Effect of ferrite phase addition on the functional properties of (K0.5Na0.5)NbO3ceramics
. Lead-free ceramics consist of ferroelectric K 0.5 Na 0.5 NbO 3 (KNN) and spinel ferrimagnetic CoFe 2 O 4 (CFO) phases were prepared by the conventional solid state reaction method. The constituent phase presence of multiferroic material was confirmed by X-ray diffraction techniques with Rietveld r...
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creator | Lima, R. J. S. Banerjee, P. Araujo, E. B. Franco, A. |
description | .
Lead-free ceramics consist of ferroelectric K
0.5
Na
0.5
NbO
3
(KNN) and spinel ferrimagnetic CoFe
2
O
4
(CFO) phases were prepared by the conventional solid state reaction method. The constituent phase presence of multiferroic material was confirmed by X-ray diffraction techniques with Rietveld refinement methods. A systematic study of dielectric properties at room temperature with frequency revealed that the dispersion is in accordance with the Cole-Cole model with the presence of dc conductivity at lower frequencies. The main reason for this type of dispersion was related with the different heterogeneous conduction mechanism between the ferroelectric and ferrite phases in multiferroic structures. Complex impedance analysis re-established non-Debye type dielectric relaxation mechanism in the multiferroic. The effect of constituents phase variation on the electric and magnetic hysteresis behavior was also examined. The ferroelectric order diluted with the addition of ferrite content. The remnant magnetization (
M
r
) and saturation magnetization (
M
s
) values increased while the coercivity (
H
c
) values of the materialss decreased with the addition of ferrite content. We established that this material is a room temperature multiferroic and highlighted a possible way to modulate functional properties of this lead-free materials for application in microelectromechanical system (MEMS) technology. |
doi_str_mv | 10.1140/epjp/i2019-12775-x |
format | Article |
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Lead-free ceramics consist of ferroelectric K
0.5
Na
0.5
NbO
3
(KNN) and spinel ferrimagnetic CoFe
2
O
4
(CFO) phases were prepared by the conventional solid state reaction method. The constituent phase presence of multiferroic material was confirmed by X-ray diffraction techniques with Rietveld refinement methods. A systematic study of dielectric properties at room temperature with frequency revealed that the dispersion is in accordance with the Cole-Cole model with the presence of dc conductivity at lower frequencies. The main reason for this type of dispersion was related with the different heterogeneous conduction mechanism between the ferroelectric and ferrite phases in multiferroic structures. Complex impedance analysis re-established non-Debye type dielectric relaxation mechanism in the multiferroic. The effect of constituents phase variation on the electric and magnetic hysteresis behavior was also examined. The ferroelectric order diluted with the addition of ferrite content. The remnant magnetization (
M
r
) and saturation magnetization (
M
s
) values increased while the coercivity (
H
c
) values of the materialss decreased with the addition of ferrite content. We established that this material is a room temperature multiferroic and highlighted a possible way to modulate functional properties of this lead-free materials for application in microelectromechanical system (MEMS) technology.</description><identifier>ISSN: 2190-5444</identifier><identifier>EISSN: 2190-5444</identifier><identifier>DOI: 10.1140/epjp/i2019-12775-x</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied and Technical Physics ; Atomic ; Cobalt ferrites ; Coercivity ; Complex Systems ; Condensed Matter Physics ; Dielectric properties ; Dielectric relaxation ; Dispersion ; Electrical properties ; Ferroelectric materials ; Ferroelectricity ; Hysteresis ; Iron constituents ; Lead free ; Magnetic saturation ; Mathematical and Computational Physics ; Microelectromechanical systems ; Molecular ; Multiferroic materials ; Optical and Plasma Physics ; Physics ; Physics and Astronomy ; Regular Article ; Room temperature ; Theoretical ; X-ray diffraction</subject><ispartof>European physical journal plus, 2019-08, Vol.134 (8), p.404, Article 404</ispartof><rights>Società Italiana di Fisica and Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Società Italiana di Fisica and Springer-Verlag GmbH Germany, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c234x-5ba71ee4c0f0b939c0fca5beb5e8c9546c9d876b78b10b3d2dda63d5c2eba8313</citedby><cites>FETCH-LOGICAL-c234x-5ba71ee4c0f0b939c0fca5beb5e8c9546c9d876b78b10b3d2dda63d5c2eba8313</cites><orcidid>0000-0001-8473-6610</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1140/epjp/i2019-12775-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2919608434?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,41464,42533,43781,51294</link.rule.ids></links><search><creatorcontrib>Lima, R. J. S.</creatorcontrib><creatorcontrib>Banerjee, P.</creatorcontrib><creatorcontrib>Araujo, E. B.</creatorcontrib><creatorcontrib>Franco, A.</creatorcontrib><title>Effect of ferrite phase addition on the functional properties of (K0.5Na0.5)NbO3ceramics</title><title>European physical journal plus</title><addtitle>Eur. Phys. J. Plus</addtitle><description>.
