Advances and challenges in palladium-catalyzed intermolecular selective allylic C-H functionalization of alkenes
During the past decade, there was increased interest in the functionalization of the allylic C-H bond of alkenes. As opposed to traditional Trost-Tsuji reactions, this strategy avoids the prefunctionalization of the alkene. Many transi- tion metals have been used to promote such processes, and palla...
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| Veröffentlicht in: | Science China. Chemistry 2015-08, Vol.58 (8), p.1249-1251 |
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| creator | Qi, Xiaoxu Chen, Pinhong Liu, Guosheng |
| description | During the past decade, there was increased interest in the functionalization of the allylic C-H bond of alkenes. As opposed to traditional Trost-Tsuji reactions, this strategy avoids the prefunctionalization of the alkene. Many transi- tion metals have been used to promote such processes, and palladium has proved to be one of the best catalysts as it offers great advantages from the point of view of substrate scope and selectivity. Therefore, many groundbreaking re- suits obtained with Pd-catalyzed processes have been re- ported, including allylic C-H oxygenation, amination, al- kylation, and other transformations, which have been well documented in reviews [1]. |
| doi_str_mv | 10.1007/s11426-015-5387-9 |
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Chemistry</title><addtitle>Sci. China Chem</addtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><description>During the past decade, there was increased interest in the functionalization of the allylic C-H bond of alkenes. As opposed to traditional Trost-Tsuji reactions, this strategy avoids the prefunctionalization of the alkene. Many transi- tion metals have been used to promote such processes, and palladium has proved to be one of the best catalysts as it offers great advantages from the point of view of substrate scope and selectivity. Therefore, many groundbreaking re- suits obtained with Pd-catalyzed processes have been re- ported, including allylic C-H oxygenation, amination, al- kylation, and other transformations, which have been well documented in reviews [1].</description><subject>C-H键</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Palladium</subject><subject>Perspectives</subject><subject>分子间</subject><subject>和面</subject><subject>官能团化</subject><subject>烯丙基</subject><subject>烯烃</subject><subject>过渡金属</subject><subject>钯催化</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kE9Lw0AQxYMoWGo_gLeg59X9v8mxFLVCwYuel-1m0qamSbubFNpP75QUvbmw7JvhvZnllyT3jD4xSs1zZExyTShTRInMkPwqGbFM54Rlhl6j1kYSw3N2m0xi3FA8QlBu1CjZTYuDazzE1DVF6teurqFZYVk16Q4LV1T9lnjXufp4ggLbHYRtW4PvaxfSCKi66gApeo915dMZmadl32CzbVxdndxZpG2Jhm9oIN4lN6WrI0wu7zj5en35nM3J4uPtfTZdEC-Z6AjkeumVk3m2dEw6yDPJC6WMoIXOQCjpPV4hS6cF49wVwI3MljovOdVGgBgnj8PcXWj3PcTObto-4JeiRRCZQjyco4sNLh_aGAOUdheqrQtHy6g9s7UDW4ts7ZmtzTHDh0xEL7IKf5P_Cz1cFq3bZrXH3O8mrZVSnFIpfgAioYir</recordid><startdate>20150801</startdate><enddate>20150801</enddate><creator>Qi, Xiaoxu</creator><creator>Chen, Pinhong</creator><creator>Liu, Guosheng</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope></search><sort><creationdate>20150801</creationdate><title>Advances and challenges in palladium-catalyzed intermolecular selective allylic C-H functionalization of alkenes</title><author>Qi, Xiaoxu ; Chen, Pinhong ; Liu, Guosheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c413t-e96bc5a498ba14ae9842d55730d68e354cc54c34fa63122ade2748b69f20673e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>C-H键</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Palladium</topic><topic>Perspectives</topic><topic>分子间</topic><topic>和面</topic><topic>官能团化</topic><topic>烯丙基</topic><topic>烯烃</topic><topic>过渡金属</topic><topic>钯催化</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qi, Xiaoxu</creatorcontrib><creatorcontrib>Chen, Pinhong</creatorcontrib><creatorcontrib>Liu, Guosheng</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. 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Many transi- tion metals have been used to promote such processes, and palladium has proved to be one of the best catalysts as it offers great advantages from the point of view of substrate scope and selectivity. Therefore, many groundbreaking re- suits obtained with Pd-catalyzed processes have been re- ported, including allylic C-H oxygenation, amination, al- kylation, and other transformations, which have been well documented in reviews [1].</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-015-5387-9</doi><tpages>3</tpages></addata></record> |
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| subjects | C-H键 Chemistry Chemistry and Materials Science Chemistry/Food Science Palladium Perspectives 分子间 和面 官能团化 烯丙基 烯烃 过渡金属 钯催化 |
| title | Advances and challenges in palladium-catalyzed intermolecular selective allylic C-H functionalization of alkenes |
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