An antiferromagnetic {Mn8} ring supported by planar multidentate ligands
Complexation of the planar multidentate ligand 3,5-bis-（2-hydroxyphenyl）pyrazole （H3L） with manganese chloride leads to the formation of the polynuclear complex [MnIHsL4Oa（MeO）a（MeOH）8] （1）. 1 has an octanuclear macrocyclic core in which the MnnI ions are bridged by four L molecules to form a ring t...
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| Veröffentlicht in: | Science China. Chemistry 2012-06, Vol.55 (6), p.973-977 |
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| container_title | Science China. Chemistry |
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| creator | Newton, Graham N. Shiga, Takuya Oshio, Hiroki |
| description | Complexation of the planar multidentate ligand 3,5-bis-（2-hydroxyphenyl）pyrazole （H3L） with manganese chloride leads to the formation of the polynuclear complex [MnIHsL4Oa（MeO）a（MeOH）8] （1）. 1 has an octanuclear macrocyclic core in which the MnnI ions are bridged by four L molecules to form a ring type structure. Antiferromagnetic interactions were shown to be op- erative between metal centers. |
| doi_str_mv | 10.1007/s11426-012-4548-3 |
| format | Article |
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Chemistry</title><addtitle>Sci. China Chem</addtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><description>Complexation of the planar multidentate ligand 3,5-bis-（2-hydroxyphenyl）pyrazole （H3L） with manganese chloride leads to the formation of the polynuclear complex [MnIHsL4Oa（MeO）a（MeOH）8] （1）. 1 has an octanuclear macrocyclic core in which the MnnI ions are bridged by four L molecules to form a ring type structure. Antiferromagnetic interactions were shown to be op- erative between metal centers.</description><subject>Antiferromagnetism</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Ligands</subject><subject>MEO</subject><subject>Molecular structure</subject><subject>Pyrazole</subject><subject>反铁磁相互作用</subject><subject>多核络合物</subject><subject>多齿配体</subject><subject>平面</subject><subject>环型结构</subject><subject>羟基苯基</subject><subject>金属中心</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9ULtOwzAUtRBIVKUfwBbEbPArsT1WFVCkIhaYLSexQ6rUSW1nqBD_jqMg2LjLvcN53HMAuMboDiPE7wPGjBQQYQJZzgSkZ2CBRSEhFhydp7vgDHIi8SVYhbBHaShFhOcLsF27TLvYWuN9f9CNM7Gtss8XJ74y37omC-Mw9D6aOitP2dBpp312GLvY1sZFHU3WtY12dbgCF1Z3wax-9hK8Pz68bbZw9_r0vFnvYEUZiZDnWtL0jrXYVggJyqnVyJhSl7hkzBhbMVKXhZQIM1saXXLJOZMVS1FqgekS3M66g--PowlR7fvRu2SpUkCRizyXEwrPqMr3IXhj1eDbg_YnhZGaOlNzZyp1pqbOFE0cMnPCMCU3_k_5P9LNj9FH75pj4v06MUJxQhX0G-sfefw</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Newton, Graham N.</creator><creator>Shiga, Takuya</creator><creator>Oshio, Hiroki</creator><general>SP Science China Press</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20120601</creationdate><title>An antiferromagnetic {Mn8} ring supported by planar multidentate ligands</title><author>Newton, Graham N. ; Shiga, Takuya ; Oshio, Hiroki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-75a93674ff1fc008373fa0eebab1b44eefc42db699014fbeab797749c4870d813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Antiferromagnetism</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Ligands</topic><topic>MEO</topic><topic>Molecular structure</topic><topic>Pyrazole</topic><topic>反铁磁相互作用</topic><topic>多核络合物</topic><topic>多齿配体</topic><topic>平面</topic><topic>环型结构</topic><topic>羟基苯基</topic><topic>金属中心</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Newton, Graham N.</creatorcontrib><creatorcontrib>Shiga, Takuya</creatorcontrib><creatorcontrib>Oshio, Hiroki</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. 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| ispartof | Science China. Chemistry, 2012-06, Vol.55 (6), p.973-977 |
| issn | 1674-7291 1869-1870 |
| language | eng |
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| subjects | Antiferromagnetism Chemistry Chemistry and Materials Science Chemistry/Food Science Ligands MEO Molecular structure Pyrazole 反铁磁相互作用 多核络合物 多齿配体 平面 环型结构 羟基苯基 金属中心 |
| title | An antiferromagnetic {Mn8} ring supported by planar multidentate ligands |
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