Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples
A new optical sensor was designed for sensitive, selective detection and determination of Cd 2+ , Cr 3+ , Ni 2+ and Pb 2+ based on immobilization of dithizone (DZ) on a BiFeO 3 (BFO) nanopowder. The sol–gel technique has been used for the synthesis of nano-multiferroic BiFeO 3 in a pure form. The ef...
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| Veröffentlicht in: | Bulletin of materials science 2021-06, Vol.44 (2), p.122, Article 122 |
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| creator | Taha, Gharib Mahmoud Rashed, Mohamed Nageeb El-Sadek, Mahmoud Sayed Abd Moghazy, Marwa Abd El-fatah |
| description | A new optical sensor was designed for sensitive, selective detection and determination of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
based on immobilization of dithizone (DZ) on a BiFeO
3
(BFO) nanopowder. The sol–gel technique has been used for the synthesis of nano-multiferroic BiFeO
3
in a pure form. The effect of DZ concentration, stirring time, pH and BFO molar concentration for immobilization of DZ as an indicator on BFO nanoparticles was developed. Highly sensing and colour change of the optical sensor of the studied metals Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
showed detection limits of 1.65 × 10
−4
, 1.5 × 10
−4
, 3 × 10
−4
and 7.8 × 10
−5
M, respectively. The optical sensor’s response time to studied metals varies with the concentration of metals. The prepared optical sensor was used to analyse the industrial wastewater sample qualitatively and quantitatively. Atomic absorption spectrometer analysis verified the assayed levels of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
. The sensor efficiencies for Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
were 95.27, 84.56, 84.99 and 104.73%, respectively. |
| doi_str_mv | 10.1007/s12034-021-02396-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2919548049</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2919548049</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-a6ff04ae59d27d9545e6456bcfdd90195e02ae91eb15aa09f230510cad920dfb3</originalsourceid><addsrcrecordid>eNp9UMtKAzEUHUTB-vgBVwHXozeZZMYstfiCihtdh3RyYyMzSU3Sgn6DH23aCu5cXO7rnAPnVNUZhQsK0F0myqDhNTBaqpFtzfeqCciuqbu2lftlZgJq3kF3WB2l9A5AJed0Un0_rYbsLMYYXE9u3B0-N8S4vHBfwSOxK99nF7we3BcaohMJy-x6PZCEPoVIbCmDGbcoor3ZbnF0Xm8vwZIURiQL1OtPMmLWQyLOE_RrF4Mf0eeNmB6XA6aT6sCWP57-9uPq9e72ZfpQz57vH6fXs7pvxFWudWstcI1CGtYZKbjAlot23ltjZDEmEJhGSXFOhdYgLWtAUOi1kQyMnTfH1flOdxnDxwpTVu9hFYvJpJgsfH4FXBYU26H6GFKKaNUyulHHT0VBbVJXu9RVSV1tU1e8kJodKRWwf8P4J_0P6wfxkojE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2919548049</pqid></control><display><type>article</type><title>Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples</title><source>Indian Academy of Sciences</source><source>Springer Nature - Complete Springer Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Free Full-Text Journals in Chemistry</source><source>ProQuest Central</source><creator>Taha, Gharib Mahmoud ; Rashed, Mohamed Nageeb ; El-Sadek, Mahmoud Sayed Abd ; Moghazy, Marwa Abd El-fatah</creator><creatorcontrib>Taha, Gharib Mahmoud ; Rashed, Mohamed Nageeb ; El-Sadek, Mahmoud Sayed Abd ; Moghazy, Marwa Abd El-fatah</creatorcontrib><description>A new optical sensor was designed for sensitive, selective detection and determination of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
based on immobilization of dithizone (DZ) on a BiFeO
3
(BFO) nanopowder. The sol–gel technique has been used for the synthesis of nano-multiferroic BiFeO
3
in a pure form. The effect of DZ concentration, stirring time, pH and BFO molar concentration for immobilization of DZ as an indicator on BFO nanoparticles was developed. Highly sensing and colour change of the optical sensor of the studied metals Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
showed detection limits of 1.65 × 10
−4
, 1.5 × 10
−4
, 3 × 10
−4
and 7.8 × 10
−5
M, respectively. The optical sensor’s response time to studied metals varies with the concentration of metals. The prepared optical sensor was used to analyse the industrial wastewater sample qualitatively and quantitatively. Atomic absorption spectrometer analysis verified the assayed levels of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
