Phase behavior and interfacial properties of symmetric polymeric ternary blends A/B/AB
In this paper, the phase behavior and interracial properties of symmetric ternary polymeric blends A/B/AB are studied by dissipative particle dynamics (DPD) simulations. By using the structure factor and nematic order parameter, we carefully characterized the diversified phases and phase transitions...
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Veröffentlicht in: | Science China. Chemistry 2013-12, Vol.56 (12), p.1710-1721 |
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description | In this paper, the phase behavior and interracial properties of symmetric ternary polymeric blends A/B/AB are studied by dissipative particle dynamics (DPD) simulations. By using the structure factor and nematic order parameter, we carefully characterized the diversified phases and phase transitions, and established the phase diagram of such symmetric ternary blends. It can be generally divided into four regions: disordered phase (DIS) region at high temperature, ordered lameUar phase (LAM) region, bicontinuous microemulsion (BμE) channel and phase-separated phase (2P) region at low temperature with the increase of the total volume fractions of homopolymers φn, which shows good accordance with that in previous experimental and theoretical reports. Furthermore, we calculated the elastic constants of 2P and LAM phase, and discussed the transition mechanisms from 2P and LAM to BμE phase, respectively. The results show a direct relevance between the phase transitions and the change of interfacial properties. Finally, we also demonstrate that the B,uE channel becomes narrower in lower temperature caused by the temperature dependence of interfacial properties of ternary blends. |
doi_str_mv | 10.1007/s11426-013-4928-3 |
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By using the structure factor and nematic order parameter, we carefully characterized the diversified phases and phase transitions, and established the phase diagram of such symmetric ternary blends. It can be generally divided into four regions: disordered phase (DIS) region at high temperature, ordered lameUar phase (LAM) region, bicontinuous microemulsion (BμE) channel and phase-separated phase (2P) region at low temperature with the increase of the total volume fractions of homopolymers φn, which shows good accordance with that in previous experimental and theoretical reports. Furthermore, we calculated the elastic constants of 2P and LAM phase, and discussed the transition mechanisms from 2P and LAM to BμE phase, respectively. The results show a direct relevance between the phase transitions and the change of interfacial properties. Finally, we also demonstrate that the B,uE channel becomes narrower in lower temperature caused by the temperature dependence of interfacial properties of ternary blends.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-013-4928-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Dissipation factor ; Dynamic structural analysis ; Elastic properties ; High temperature ; Interfacial properties ; Low temperature ; Order parameters ; Phase diagrams ; Phase transitions ; Polymer blends ; Structure factor ; Temperature dependence ; 三元共混物 ; 三元聚合物 ; 体积分数 ; 子动力学 ; 对称 ; 界面性能 ; 界面性质 ; 相行为</subject><ispartof>Science China. Chemistry, 2013-12, Vol.56 (12), p.1710-1721</ispartof><rights>Science China Press and Springer-Verlag Berlin Heidelberg 2013</rights><rights>Science China Press and Springer-Verlag Berlin Heidelberg 2013.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-9e4b3cac4ac6e4707a26b77e05020bb7d6e9a53e81abb3f683c3bd1da22578b43</citedby><cites>FETCH-LOGICAL-c342t-9e4b3cac4ac6e4707a26b77e05020bb7d6e9a53e81abb3f683c3bd1da22578b43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/60113X/60113X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11426-013-4928-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918587587?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,21389,21390,21391,23256,27924,27925,33530,33703,33744,34005,34314,41488,42557,43659,43787,43805,43953,44067,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Liu, XiaoHan</creatorcontrib><creatorcontrib>Bai, ZhiQiang</creatorcontrib><creatorcontrib>Yang, KeDa</creatorcontrib><creatorcontrib>Su, JiaYe</creatorcontrib><creatorcontrib>Guo, HongXia</creatorcontrib><title>Phase behavior and interfacial properties of symmetric polymeric ternary blends A/B/AB</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><description>In this paper, the phase behavior and interracial properties of symmetric ternary polymeric blends A/B/AB are studied by dissipative particle dynamics (DPD) simulations. By using the structure factor and nematic order parameter, we carefully characterized the diversified phases and phase transitions, and established the phase diagram of such symmetric ternary blends. It can be generally divided into four regions: disordered phase (DIS) region at high temperature, ordered lameUar phase (LAM) region, bicontinuous microemulsion (BμE) channel and phase-separated phase (2P) region at low temperature with the increase of the total volume fractions of homopolymers φn, which shows good accordance with that in previous experimental and theoretical reports. Furthermore, we calculated the elastic constants of 2P and LAM phase, and discussed the transition mechanisms from 2P and LAM to BμE phase, respectively. The results show a direct relevance between the phase transitions and the change of interfacial properties. Finally, we also demonstrate that the B,uE channel becomes narrower in lower temperature caused by the temperature dependence of interfacial properties of ternary blends.