Investigating the Absorption and Desorption Behavior of Methylene Chloride in the Poly(aryl ether ketone) Film with Different Crystallinities
Poly(aryl ether ketone) (PAEK) films with different crystallinities were obtained by controlling the cooling rate, which were subjected to the absorption and desorption of methylene chloride (CH 2 Cl 2 ). We employed attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy anal...
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Veröffentlicht in: | Chinese journal of polymer science 2024-02, Vol.42 (2), p.239-246 |
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creator | Yang, Hong-Ru Zhang, Jin-Dong Gao, Dong-Ting Liu, Gang Chen, Chun-Hai Yao, Jia-Nan |
description | Poly(aryl ether ketone) (PAEK) films with different crystallinities were obtained by controlling the cooling rate, which were subjected to the absorption and desorption of methylene chloride (CH
2
Cl
2
). We employed attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy analyses to investigate the diffusion behavior of CH
2
Cl
2
in PAEK films with different crystallinities. According to the Fickian diffusion model, the calculated diffusion coefficients of CH
2
Cl
2
in PAEK films were observed to decrease with increasing crystallinity. The effect of CH
2
Cl
2
absorption and desorption on the mechanical properties of PAEK films with different crystallinity was further analyzed using tensile tests. The tensile tests exhibited that CH
2
Cl
2
has two concurrent effects: plasticization and solvent-induced crystallization. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WXRD) techniques further confirmed solvent-induced crystallization behavior. The results would be beneficial to understand the solvent resistance of PAEK materials and consequently provide the practical application conditions of PAEK with a theoretical basis. |
doi_str_mv | 10.1007/s10118-023-3046-8 |
format | Article |
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2
Cl
2
). We employed attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy analyses to investigate the diffusion behavior of CH
2
Cl
2
in PAEK films with different crystallinities. According to the Fickian diffusion model, the calculated diffusion coefficients of CH
2
Cl
2
in PAEK films were observed to decrease with increasing crystallinity. The effect of CH
2
Cl
2
absorption and desorption on the mechanical properties of PAEK films with different crystallinity was further analyzed using tensile tests. The tensile tests exhibited that CH
2
Cl
2
has two concurrent effects: plasticization and solvent-induced crystallization. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WXRD) techniques further confirmed solvent-induced crystallization behavior. The results would be beneficial to understand the solvent resistance of PAEK materials and consequently provide the practical application conditions of PAEK with a theoretical basis.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-023-3046-8</identifier><language>eng</language><publisher>Singapore: Springer Nature Singapore</publisher><subject>Absorption ; Aromatic compounds ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Chlorides ; Condensed Matter Physics ; Cooling rate ; Corrosion resistance ; Crystallinity ; Crystallization ; Desorption ; Dichloromethane ; Fourier transforms ; Industrial Chemistry/Chemical Engineering ; Infrared analysis ; Infrared reflection ; Ketones ; Mechanical properties ; Polyaryletherketones ; Polymer Sciences ; Research Article ; Solvents ; Tensile tests</subject><ispartof>Chinese journal of polymer science, 2024-02, Vol.42 (2), p.239-246</ispartof><rights>Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2023</rights><rights>Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-90d16b4be805137b54b50146db1f5978f682ad5de4e67831283789fcd471c2773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-023-3046-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-023-3046-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Yang, Hong-Ru</creatorcontrib><creatorcontrib>Zhang, Jin-Dong</creatorcontrib><creatorcontrib>Gao, Dong-Ting</creatorcontrib><creatorcontrib>Liu, Gang</creatorcontrib><creatorcontrib>Chen, Chun-Hai</creatorcontrib><creatorcontrib>Yao, Jia-Nan</creatorcontrib><title>Investigating the Absorption and Desorption Behavior of Methylene Chloride in the Poly(aryl ether ketone) Film with Different Crystallinities</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><description>Poly(aryl ether ketone) (PAEK) films with different crystallinities were obtained by controlling the cooling rate, which were subjected to the absorption and desorption of methylene chloride (CH
2
Cl
2
). We employed attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy analyses to investigate the diffusion behavior of CH
2
Cl
2
in PAEK films with different crystallinities. According to the Fickian diffusion model, the calculated diffusion coefficients of CH
2
Cl
2
in PAEK films were observed to decrease with increasing crystallinity. The effect of CH
2
Cl
2
absorption and desorption on the mechanical properties of PAEK films with different crystallinity was further analyzed using tensile tests. The tensile tests exhibited that CH
2
Cl
2