. The sensor efficiencies for Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
were 95.27, 84.56, 84.99 and 104.73%, respectively.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-021-02396-4</identifier><language>eng</language><publisher>Bangalore: Indian Academy of Sciences</publisher><subject>Bismuth ferrite ; Cadmium ; Chemistry and Materials Science ; Engineering ; Enzymes ; Ethanol ; Heavy metals ; Immobilization ; Industrial wastes ; Materials Science ; Multiferroic materials ; Nanoparticles ; Optical measuring instruments ; Radiation ; Sensors ; Sol-gel processes ; Trivalent chromium ; Water sampling</subject><ispartof>Bulletin of materials science, 2021-06, Vol.44 (2), p.122, Article 122</ispartof><rights>Indian Academy of Sciences 2021</rights><rights>Indian Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-a6ff04ae59d27d9545e6456bcfdd90195e02ae91eb15aa09f230510cad920dfb3</citedby><cites>FETCH-LOGICAL-c358t-a6ff04ae59d27d9545e6456bcfdd90195e02ae91eb15aa09f230510cad920dfb3</cites><orcidid>0000-0002-7295-081X ; 0000-0003-2987-8469 ; 0000-0002-8401-4359</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2919548049/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2919548049?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,41464,42533,43781,51294,74045</link.rule.ids></links><search><creatorcontrib>Taha, Gharib Mahmoud</creatorcontrib><creatorcontrib>Rashed, Mohamed Nageeb</creatorcontrib><creatorcontrib>El-Sadek, Mahmoud Sayed Abd</creatorcontrib><creatorcontrib>Moghazy, Marwa Abd El-fatah</creatorcontrib><title>Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples</title><title>Bulletin of materials science</title><addtitle>Bull Mater Sci</addtitle><description>A new optical sensor was designed for sensitive, selective detection and determination of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
based on immobilization of dithizone (DZ) on a BiFeO
3
(BFO) nanopowder. The sol–gel technique has been used for the synthesis of nano-multiferroic BiFeO
3
in a pure form. The effect of DZ concentration, stirring time, pH and BFO molar concentration for immobilization of DZ as an indicator on BFO nanoparticles was developed. Highly sensing and colour change of the optical sensor of the studied metals Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
showed detection limits of 1.65 × 10
−4
, 1.5 × 10
−4
, 3 × 10
−4
and 7.8 × 10
−5
M, respectively. The optical sensor’s response time to studied metals varies with the concentration of metals. The prepared optical sensor was used to analyse the industrial wastewater sample qualitatively and quantitatively. Atomic absorption spectrometer analysis verified the assayed levels of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
. The sensor efficiencies for Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
were 95.27, 84.56, 84.99 and 104.73%, respectively.</description><subject>Bismuth ferrite</subject><subject>Cadmium</subject><subject>Chemistry and Materials Science</subject><subject>Engineering</subject><subject>Enzymes</subject><subject>Ethanol</subject><subject>Heavy metals</subject><subject>Immobilization</subject><subject>Industrial wastes</subject><subject>Materials Science</subject><subject>Multiferroic materials</subject><subject>Nanoparticles</subject><subject>Optical measuring instruments</subject><subject>Radiation</subject><subject>Sensors</subject><subject>Sol-gel processes</subject><subject>Trivalent chromium</subject><subject>Water sampling</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9UMtKAzEUHUTB-vgBVwHXozeZZMYstfiCihtdh3RyYyMzSU3Sgn6DH23aCu5cXO7rnAPnVNUZhQsK0F0myqDhNTBaqpFtzfeqCciuqbu2lftlZgJq3kF3WB2l9A5AJed0Un0_rYbsLMYYXE9u3B0-N8S4vHBfwSOxK99nF7we3BcaohMJy-x6PZCEPoVIbCmDGbcoor3ZbnF0Xm8vwZIURiQL1OtPMmLWQyLOE_RrF4Mf0eeNmB6XA6aT6sCWP57-9uPq9e72ZfpQz57vH6fXs7pvxFWudWstcI1CGtYZKbjAlot23ltjZDEmEJhGSXFOhdYgLWtAUOi1kQyMnTfH1flOdxnDxwpTVu9hFYvJpJgsfH4FXBYU26H6GFKKaNUyulHHT0VBbVJXu9RVSV1tU1e8kJodKRWwf8P4J_0P6wfxkojE</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Taha, Gharib Mahmoud</creator><creator>Rashed, Mohamed Nageeb</creator><creator>El-Sadek, Mahmoud Sayed