Preparation and electronic characteristics of anionic perylene bisimide films
Neutral perylene bisimides（PBI） are well-known n-type organic semiconductors, with number of challenging electronic properties in their neutral and reduced states. We report the characteristic electronic properties of PBI anionic films. We unexpectedly discovered that pristine PBI dianion film showe...
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| Veröffentlicht in: | Science China. Chemistry 2017-10, Vol.60 (10), p.1334-1339 |
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| container_end_page | 1339 |
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| container_title | Science China. Chemistry |
| container_volume | 60 |
| creator | Zhang, Wenqiang Jiang, Qinglin Zhou, Jiadong Hu, Dehua Zhou, Xuehong Ma, Weitao Hanif, Muddasir Xie, Zengqi Liu, Linlin Ma, Yuguang |
| description | Neutral perylene bisimides（PBI） are well-known n-type organic semiconductors, with number of challenging electronic properties in their neutral and reduced states. We report the characteristic electronic properties of PBI anionic films. We unexpectedly discovered that pristine PBI dianion film showed p-type character, while oxidized dianion film（dominant neutral state with few radical anions） showed normal n-type semiconductor character based on Seebeck effect measurements. Both kinds of films exhibit high electrical conductivity with a potential for thermoelectric applications. The mechanism of polarity reversal is proposed. |
| doi_str_mv | 10.1007/s11426-017-9098-6 |
| format | Article |
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We report the characteristic electronic properties of PBI anionic films. We unexpectedly discovered that pristine PBI dianion film showed p-type character, while oxidized dianion film（dominant neutral state with few radical anions） showed normal n-type semiconductor character based on Seebeck effect measurements. Both kinds of films exhibit high electrical conductivity with a potential for thermoelectric applications. 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Chemistry</title><addtitle>Sci. China Chem</addtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><description>Neutral perylene bisimides（PBI） are well-known n-type organic semiconductors, with number of challenging electronic properties in their neutral and reduced states. We report the characteristic electronic properties of PBI anionic films. We unexpectedly discovered that pristine PBI dianion film showed p-type character, while oxidized dianion film（dominant neutral state with few radical anions） showed normal n-type semiconductor character based on Seebeck effect measurements. Both kinds of films exhibit high electrical conductivity with a potential for thermoelectric applications. 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Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Wenqiang</au><au>Jiang, Qinglin</au><au>Zhou, Jiadong</au><au>Hu, Dehua</au><au>Zhou, Xuehong</au><au>Ma, Weitao</au><au>Hanif, Muddasir</au><au>Xie, Zengqi</au><au>Liu, Linlin</au><au>Ma, Yuguang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and electronic characteristics of anionic perylene bisimide films</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>2017-10-01</date><risdate>2017</risdate><volume>60</volume><issue>10</issue><spage>1334</spage><epage>1339</epage><pages>1334-1339</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>Neutral perylene bisimides（PBI） are well-known n-type organic semiconductors, with number of challenging electronic properties in their neutral and reduced states. We report the characteristic electronic properties of PBI anionic films. We unexpectedly discovered that pristine PBI dianion film showed p-type character, while oxidized dianion film（dominant neutral state with few radical anions） showed normal n-type semiconductor character based on Seebeck effect measurements. Both kinds of films exhibit high electrical conductivity with a potential for thermoelectric applications. The mechanism of polarity reversal is proposed.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-017-9098-6</doi><tpages>6</tpages></addata></record> |
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| subjects | Anions Chemistry Chemistry and Materials Science Chemistry/Food Science Electrical resistivity Electronic properties Glass substrates Investigations Measurement techniques N-type semiconductors Organic semiconductors Seebeck effect Semiconductors 制备 半导体特性 塞贝克效应 有机半导体材料 电学特性 苝酰亚胺 薄膜 阴离子膜 |
| title | Preparation and electronic characteristics of anionic perylene bisimide films |
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