Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers
A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The structures of polymers are characterized by means of FT-IR, 1 H NMR spectroscopy,...
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| Veröffentlicht in: | Science China. Chemistry 2008-03, Vol.51 (3), p.275-281 |
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| container_title | Science China. Chemistry |
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| creator | Chang, GuanJun Tang, ShiZhen Luo, Xuan Wang, Qiang Xu, Zhe Zhang, Lin Lin, RunXiong |
| description | A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The structures of polymers are characterized by means of FT-IR,
1
H NMR spectroscopy, and elemental analysis. The results show an agreement with the proposed structures. DSC and TG measurements show that polymers possess high glass transition temperature (
T
g
>170°C) and good thermal stability with high decomposition temperatures (
T
D
>450°C). These novel polymers also exhibit good mechanical behaviors and good solubility. |
| doi_str_mv | 10.1007/s11426-008-0033-4 |
| format | Article |
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1
H NMR spectroscopy, and elemental analysis. The results show an agreement with the proposed structures. DSC and TG measurements show that polymers possess high glass transition temperature (
T
g
>170°C) and good thermal stability with high decomposition temperatures (
T
D
>450°C). These novel polymers also exhibit good mechanical behaviors and good solubility.</description><identifier>ISSN: 1006-9291</identifier><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1862-2771</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-008-0033-4</identifier><language>eng</language><publisher>Beijing: Science in China Press</publisher><subject>Aromatic compounds ; Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Condensation polymerization ; Diamines ; Dibromides ; Glass transition temperature ; Infrared spectroscopy ; Ketones ; NMR spectroscopy ; Palladium ; Polymers ; Thermal stability</subject><ispartof>Science China. Chemistry, 2008-03, Vol.51 (3), p.275-281</ispartof><rights>Science in China Press 2008</rights><rights>Science in China Press 2008.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-241a3a2d8767714b000a654a804b8f2188a379d99f237d30ba342832e84978c3</citedby><cites>FETCH-LOGICAL-c316t-241a3a2d8767714b000a654a804b8f2188a379d99f237d30ba342832e84978c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11426-008-0033-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918608795?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,21389,21390,21391,23256,27924,27925,33530,33703,33744,34005,34314,41488,42557,43659,43787,43805,43953,44067,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Chang, GuanJun</creatorcontrib><creatorcontrib>Tang, ShiZhen</creatorcontrib><creatorcontrib>Luo, Xuan</creatorcontrib><creatorcontrib>Wang, Qiang</creatorcontrib><creatorcontrib>Xu, Zhe</creatorcontrib><creatorcontrib>Zhang, Lin</creatorcontrib><creatorcontrib>Lin, RunXiong</creatorcontrib><title>Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers</title><title>Science China. Chemistry</title><addtitle>Sci. China Ser. B-Chem</addtitle><description>A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The structures of polymers are characterized by means of FT-IR,
1
H NMR spectroscopy, and elemental analysis. The results show an agreement with the proposed structures. DSC and TG measurements show that polymers possess high glass transition temperature (
T
g
>170°C) and good thermal stability with high decomposition temperatures (
T
D
>450°C). These novel polymers also exhibit good mechanical behaviors and good solubility.</description><subject>Aromatic compounds</subject><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Condensation polymerization</subject><subject>Diamines</subject><subject>Dibromides</subject><subject>Glass transition temperature</subject><subject>Infrared spectroscopy</subject><subject>Ketones</subject><subject>NMR spectroscopy</subject><subject>Palladium</subject><subject>Polymers</subject><subject>Thermal stability</subject><issn>1006-9291</issn><issn>1674-7291</issn><issn>1862-2771</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kD1PwzAQhi0EEqXwA9gsscBgOH80tkdU8SVVYqC75SROm5LYwU6R-u9xFSQmhtPd8D53974IXVO4pwDyIVEqWEEAVC7OiThBM6oKRpiU9DTPAAXRTNNzdJHSDkAIUDBD5uPgx61LbcLW13iIYXBxbF3CocE-fLsOp9Dty87hIXSHWxsPHbZ96x3-dGPw7i6DCW_bzZZksgmxt76axL2L6RKdNbZL7uq3z9H6-Wm9fCWr95e35eOKVJwWI2GCWm5ZrWSR_xUlANhiIawCUaqGUaUsl7rWumFc1hxKywVTnDkltFQVn6ObaW028LV3aTS7sI8-XzTZsypASb3IKjqpqhhSiq4xQ2z7bMlQMMcYzRSjyTGaY4xGZIZNTMpav3Hxb_P_0A8QJHSv</recordid><startdate>20080301</startdate><enddate>20080301</enddate><creator>Chang, GuanJun</creator><creator>Tang, ShiZhen</creator><creator>Luo, Xuan</creator><creator>Wang, Qiang</creator><creator>Xu, Zhe</creator><creator>Zhang, Lin</creator><creator>Lin, RunXiong</creator><general>Science in China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20080301</creationdate><title>Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers</title><author>Chang, GuanJun ; 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The structures of polymers are characterized by means of FT-IR,
1
H NMR spectroscopy, and elemental analysis. The results show an agreement with the proposed structures. DSC and TG measurements show that polymers possess high glass transition temperature (
T
g
>170°C) and good thermal stability with high decomposition temperatures (
T
D
>450°C). These novel polymers also exhibit good mechanical behaviors and good solubility.</abstract><cop>Beijing</cop><pub>Science in China Press</pub><doi>10.1007/s11426-008-0033-4</doi><tpages>7</tpages></addata></record> |
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| subjects | Aromatic compounds Chemical analysis Chemistry Chemistry and Materials Science Chemistry/Food Science Condensation polymerization Diamines Dibromides Glass transition temperature Infrared spectroscopy Ketones NMR spectroscopy Palladium Polymers Thermal stability |
| title | Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers |
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