Lead-free ceramics consist of ferroelectric K
0.5
Na
0.5
NbO
3
(KNN) and spinel ferrimagnetic CoFe
2
O
4
(CFO) phases were prepared by the conventional solid state reaction method. The constituent phase presence of multiferroic material was confirmed by X-ray diffraction techniques with Rietveld refinement methods. A systematic study of dielectric properties at room temperature with frequency revealed that the dispersion is in accordance with the Cole-Cole model with the presence of dc conductivity at lower frequencies. The main reason for this type of dispersion was related with the different heterogeneous conduction mechanism between the ferroelectric and ferrite phases in multiferroic structures. Complex impedance analysis re-established non-Debye type dielectric relaxation mechanism in the multiferroic. The effect of constituents phase variation on the electric and magnetic hysteresis behavior was also examined. The ferroelectric order diluted with the addition of ferrite content. The remnant magnetization (
M
r
) and saturation magnetization (
M
s
) values increased while the coercivity (
H
c
) values of the materialss decreased with the addition of ferrite content. We established that this material is a room temperature multiferroic and highlighted a possible way to modulate functional properties of this lead-free materials for application in microelectromechanical system (MEMS) technology.</description><subject>Applied and Technical Physics</subject><subject>Atomic</subject><subject>Cobalt ferrites</subject><subject>Coercivity</subject><subject>Complex Systems</subject><subject>Condensed Matter Physics</subject><subject>Dielectric properties</subject><subject>Dielectric relaxation</subject><subject>Dispersion</subject><subject>Electrical properties</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Hysteresis</subject><subject>Iron constituents</subject><subject>Lead free</subject><subject>Magnetic saturation</subject><subject>Mathematical and Computational Physics</subject><subject>Microelectromechanical systems</subject><subject>Molecular</subject><subject>Multiferroic materials</subject><subject>Optical and Plasma Physics</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Regular Article</subject><subject>Room temperature</subject><subject>Theoretical</subject><subject>X-ray diffraction</subject><issn>2190-5444</issn><issn>2190-5444</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9UE1LAzEQDaJgqf0Dnha86GHbfO5ujlLqB5b2ouAtJNmJTWm7a7KF-u_NtoKeHIZ5M_De8HgIXRM8JoTjCbTrduIpJjIntCxFfjhDA0okzgXn_PzPfolGMa5xKi4Jl3yA3mfOge2yxmUOQvAdZO1KR8h0XfvON7ssdbeCzO13tr_1JmtD00LoPMRedvuCx2Kh07hbmCWzEPTW23iFLpzeRBj94BC9Pcxep0_5fPn4PL2f55YyfsiF0SUB4BY7bCSTCa0WBoyAykrBCyvrqixMWRmCDatpXeuC1cJSMLpihA3RzelvcvW5h9ipdbMPyWZUVBJZ4Ioznlj0xLKhiTGAU23wWx2-FMGqD1H1IapjiOoYojokETuJYiLvPiD8vv5H9Q0j_3cd</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Lima, R. J. S.</creator><creator>Banerjee, P.</creator><creator>Araujo, E. B.</creator><creator>Franco, A.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>P5Z</scope><scope>P62</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0001-8473-6610</orcidid></search><sort><creationdate>20190801</creationdate><title>Effect of ferrite phase addition on the functional properties of (K0.5Na0.5)NbO3ceramics</title><author>Lima, R. J. S. ; Banerjee, P. ; Araujo, E. B. ; Franco, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c234x-5ba71ee4c0f0b939c0fca5beb5e8c9546c9d876b78b10b3d2dda63d5c2eba8313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Applied and Technical Physics</topic><topic>Atomic</topic><topic>Cobalt ferrites</topic><topic>Coercivity</topic><topic>Complex Systems</topic><topic>Condensed Matter Physics</topic><topic>Dielectric