Simple route deposition and some physical investigations on nanoflower NiMoO4 sprayed thin films
Nickel molybdate (NiMoO 4 ) thin film has been prepared by the spray pyrolysis method, using nickel chloride hexahydrate (NiCl 2 ·6H 2 O) and ammonium molybdate tetrahydrate [(NH 4 ) 6Mo 7 O 24 ·4H 2 O] as precursors in the aqueous starting solution. First, the structure and the surface morphology c...
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| Veröffentlicht in: | Bulletin of materials science 2021-06, Vol.44 (2), p.128, Article 128 |
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| creator | Gassoumi, B Jaballah, R Boukhachem, A Kamoun-Turki, N Amlouk, M |
| description | Nickel molybdate (NiMoO
4
) thin film has been prepared by the spray pyrolysis method, using nickel chloride hexahydrate (NiCl
2
·6H
2
O) and ammonium molybdate tetrahydrate [(NH
4
) 6Mo
7
O
24
·4H
2
O] as precursors in the aqueous starting solution. First, the structure and the surface morphology characterizations were carried out by scanning electron spectroscopy (SEM), Raman and X-ray diffraction (XRD) techniques. Structural analysis by using XRD technique shows that the NiMoO
4
thin film crystallizes in the monoclinic phase, mainly orientation along (110), (021), (
2
¯
04
), (220), (150) and (
1
¯
52
), directions. In addition to these studies, the stoichiometric composition has been reached by the energy dispersion analysis technique. Second, the optical properties have been studied by means of the reflectance and the transmittance spectra, in the wavelength range of 300–1800 nm. This study shows a direct transition of this ternary oxide with an optical bandgap about 3.12 eV and Urbach energy
E
U
in the order of 663 meV. Finally, the photoluminescence emission spectrum of the NiMoO
4
thin film showed emissions peaks in the violet and blue regions and others emission related to some defects in the prepared film. |
| doi_str_mv | 10.1007/s12034-021-02404-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2919479745</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2919479745</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-2de48b5cbe6a82aefa733aa9e46c015fae9528bb41536898e6498732d539df573</originalsourceid><addsrcrecordid>eNp9UMtOwzAQtBBIlMIPcLLEOeBX4viIEC-p0ANwNk6yaV0ldrBTUP8elyBx47DalXZmdmcQOqfkkhIiryJlhIuMMJpKEJHJAzQjSvJMFoU6TDPLSSYkkcfoJMYNIVQJQWfo_cX2Qwc4-O0IuIHBRzta77BxDY6-Bzysd9HWpsPWfUIc7crs9xEnjDPOt53_goCf7ZNfChyHYHbQ4HFtHW5t18dTdNSaLsLZb5-jt7vb15uHbLG8f7y5XmQ1p2rMWAOirPK6gsKUzEBrJOfGKBBFTWjeGlA5K6tK0JwXpSqhEKqUnDU5V02bSz5HF5PuEPzHNj2qN34bXDqpmUpmpZIiTyg2oergYwzQ6iHY3oSdpkTvk9RTkjolqX-S1HtpPpGSO-tWEP6k_2F9A4I9d2w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2919479745</pqid></control><display><type>article</type><title>Simple route deposition and some physical investigations on nanoflower NiMoO4 sprayed thin films</title><source>Indian Academy of Sciences</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Free Full-Text Journals in Chemistry</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Gassoumi, B ; Jaballah, R ; Boukhachem, A ; Kamoun-Turki, N ; Amlouk, M</creator><creatorcontrib>Gassoumi, B ; Jaballah, R ; Boukhachem, A ; Kamoun-Turki, N ; Amlouk, M</creatorcontrib><description>Nickel molybdate (NiMoO
4
) thin film has been prepared by the spray pyrolysis method, using nickel chloride hexahydrate (NiCl
2
·6H
2
O) and ammonium molybdate tetrahydrate [(NH
4
) 6Mo
7
O
24
·4H
2
O] as precursors in the aqueous starting solution. First, the structure and the surface morphology characterizations were carried out by scanning electron spectroscopy (SEM), Raman and X-ray diffraction (XRD) techniques. Structural analysis by using XRD technique shows that the NiMoO
4
thin film crystallizes in the monoclinic phase, mainly orientation along (110), (021), (
2
¯
04
), (220), (150) and (
1
¯
52
), directions. In addition to these studies, the stoichiometric composition has been reached by the energy dispersion analysis technique. Second, the optical properties have been studied by means of the reflectance and the transmittance spectra, in the wavelength range of 300–1800 nm. This study shows a direct transition of this ternary oxide with an optical bandgap about 3.12 eV and Urbach energy
E
U
in the order of 663 meV. Finally, the photoluminescence emission spectrum of the NiMoO
4
