Reaction of Chloroethynylphosphonates with Diethyl 2-(Acylamino)propane-1,3-dioates
Reaction of 2-(acylamino)malonic acids esters with chloroethynylphosphonates yielded 2-substituted (5 E / Z )-5-(dialkoxyphosphoryl)methylidene-2-oxazoline-4,4-dicarboxylates, isomers of which could be separated. Following reaction of hydrolysis and decarboxylation affords 2-substituted 5-(dialkoxyp...
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Veröffentlicht in: | Russian journal of general chemistry 2023-12, Vol.93 (12), p.3089-3100 |
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container_title | Russian journal of general chemistry |
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creator | Viktorov, N. B. Dogadina, A. V. Stepakov, A. V. |
description | Reaction of 2-(acylamino)malonic acids esters with chloroethynylphosphonates yielded 2-substituted (5
E
/
Z
)-5-(dialkoxyphosphoryl)methylidene-2-oxazoline-4,4-dicarboxylates, isomers of which could be separated. Following reaction of hydrolysis and decarboxylation affords 2-substituted 5-(dialkoxyphosphoryl)methyl-1,3-oxazole-4-carboxylates. |
doi_str_mv | 10.1134/S1070363223120083 |
format | Article |
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E
/
Z
)-5-(dialkoxyphosphoryl)methylidene-2-oxazoline-4,4-dicarboxylates, isomers of which could be separated. Following reaction of hydrolysis and decarboxylation affords 2-substituted 5-(dialkoxyphosphoryl)methyl-1,3-oxazole-4-carboxylates.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363223120083</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Carboxylates ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Decarboxylation ; Esters ; Hydrolysis ; Oxazole ; Oxazoles ; Propane ; Substitutes</subject><ispartof>Russian journal of general chemistry, 2023-12, Vol.93 (12), p.3089-3100</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>COPYRIGHT 2023 Springer</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-3ee117f14ef157b9f5f1a6046e8f17250a69c8119cb5cad566cf3318b00bd4b33</citedby><cites>FETCH-LOGICAL-c355t-3ee117f14ef157b9f5f1a6046e8f17250a69c8119cb5cad566cf3318b00bd4b33</cites><orcidid>0000-0001-9470-1710 ; 0000-0002-8369-2537 ; 0000-0002-2853-0324</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363223120083$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363223120083$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Viktorov, N. B.</creatorcontrib><creatorcontrib>Dogadina, A. V.</creatorcontrib><creatorcontrib>Stepakov, A. V.</creatorcontrib><title>Reaction of Chloroethynylphosphonates with Diethyl 2-(Acylamino)propane-1,3-dioates</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Reaction of 2-(acylamino)malonic acids esters with chloroethynylphosphonates yielded 2-substituted (5
E
/
Z
)-5-(dialkoxyphosphoryl)methylidene-2-oxazoline-4,4-dicarboxylates, isomers of which could be separated. Following reaction of hydrolysis and decarboxylation affords 2-substituted 5-(dialkoxyphosphoryl)methyl-1,3-oxazole-4-carboxylates.</description><subject>Carboxylates</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Decarboxylation</subject><subject>Esters</subject><subject>Hydrolysis</subject><subject>Oxazole</subject><subject>Oxazoles</subject><subject>Propane</subject><subject>Substitutes</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxRdRsFY_gLcFLwpunUk22fRY6l8oCFbPSzZN2pRtUpMt0m9vygoeRMKQMO_9Jo_JskuEESIt7-YIFVBOCaFIAAQ9ygbIQRSUMjhO7yQXB_00O4txDYAAnAyy-ZuWqrPe5d7k01Xrg9fdau_27XblYyonOx3zL9ut8nt7kNqcFNcTtW_lxjp_sw1-K50u8JYWC-sP7vPsxMg26oufe5h9PD68T5-L2evTy3QyKxRlrCuo1oiVwVIbZFUzNsyg5FByLQxWhIHkYyUQx6phSi4Y58pQiqIBaBZlQ-kwu-rnpgyfOx27eu13waUvazJGUTHBK5Jco961lK2urTO-C1Kls9Abq7zTxqb-pBLARMWBJQB7QAUfY9Cm3ga7kWFfI9SHZdd_lp0Y0jMxed1Sh98o_0PfpQ1_hQ</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Viktorov, N. B.</creator><creator>Dogadina, A. V.</creator><creator>Stepakov, A. V.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-9470-1710</orcidid><orcidid>https://orcid.org/0000-0002-8369-2537</orcidid><orcidid>https://orcid.org/0000-0002-2853-0324</orcidid></search><sort><creationdate>20231201</creationdate><title>Reaction of Chloroethynylphosphonates with Diethyl 2-(Acylamino)propane-1,3-dioates</title><author>Viktorov, N. B. ; Dogadina, A. V. ; Stepakov, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-3ee117f14ef157b9f5f1a6046e8f17250a69c8119cb5cad566cf3318b00bd4b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carboxylates</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Decarboxylation</topic><topic>Esters</topic><topic>Hydrolysis</topic><topic>Oxazole</topic><topic>Oxazoles</topic><topic>Propane</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Viktorov, N. B.</creatorcontrib><creatorcontrib>Dogadina, A. V.</creatorcontrib><creatorcontrib>Stepakov, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Viktorov, N. B.</au><au>Dogadina, A. V.</au><au>Stepakov, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reaction of Chloroethynylphosphonates with Diethyl 2-(Acylamino)propane-1,3-dioates</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>93</volume><issue>12</issue><spage>3089</spage><epage>3100</epage><pages>3089-3100</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Reaction of 2-(acylamino)malonic acids esters with chloroethynylphosphonates yielded 2-substituted (5
E
/
Z
)-5-(dialkoxyphosphoryl)methylidene-2-oxazoline-4,4-dicarboxylates, isomers of which could be separated. Following reaction of hydrolysis and decarboxylation affords 2-substituted 5-(dialkoxyphosphoryl)methyl-1,3-oxazole-4-carboxylates.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363223120083</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-9470-1710</orcidid><orcidid>https://orcid.org/0000-0002-8369-2537</orcidid><orcidid>https://orcid.org/0000-0002-2853-0324</orcidid></addata></record> |
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subjects | Carboxylates Chemistry Chemistry and Materials Science Chemistry/Food Science Decarboxylation Esters Hydrolysis Oxazole Oxazoles Propane Substitutes |
title | Reaction of Chloroethynylphosphonates with Diethyl 2-(Acylamino)propane-1,3-dioates |
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