Abd</creator><creator>Moghazy, Marwa Abd El-fatah</creator><general>Indian Academy of Sciences</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-7295-081X</orcidid><orcidid>https://orcid.org/0000-0003-2987-8469</orcidid><orcidid>https://orcid.org/0000-0002-8401-4359</orcidid></search><sort><creationdate>20210601</creationdate><title>Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples</title><author>Taha, Gharib Mahmoud ; Rashed, Mohamed Nageeb ; El-Sadek, Mahmoud Sayed Abd ; Moghazy, Marwa Abd El-fatah</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-a6ff04ae59d27d9545e6456bcfdd90195e02ae91eb15aa09f230510cad920dfb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Bismuth ferrite</topic><topic>Cadmium</topic><topic>Chemistry and Materials Science</topic><topic>Engineering</topic><topic>Enzymes</topic><topic>Ethanol</topic><topic>Heavy metals</topic><topic>Immobilization</topic><topic>Industrial wastes</topic><topic>Materials Science</topic><topic>Multiferroic materials</topic><topic>Nanoparticles</topic><topic>Optical measuring instruments</topic><topic>Radiation</topic><topic>Sensors</topic><topic>Sol-gel processes</topic><topic>Trivalent chromium</topic><topic>Water sampling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Taha, Gharib Mahmoud</creatorcontrib><creatorcontrib>Rashed, Mohamed Nageeb</creatorcontrib><creatorcontrib>El-Sadek, Mahmoud Sayed Abd</creatorcontrib><creatorcontrib>Moghazy, Marwa Abd El-fatah</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Bulletin of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Taha, Gharib Mahmoud</au><au>Rashed, Mohamed Nageeb</au><au>El-Sadek, Mahmoud Sayed Abd</au><au>Moghazy, Marwa Abd El-fatah</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples</atitle><jtitle>Bulletin of materials science</jtitle><stitle>Bull Mater Sci</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>44</volume><issue>2</issue><spage>122</spage><pages>122-</pages><artnum>122</artnum><issn>0250-4707</issn><eissn>0973-7669</eissn><abstract>A new optical sensor was designed for sensitive, selective detection and determination of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
based on immobilization of dithizone (DZ) on a BiFeO
3
(BFO) nanopowder. The sol–gel technique has been used for the synthesis of nano-multiferroic BiFeO
3
in a pure form. The effect of DZ concentration, stirring time, pH and BFO molar concentration for immobilization of DZ as an indicator on BFO nanoparticles was developed. Highly sensing and colour change of the optical sensor of the studied metals Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
showed detection limits of 1.65 × 10
−4
, 1.5 × 10
−4
, 3 × 10
−4
and 7.8 × 10
−5
M, respectively. The optical sensor’s response time to studied metals varies with the concentration of metals. The prepared optical sensor was used to analyse the industrial wastewater sample qualitatively and quantitatively. Atomic absorption spectrometer analysis verified the assayed levels of Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
. The sensor efficiencies for Cd
2+
, Cr
3+
, Ni
2+
and Pb
2+
were 95.27, 84.56, 84.99 and 104.73%, respectively.</abstract><cop>Bangalore</cop><pub>Indian Academy of Sciences</pub><doi>10.1007/s12034-021-02396-4</doi><orcidid>https://orcid.org/0000-0002-7295-081X</orcidid><orcidid>https://orcid.org/0000-0003-2987-8469</orcidid><orcidid>https://orcid.org/0000-0002-8401-4359</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0250-4707 |
| ispartof | Bulletin of materials science, 2021-06, Vol.44 (2), p.122, Article 122 |
| issn | 0250-4707 0973-7669 |
| language | eng |
| recordid | cdi_proquest_journals_2919548049 |
| source | Indian Academy of Sciences; Springer Nature - Complete Springer Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry; ProQuest Central |
| subjects | Bismuth ferrite Cadmium Chemistry and Materials Science Engineering Enzymes Ethanol Heavy metals Immobilization Industrial wastes Materials Science Multiferroic materials Nanoparticles Optical measuring instruments Radiation Sensors Sol-gel processes Trivalent chromium Water sampling |
| title | Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples |
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