thin film showed emissions peaks in the violet and blue regions and others emission related to some defects in the prepared film.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-021-02404-7</identifier><language>eng</language><publisher>Bangalore: Indian Academy of Sciences</publisher><subject>Ammonium molybdate ; Catalysis ; Chemistry and Materials Science ; Crystal defects ; Engineering ; Glass substrates ; Materials Science ; Metal oxides ; Molybdates ; Molybdenum ; Nickel chloride ; Nickel compounds ; Optical properties ; Photoluminescence ; Radiation ; Scanning electron microscopy ; Sensors ; Spectrum analysis ; Spray pyrolysis ; Structural analysis ; Temperature ; Thin films ; X-ray diffraction</subject><ispartof>Bulletin of materials science, 2021-06, Vol.44 (2), p.128, Article 128</ispartof><rights>Indian Academy of Sciences 2021</rights><rights>Indian Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-2de48b5cbe6a82aefa733aa9e46c015fae9528bb41536898e6498732d539df573</citedby><cites>FETCH-LOGICAL-c319t-2de48b5cbe6a82aefa733aa9e46c015fae9528bb41536898e6498732d539df573</cites><orcidid>0000-0003-2030-483X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2919479745/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2919479745?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21369,27903,27904,33723,41467,42536,43784,51297,74048</link.rule.ids></links><search><creatorcontrib>Gassoumi, B</creatorcontrib><creatorcontrib>Jaballah, R</creatorcontrib><creatorcontrib>Boukhachem, A</creatorcontrib><creatorcontrib>Kamoun-Turki, N</creatorcontrib><creatorcontrib>Amlouk, M</creatorcontrib><title>Simple route deposition and some physical investigations on nanoflower NiMoO4 sprayed thin films</title><title>Bulletin of materials science</title><addtitle>Bull Mater Sci</addtitle><description>Nickel molybdate (NiMoO
4
) thin film has been prepared by the spray pyrolysis method, using nickel chloride hexahydrate (NiCl
2
·6H
2
O) and ammonium molybdate tetrahydrate [(NH
4
) 6Mo
7
O
24
·4H
2
O] as precursors in the aqueous starting solution. First, the structure and the surface morphology characterizations were carried out by scanning electron spectroscopy (SEM), Raman and X-ray diffraction (XRD) techniques. Structural analysis by using XRD technique shows that the NiMoO
4
thin film crystallizes in the monoclinic phase, mainly orientation along (110), (021), (
2
¯
04
), (220), (150) and (
1
¯
52
), directions. In addition to these studies, the stoichiometric composition has been reached by the energy dispersion analysis technique. Second, the optical properties have been studied by means of the reflectance and the transmittance spectra, in the wavelength range of 300–1800 nm. This study shows a direct transition of this ternary oxide with an optical bandgap about 3.12 eV and Urbach energy
E
U
in the order of 663 meV. Finally, the photoluminescence emission spectrum of the NiMoO
4
thin film showed emissions peaks in the violet and blue regions and others emission related to some defects in the prepared film.</description><subject>Ammonium molybdate</subject><subject>Catalysis</subject><subject>Chemistry and Materials Science</subject><subject>Crystal defects</subject><subject>Engineering</subject><subject>Glass substrates</subject><subject>Materials Science</subject><subject>Metal oxides</subject><subject>Molybdates</subject><subject>Molybdenum</subject><subject>Nickel chloride</subject><subject>Nickel compounds</subject><subject>Optical properties</subject><subject>Photoluminescence</subject><subject>Radiation</subject><subject>Scanning electron microscopy</subject><subject>Sensors</subject><subject>Spectrum analysis</subject><subject>Spray pyrolysis</subject><subject>Structural analysis</subject><subject>Temperature</subject><subject>Thin films</subject><subject>X-ray diffraction</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9UMtOwzAQtBBIlMIPcLLEOeBX4viIEC-p0ANwNk6yaV0ldrBTUP8elyBx47DalXZmdmcQOqfkkhIiryJlhIuMMJpKEJHJAzQjSvJMFoU6TDPLSSYkkcfoJMYNIVQJQWfo_cX2Qwc4-O0IuIHBRzta77BxDY6-Bzysd9HWpsPWfUIc7crs9xEnjDPOt53_goCf7ZNfChyHYHbQ4HFtHW5t18dTdNSaLsLZb5-jt7vb15uHbLG8f7y5XmQ1p2rMWAOirPK6gsKUzEBrJOfGKBBFTWjeGlA5K6tK0JwXpSqhEKqUnDU5V02bSz5HF5PuEPzHNj2qN34bXDqpmUpmpZIiTyg2oergYwzQ6iHY3oSdpkTvk9RTkjolqX-S1HtpPpGSO-tWEP6k_2F9A4I9d2w</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Gassoumi, B</creator><creator>Jaballah, R</creator><creator>Boukhachem, A</creator><creator>Kamoun-Turki, N</creator><creator>Amlouk, M</creator><general>Indian