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Dissipation factor</subject><subject>Dynamic structural analysis</subject><subject>Elastic properties</subject><subject>High temperature</subject><subject>Interfacial properties</subject><subject>Low temperature</subject><subject>Order parameters</subject><subject>Phase diagrams</subject><subject>Phase transitions</subject><subject>Polymer blends</subject><subject>Structure factor</subject><subject>Temperature dependence</subject><subject>三元共混物</subject><subject>三元聚合物</subject><subject>体积分数</subject><subject>子动力学</subject><subject>对称</subject><subject>界面性能</subject><subject>界面性质</subject><subject>相行为</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9UMtOwzAQtBBIVKUfwM2Ic6hfiZ1jW_GSKsEBuFq2s2lT5VU7Rerf4yoV3FittHuY2ZkdhG4peaCEyHmgVLAsIZQnImcq4RdoQlWWJ1RJchn3TIpEspxeo1kIOxKLc8JkOkFf71sTAFvYmu-q89i0Ba7aAXxpXGVq3PuuBz9UEHBX4nBsGhh85XDf1ccGTlvEtsYfsa2hLQJezJfzxfIGXZWmDjA7zyn6fHr8WL0k67fn19VinTgu2JDkICx3xgnjMhCSSMMyKyWQlDBirSwyyE3KQVFjLS8zxR23BS0MY6lUVvApuh_vRp_7A4RB77pD9FMHHd9VqZKxI4qOKOe7EDyUuvdVE01rSvQpQT0mqGOC-pSg5pHDRk6I2HYD_u_yf6S7s9C2azf7yPtVEjLnlAnBfwBEMH6N</recordid><startdate>20131201</startdate><enddate>20131201</enddate><creator>Liu, XiaoHan</creator><creator>Bai, ZhiQiang</creator><creator>Yang, KeDa</creator><creator>Su, JiaYe</creator><creator>Guo, HongXia</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20131201</creationdate><title>Phase behavior and interfacial properties of symmetric polymeric ternary blends A/B/AB</title><author>Liu, XiaoHan ; Bai, ZhiQiang ; Yang, KeDa ; Su, JiaYe ; Guo, HongXia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-9e4b3cac4ac6e4707a26b77e05020bb7d6e9a53e81abb3f683c3bd1da22578b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Dissipation factor</topic><topic>Dynamic structural analysis</topic><topic>Elastic properties</topic><topic>High temperature</topic><topic>Interfacial properties</topic><topic>Low temperature</topic><topic>Order parameters</topic><topic>Phase diagrams</topic><topic>Phase transitions</topic><topic>Polymer blends</topic><topic>Structure factor</topic><topic>Temperature dependence</topic><topic>三元共混物</topic><topic>三元聚合物</topic><topic>体积分数</topic><topic>子动力学</topic><topic>对称</topic><topic>界面性能</topic><topic>界面性质</topic><topic>相行为</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, XiaoHan</creatorcontrib><creatorcontrib>Bai, ZhiQiang</creatorcontrib><creatorcontrib>Yang, KeDa</creatorcontrib><creatorcontrib>Su, JiaYe</creatorcontrib><creatorcontrib>Guo, HongXia</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, XiaoHan</au><au>Bai, ZhiQiang</au><au>Yang, KeDa</au><au>Su, JiaYe</au><au>Guo, HongXia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phase behavior and interfacial properties of symmetric polymeric ternary blends A/B/AB</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>2013-12-01</date><risdate>2013</risdate><volume>56</volume><issue>12</issue><spage>1710</spage><epage>1721</epage><pages>1710-1721</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>In this paper, the phase behavior and interracial properties of symmetric ternary polymeric blends A/B/AB are studied by dissipative particle dynamics (DPD) simulations. By using the structure factor and nematic order parameter, we carefully characterized the diversified phases and phase transitions, and established the phase diagram of such symmetric ternary blends. It can be generally divided into four regions: disordered phase (DIS) region at high temperature, ordered lameUar phase (LAM) region, bicontinuous microemulsion (BμE) channel and phase-separated phase (2P) region at low temperature with the increase of the total volume fractions of homopolymers φn, which shows good accordance with that in previous experimental and theoretical reports. Furthermore, we calculated the elastic constants of 2P and LAM phase, and discussed the transition mechanisms from 2P and LAM to BμE phase, respectively. The results show a direct relevance between the phase transitions and the change of interfacial properties. Finally, we also demonstrate that the B,uE channel becomes narrower in lower temperature caused by the temperature dependence of interfacial properties of ternary blends.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11426-013-4928-3</doi><tpages>12</tpages></addata></record> |
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subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Dissipation factor Dynamic structural analysis Elastic properties High temperature Interfacial properties Low temperature Order parameters Phase diagrams Phase transitions Polymer blends Structure factor Temperature dependence 三元共混物 三元聚合物 体积分数 子动力学 对称 界面性能 界面性质 相行为 |
title | Phase behavior and interfacial properties of symmetric polymeric ternary blends A/B/AB |
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