has two concurrent effects: plasticization and solvent-induced crystallization. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WXRD) techniques further confirmed solvent-induced crystallization behavior. The results would be beneficial to understand the solvent resistance of PAEK materials and consequently provide the practical application conditions of PAEK with a theoretical basis.</description><subject>Absorption</subject><subject>Aromatic compounds</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Condensed Matter Physics</subject><subject>Cooling rate</subject><subject>Corrosion resistance</subject><subject>Crystallinity</subject><subject>Crystallization</subject><subject>Desorption</subject><subject>Dichloromethane</subject><subject>Fourier transforms</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared analysis</subject><subject>Infrared reflection</subject><subject>Ketones</subject><subject>Mechanical properties</subject><subject>Polyaryletherketones</subject><subject>Polymer Sciences</subject><subject>Research Article</subject><subject>Solvents</subject><subject>Tensile tests</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE1PGzEQhq2KSgTaH9CbJS70sNRjrz_2mCaFRkoFBzhbu9nZrNONHWxDlR_Bf2ZDKnrqaTTS87yjeQn5AuwKGNPfEjAAUzAuCsFKVZgPZAKlqArFmTghE8alKrTS1Sk5S2nDmCq11BPysvDPmLJb19n5Nc090mmTQtxlFzytfUvn-L5-x75-diHS0NFfmPv9gB7prB9CdC1S59_8uzDsL-u4H-iIYKS_MQePX-m1G7b0j8s9nbuuw4g-01ncp1wPg_MuO0yfyMeuHhJ-_jvPycP1j_vZz2J5e7OYTZfFiiuTi4q1oJqyQcMkCN3IspEMStU20MlKm04ZXreyxRKVNgK4EdpU3aotNay41uKcXBxzdzE8Po3_2014in48aXkFFQgFUo4UHKlVDClF7Owuuu34mQVmD63bY-t2bN0eWrdmdPjRSSPr1xj_Jf9fegU-6YZP</recordid><startdate>20240201</startdate><enddate>20240201</enddate><creator>Yang, Hong-Ru</creator><creator>Zhang, Jin-Dong</creator><creator>Gao, Dong-Ting</creator><creator>Liu, Gang</creator><creator>Chen, Chun-Hai</creator><creator>Yao, Jia-Nan</creator><general>Springer Nature Singapore</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240201</creationdate><title>Investigating the Absorption and Desorption Behavior of Methylene Chloride in the Poly(aryl ether ketone) Film with Different Crystallinities</title><author>Yang, Hong-Ru ; Zhang, Jin-Dong ; Gao, Dong-Ting ; Liu, Gang ; Chen, Chun-Hai ; Yao, Jia-Nan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-90d16b4be805137b54b50146db1f5978f682ad5de4e67831283789fcd471c2773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Absorption</topic><topic>Aromatic compounds</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorides</topic><topic>Condensed Matter Physics</topic><topic>Cooling rate</topic><topic>Corrosion resistance</topic><topic>Crystallinity</topic><topic>Crystallization</topic><topic>Desorption</topic><topic>Dichloromethane</topic><topic>Fourier transforms</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared analysis</topic><topic>Infrared reflection</topic><topic>Ketones</topic><topic>Mechanical properties</topic><topic>Polyaryletherketones</topic><topic>Polymer Sciences</topic><topic>Research Article</topic><topic>Solvents</topic><topic>Tensile tests</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Hong-Ru</creatorcontrib><creatorcontrib>Zhang, Jin-Dong</creatorcontrib><creatorcontrib>Gao, Dong-Ting</creatorcontrib><creatorcontrib>Liu, Gang</creatorcontrib><creatorcontrib>Chen, Chun-Hai</creatorcontrib><creatorcontrib>Yao, Jia-Nan</creatorcontrib><collection>CrossRef</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Hong-Ru</au><au>Zhang, Jin-Dong</au><au>Gao, Dong-Ting</au><au>Liu, Gang</au><au>Chen, Chun-Hai</au><au>Yao, Jia-Nan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigating the Absorption and Desorption Behavior of Methylene Chloride in the Poly(aryl ether ketone) Film with Different Crystallinities</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><date>2024-02-01</date><risdate>2024</risdate><volume>42</volume><issue>2</issue><spage>239</spage><epage>246</epage><pages>239-246</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>Poly(aryl ether ketone) (PAEK) films with different crystallinities were obtained by controlling the cooling rate, which were subjected to the absorption and desorption of methylene chloride (CH
2
Cl
2
). We employed attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy analyses to investigate the diffusion behavior of CH
2
Cl
2
in PAEK films with different crystallinities. According to the Fickian diffusion model, the calculated diffusion coefficients of CH
2
Cl
2
in PAEK films were observed to decrease with increasing crystallinity. The effect of CH
2
Cl
2
absorption and desorption on the mechanical properties of PAEK films with different crystallinity was further analyzed using tensile tests. The tensile tests exhibited that CH
2
Cl
2
has two concurrent effects: plasticization and solvent-induced crystallization. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WXRD) techniques further confirmed solvent-induced crystallization behavior. The results would be beneficial to understand the solvent resistance of PAEK materials and consequently provide the practical application conditions of PAEK with a theoretical basis.</abstract><cop>Singapore</cop><pub>Springer Nature Singapore</pub><doi>10.1007/s10118-023-3046-8</doi><tpages>8</tpages></addata></record> |
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source | Springer Nature - Complete Springer Journals; Alma/SFX Local Collection |
subjects | Absorption Aromatic compounds Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chlorides Condensed Matter Physics Cooling rate Corrosion resistance Crystallinity Crystallization Desorption Dichloromethane Fourier transforms Industrial Chemistry/Chemical Engineering Infrared analysis Infrared reflection Ketones Mechanical properties Polyaryletherketones Polymer Sciences Research Article Solvents Tensile tests |
title | Investigating the Absorption and Desorption Behavior of Methylene Chloride in the Poly(aryl ether ketone) Film with Different Crystallinities |
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