Academy of Sciences</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0003-2030-483X</orcidid></search><sort><creationdate>20210601</creationdate><title>Simple route deposition and some physical investigations on nanoflower NiMoO4 sprayed thin films</title><author>Gassoumi, B ; Jaballah, R ; Boukhachem, A ; Kamoun-Turki, N ; Amlouk, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-2de48b5cbe6a82aefa733aa9e46c015fae9528bb41536898e6498732d539df573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Ammonium molybdate</topic><topic>Catalysis</topic><topic>Chemistry and Materials Science</topic><topic>Crystal defects</topic><topic>Engineering</topic><topic>Glass substrates</topic><topic>Materials Science</topic><topic>Metal oxides</topic><topic>Molybdates</topic><topic>Molybdenum</topic><topic>Nickel chloride</topic><topic>Nickel compounds</topic><topic>Optical properties</topic><topic>Photoluminescence</topic><topic>Radiation</topic><topic>Scanning electron microscopy</topic><topic>Sensors</topic><topic>Spectrum analysis</topic><topic>Spray pyrolysis</topic><topic>Structural analysis</topic><topic>Temperature</topic><topic>Thin films</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gassoumi, B</creatorcontrib><creatorcontrib>Jaballah, R</creatorcontrib><creatorcontrib>Boukhachem, A</creatorcontrib><creatorcontrib>Kamoun-Turki, N</creatorcontrib><creatorcontrib>Amlouk, M</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Bulletin of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gassoumi, B</au><au>Jaballah, R</au><au>Boukhachem, A</au><au>Kamoun-Turki, N</au><au>Amlouk, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Simple route deposition and some physical investigations on nanoflower NiMoO4 sprayed thin films</atitle><jtitle>Bulletin of materials science</jtitle><stitle>Bull Mater Sci</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>44</volume><issue>2</issue><spage>128</spage><pages>128-</pages><artnum>128</artnum><issn>0250-4707</issn><eissn>0973-7669</eissn><abstract>Nickel molybdate (NiMoO
4
) thin film has been prepared by the spray pyrolysis method, using nickel chloride hexahydrate (NiCl
2
·6H
2
O) and ammonium molybdate tetrahydrate [(NH
4
) 6Mo
7
O
24
·4H
2
O] as precursors in the aqueous starting solution. First, the structure and the surface morphology characterizations were carried out by scanning electron spectroscopy (SEM), Raman and X-ray diffraction (XRD) techniques. Structural analysis by using XRD technique shows that the NiMoO
4
thin film crystallizes in the monoclinic phase, mainly orientation along (110), (021), (
2
¯
04
), (220), (150) and (
1
¯
52
), directions. In addition to these studies, the stoichiometric composition has been reached by the energy dispersion analysis technique. Second, the optical properties have been studied by means of the reflectance and the transmittance spectra, in the wavelength range of 300–1800 nm. This study shows a direct transition of this ternary oxide with an optical bandgap about 3.12 eV and Urbach energy
E
U
in the order of 663 meV. Finally, the photoluminescence emission spectrum of the NiMoO
4
thin film showed emissions peaks in the violet and blue regions and others emission related to some defects in the prepared film.</abstract><cop>Bangalore</cop><pub>Indian Academy of Sciences</pub><doi>10.1007/s12034-021-02404-7</doi><orcidid>https://orcid.org/0000-0003-2030-483X</orcidid></addata></record> |
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| issn | 0250-4707 0973-7669 |
| language | eng |
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| source | Indian Academy of Sciences; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Ammonium molybdate Catalysis Chemistry and Materials Science Crystal defects Engineering Glass substrates Materials Science Metal oxides Molybdates Molybdenum Nickel chloride Nickel compounds Optical properties Photoluminescence Radiation Scanning electron microscopy Sensors Spectrum analysis Spray pyrolysis Structural analysis Temperature Thin films X-ray diffraction |
| title | Simple route deposition and some physical investigations on nanoflower NiMoO4 sprayed thin films |
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