized by field-emission scanning electron microscopy, X-ray diffraction and optical absorption. The effects of temperature on film morphology, grain size and light absorbance are reported.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-021-02400-x</identifier><language>eng</language><publisher>Bangalore: Indian Academy of Sciences</publisher><subject>Alternative energy sources ; Chemistry and Materials Science ; Efficiency ; Engineering ; Exposure ; Glass substrates ; Grain size ; Greenhouse gases ; Light ; Materials Science ; Morphology ; Perovskites ; Phase transitions ; Photovoltaic cells ; Solar cells ; Solvents ; Temperature ; Temperature effects ; Thin films</subject><ispartof>Bulletin of materials science, 2021-06, Vol.44 (2), p.83, Article 83</ispartof><rights>Indian Academy of Sciences 2021</rights><rights>Indian Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-a8ce8094f5f5995fdaed9909bb5d84ae43cd1064d5d38eabfb416c9c1aa4c5ea3</citedby><cites>FETCH-LOGICAL-c358t-a8ce8094f5f5995fdaed9909bb5d84ae43cd1064d5d38eabfb416c9c1aa4c5ea3</cites><orcidid>0000-0002-5021-4942 ; 0000-0001-6090-5547</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2919639351/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2919639351?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21368,27903,27904,33723,41467,42536,43784,51297,64361,64365,72215,74048</link.rule.ids></links><search><creatorcontrib>Sanchez-Diaz, Jesus</creatorcontrib><creatorcontrib>Torres, Jeevan</creatorcontrib><creatorcontrib>de la Torre, Jorge</creatorcontrib><creatorcontrib>Esparza, Diego</creatorcontrib><creatorcontrib>Rivas, Jesús Manuel</creatorcontrib><title>Study of perovskite CH3NH3PbI3 thin films under thermal exposure</title><title>Bulletin of materials science</title><addtitle>Bull Mater Sci</addtitle><description>Methyl-ammonium lead iodide-based perovskite materials have been extensively studied for applications in solar cells, which have reached high efficiencies of about 24% in the laboratory. However, being a hybrid (organic–inorganic) material, methyl-ammonium lead iodide can be affected by climatic conditions, such as humidity, light and temperature. While perovskite films have been synthesized, and annealing as part of the fabrication process has been reported, there have been, however, relatively few studies on the effects of temperature when the films, after synthesis, have been intentionally exposed to different temperatures. In this work, a study of the behaviour of perovskite films (MAPbI
3
) has been conducted exposing the films to different temperatures (25, 40, 50, 60 and 70°C) in small greenhouses. Homogeneous perovskite films were deposited by the anti-solvent method. The films were characterized by field-emission scanning electron microscopy, X-ray diffraction and optical absorption. The effects of temperature on film morphology, grain size and light absorbance are reported.</description><subject>Alternative energy sources</subject><subject>Chemistry and Materials Science</subject><subject>Efficiency</subject><subject>Engineering</subject><subject>Exposure</subject><subject>Glass substrates</subject><subject>Grain size</subject><subject>Greenhouse gases</subject><subject>Light</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Perovskites</subject><subject>Phase transitions</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><subject>Solvents</subject><subject>Temperature</subject><subject>Temperature effects</subject><subject>Thin films</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kN9LwzAQx4MoOKf_gE8Fn6OXJmmbN2XoNhgqqM8hbS7aubU1aWX7741W8M2H447j-wM-hJwzuGQA-VVgKXBBIWVxBADdHZAJqJzTPMvUYbxTCVTkkB-TkxDWAEwJwSbk-qkf7D5pXdKhbz_De91jMlvw-wV_LJc86d_qJnH1ZhuSobHo4wP91mwS3HVtGDyekiNnNgHPfveUvNzdPs8WdPUwX85uVrTisuipKSosQAknnVRKOmvQKgWqLKUthEHBK8sgE1ZaXqApXSlYVqmKGSMqiYZPycWY2_n2Y8DQ63U7-CZW6lQxlXHFJYuqdFRVvg3Bo9Odr7fG7zUD_U1Kj6R0JKV_SOldNPHRFKK4eUX_F_2P6wsZLGwa</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Sanchez-Diaz, Jesus</creator><creator>Torres, Jeevan</creator><creator>de la Torre, Jorge</creator><creator>Esparza, Diego</creator><creator>Rivas, Jesús Manuel</creator><general>Indian Academy of Sciences</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-5021-4942</orcidid><orcidid>https://orcid.org/0000-0001-6090-5547</orcidid></search><sort><creationdate>20210601</creationdate><title>Study of perovskite CH3NH3PbI3 thin films under thermal exposure</title><author>Sanchez-Diaz, Jesus ; 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However, being a hybrid (organic–inorganic) material, methyl-ammonium lead iodide can be affected by climatic conditions, such as humidity, light and temperature. While perovskite films have been synthesized, and annealing as part of the fabrication process has been reported, there have been, however, relatively few studies on the effects of temperature when the films, after synthesis, have been intentionally exposed to different temperatures. In this work, a study of the behaviour of perovskite films (MAPbI
3
) has been conducted exposing the films to different temperatures (25, 40, 50, 60 and 70°C) in small greenhouses. Homogeneous perovskite films were deposited by the anti-solvent method. The films were characterized by field-emission scanning electron microscopy, X-ray diffraction and optical absorption. The effects of temperature on film morphology, grain size and light absorbance are reported.</abstract><cop>Bangalore</cop><pub>Indian Academy of Sciences</pub><doi>10.1007/s12034-021-02400-x</doi><orcidid>https://orcid.org/0000-0002-5021-4942</orcidid><orcidid>https://orcid.org/0000-0001-6090-5547</orcidid></addata></record> |
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| subjects | Alternative energy sources Chemistry and Materials Science Efficiency Engineering Exposure Glass substrates Grain size Greenhouse gases Light Materials Science Morphology Perovskites Phase transitions Photovoltaic cells Solar cells Solvents Temperature Temperature effects Thin films |
| title | Study of perovskite CH3NH3PbI3 thin films under thermal exposure |
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