Cu/photoredox-catalyzed decarboxylative radical C(sp3)-C(sp3) cross-coupling reactions

A radical decarboxylative C(sp 3 )-C(sp 3 ) cross-coupling of NHPI esters and cyclopropanols was developed by combining photocatalysis and copper catalysis, which presents the efficient access to β-benzyl ketones in excellent yields. Terpyridin-4′-one used as the ligand is vital for the reaction, wh...

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Veröffentlicht in:	Science China. Chemistry 2023-10, Vol.66 (10), p.2858-2862
Hauptverfasser:	Jiang, Chao, Chen, Pinhong, Liu, Guosheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Carbon Catalysis Chemical reactions Chemistry Chemistry and Materials Science Chemistry/Food Science Copper Cross coupling Esters Functional groups Ketones Ligands Light emitting diodes Photocatalysis Photoredox catalysis Reagents Ring opening Substrates
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