Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path risk within an abandoned pesticide manufacturing plant

Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg·kg-1 Cd was found present i...

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Veröffentlicht in:Frontiers of environmental science & engineering 2017-02, Vol.11 (1), p.123-135, Article 12
Hauptverfasser: Huang, Sheng, Zhao, Xin, Sun, Yanqiu, Ma, Jianli, Gao, Xiaofeng, Xie, Tian, Xu, Dongsheng, Yu, Yi, Zhao, Youcai
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container_issue 1
container_start_page 123
container_title Frontiers of environmental science & engineering
container_volume 11
creator Huang, Sheng
Zhao, Xin
Sun, Yanqiu
Ma, Jianli
Gao, Xiaofeng
Xie, Tian
Xu, Dongsheng
Yu, Yi
Zhao, Youcai
description Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg·kg-1 Cd was found present in the wastes, which might originate from phosphorus rocks and industrial sulfuric acid used in pesticide production processes. An average concentration of 979.8 mg·kg-1 dichlorovos and other 11 organophosphorus pesticide were also detected. Relatively high leaching rates of around 4.14‰ were obtained from laboratory simulated ICDW using both glacial acetic acidsodium hydroxide and deionized water. Pesticide pollutants had the strongest tendency to retaining on dry bricks (leaching rate 1.68 9‰) compared to mortar-coatings, etc. due to their different physical characteristics and octanol-water partioning coefficient. Mobility of pesticide from on-site ICDW by water was spatially correlated to waste types, process sections and human activities, with a flux of leaching rate between 5.9‰ to 27.4%. Risk-based corrective action (RBCA) model was used to simulate the risk of contaminated ICDW debris randomly scattered. Oral and demlal ingestion amount by local workers was 9.8 × 10-3 and 1.9 × 10-2 mg.(kg-d)-1, respectively. Potential leaching risk to aquatic systems exceeded the limit for nearly 75% waste. Environmental and health risk exceedance was found in most ICDW, while the risk value of the most severely contaminated brick waste was 660 times beyond critical level. Implications for waste management involving construction and deconstruction work, waste transferring and regulation supplying were also provided.
doi_str_mv 10.1007/s11783-017-0901-2
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Environ. Sci. Eng</addtitle><addtitle>Frontiers of Environmental Science & Engineering in China</addtitle><description>Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg·kg-1 Cd was found present in the wastes, which might originate from phosphorus rocks and industrial sulfuric acid used in pesticide production processes. An average concentration of 979.8 mg·kg-1 dichlorovos and other 11 organophosphorus pesticide were also detected. Relatively high leaching rates of around 4.14‰ were obtained from laboratory simulated ICDW using both glacial acetic acidsodium hydroxide and deionized water. 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Environ. Sci. Eng</stitle><addtitle>Frontiers of Environmental Science & Engineering in China</addtitle><date>2017-02-01</date><risdate>2017</risdate><volume>11</volume><issue>1</issue><spage>123</spage><epage>135</epage><pages>123-135</pages><artnum>12</artnum><issn>2095-2201</issn><eissn>2095-221X</eissn><abstract>Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg·kg-1 Cd was found present in the wastes, which might originate from phosphorus rocks and industrial sulfuric acid used in pesticide production processes. An average concentration of 979.8 mg·kg-1 dichlorovos and other 11 organophosphorus pesticide were also detected. Relatively high leaching rates of around 4.14‰ were obtained from laboratory simulated ICDW using both glacial acetic acidsodium hydroxide and deionized water. Pesticide pollutants had the strongest tendency to retaining on dry bricks (leaching rate 1.68 9‰) compared to mortar-coatings, etc. due to their different physical characteristics and octanol-water partioning coefficient. Mobility of pesticide from on-site ICDW by water was spatially correlated to waste types, process sections and human activities, with a flux of leaching rate between 5.9‰ to 27.4%. Risk-based corrective action (RBCA) model was used to simulate the risk of contaminated ICDW debris randomly scattered. Oral and demlal ingestion amount by local workers was 9.8 × 10-3 and 1.9 × 10-2 mg.(kg-d)-1, respectively. Potential leaching risk to aquatic systems exceeded the limit for nearly 75% waste. Environmental and health risk exceedance was found in most ICDW, while the risk value of the most severely contaminated brick waste was 660 times beyond critical level. Implications for waste management involving construction and deconstruction work, waste transferring and regulation supplying were also provided.</abstract><cop>Beijing</cop><pub>Higher Education Press</pub><doi>10.1007/s11783-017-0901-2</doi><tpages>13</tpages></addata></record>
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ispartof Frontiers of environmental science & engineering, 2017-02, Vol.11 (1), p.123-135, Article 12
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subjects Acetic acid
Aquatic environment
Bricks
Cadmium
Construction industry wastes
Contamination
Deionization
Demolition
Earth and Environmental Science
Environment
Environmental risk
Hazardous materials
Health risks
Heavy metals
Industrial demolition wastes
Industrial pollution
Ingestion
Leaching
Leaching characteristics
Manufacturing
Manufacturing industry
Octanol
Organophosphorus pesticides
Pesticides
Physical characteristics
Physical properties
Pollutants
Research Article
Risk assessment
Sodium hydroxide
Sulfuric acid
Waste disposal
Waste management
Wastes
Water pollution
多路径
工业硫酸
建筑废弃物
有害物质
有机污染物
有机磷农药
正辛醇-水分配系数
环境风险
title Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path risk within an abandoned pesticide manufacturing plant
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