properties</topic><topic>Dielectric relaxation</topic><topic>Dispersion</topic><topic>Electrical properties</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Hysteresis</topic><topic>Iron constituents</topic><topic>Lead free</topic><topic>Magnetic saturation</topic><topic>Mathematical and Computational Physics</topic><topic>Microelectromechanical systems</topic><topic>Molecular</topic><topic>Multiferroic materials</topic><topic>Optical and Plasma Physics</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Regular Article</topic><topic>Room temperature</topic><topic>Theoretical</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lima, R. J. S.</creatorcontrib><creatorcontrib>Banerjee, P.</creatorcontrib><creatorcontrib>Araujo, E. B.</creatorcontrib><creatorcontrib>Franco, A.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>European physical journal plus</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lima, R. J. S.</au><au>Banerjee, P.</au><au>Araujo, E. B.</au><au>Franco, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of ferrite phase addition on the functional properties of (K0.5Na0.5)NbO3ceramics</atitle><jtitle>European physical journal plus</jtitle><stitle>Eur. Phys. J. Plus</stitle><date>2019-08-01</date><risdate>2019</risdate><volume>134</volume><issue>8</issue><spage>404</spage><pages>404-</pages><artnum>404</artnum><issn>2190-5444</issn><eissn>2190-5444</eissn><abstract>.
Lead-free ceramics consist of ferroelectric K
0.5
Na
0.5
NbO
3
(KNN) and spinel ferrimagnetic CoFe
2
O
4
(CFO) phases were prepared by the conventional solid state reaction method. The constituent phase presence of multiferroic material was confirmed by X-ray diffraction techniques with Rietveld refinement methods. A systematic study of dielectric properties at room temperature with frequency revealed that the dispersion is in accordance with the Cole-Cole model with the presence of dc conductivity at lower frequencies. The main reason for this type of dispersion was related with the different heterogeneous conduction mechanism between the ferroelectric and ferrite phases in multiferroic structures. Complex impedance analysis re-established non-Debye type dielectric relaxation mechanism in the multiferroic. The effect of constituents phase variation on the electric and magnetic hysteresis behavior was also examined. The ferroelectric order diluted with the addition of ferrite content. The remnant magnetization (
M
r
) and saturation magnetization (
M
s
) values increased while the coercivity (
H
c
) values of the materialss decreased with the addition of ferrite content. We established that this material is a room temperature multiferroic and highlighted a possible way to modulate functional properties of this lead-free materials for application in microelectromechanical system (MEMS) technology.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1140/epjp/i2019-12775-x</doi><orcidid>https://orcid.org/0000-0001-8473-6610</orcidid></addata></record> |
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subjects | Applied and Technical Physics Atomic Cobalt ferrites Coercivity Complex Systems Condensed Matter Physics Dielectric properties Dielectric relaxation Dispersion Electrical properties Ferroelectric materials Ferroelectricity Hysteresis Iron constituents Lead free Magnetic saturation Mathematical and Computational Physics Microelectromechanical systems Molecular Multiferroic materials Optical and Plasma Physics Physics Physics and Astronomy Regular Article Room temperature Theoretical X-ray diffraction |
title | Effect of ferrite phase addition on the functional properties of (K0.5Na0.5)NbO3ceramics |
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