Fine-tuning hydroxylamines as single-nitrogen sources for Pd(0)-catalyzed diamination of o-bromo(or chloro)-biaryls

Transition metal-catalyzed diamination by hydroxylamines is a common approach for making three-membered aziridines, while its use for building the larger N -heterocycles is still underdeveloped. Herein, we report an efficient Pd(0)-catalyzed inter-molecular [4+1] annulation of o -bromo(or chloro)-bi...

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Veröffentlicht in:Science China. Chemistry 2022-04, Vol.65 (4), p.686-693
Hauptverfasser: Ding, Pin, Han, Lingbo, Bai, Jiaxing, Liu, Jingjing, Luan, Xinjun
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Sprache:eng
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