Coordination behavior of N-benzoylamino acids: Synthesis and structure of mixed-ligand complexes of palladium(Ⅱ) with N-benzoylamino acid dianion and diamine
Four new mixed-ligand complexes of pailadiumt(Ⅱ) with L1(N-benzoyl-α-amino acid dianion) and L2[ethyldiamine (en),2,2’-bipyridine (Bpy) and 1,10-phenanthroline (Phen)] were synthesized.Ail the complexes have been characterized by elemental analyses,molar conductance,infrared and 1H NMR spectra and t...
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| Veröffentlicht in: | Science China. Chemistry 1997-12, Vol.40 (6), p.600-607 |
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| creator | 龚钰秋 陈耀峰 顾建明 胡秀荣 |
| description | Four new mixed-ligand complexes of pailadiumt(Ⅱ) with L1(N-benzoyl-α-amino acid dianion) and L2[ethyldiamine (en),2,2’-bipyridine (Bpy) and 1,10-phenanthroline (Phen)] were synthesized.Ail the complexes have been characterized by elemental analyses,molar conductance,infrared and 1H NMR spectra and therme-gravimetric analyses.Crystal structures of [Pd(Bpy)(Bzval-N,O)] and [Pd(en) (Bzphe-N,O)] H2O have been do termmed by X-ray diffraction analysis.The results indicate that in all the complexes hgand L1 coordinates to palladium (Ⅱ) through deprotonated amide nitrogen and carboxylic oxygen,and there are some intramolecular nonrovalent in teractions in the complexes. |
| doi_str_mv | 10.1007/BF02875478 |
| format | Article |
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Chemistry, 1997-12, Vol.40 (6), p.600-607</ispartof><rights>Science in China Press 1997.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c285t-905c0ec627253fc7065bfcae751ff070665dd84b9c98f15bd9abb94e10aba3623</citedby><cites>FETCH-LOGICAL-c285t-905c0ec627253fc7065bfcae751ff070665dd84b9c98f15bd9abb94e10aba3623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/60113X/60113X.jpg</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/2918585141?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,43781</link.rule.ids></links><search><creatorcontrib>龚钰秋 陈耀峰 顾建明 胡秀荣</creatorcontrib><title>Coordination behavior of N-benzoylamino acids: Synthesis and structure of mixed-ligand complexes of palladium(Ⅱ) with N-benzoylamino acid dianion and diamine</title><title>Science China. Chemistry</title><addtitle>SCIENCE CHINA Chemistry</addtitle><description>Four new mixed-ligand complexes of pailadiumt(Ⅱ) with L1(N-benzoyl-α-amino acid dianion) and L2[ethyldiamine (en),2,2’-bipyridine (Bpy) and 1,10-phenanthroline (Phen)] were synthesized.Ail the complexes have been characterized by elemental analyses,molar conductance,infrared and 1H NMR spectra and therme-gravimetric analyses.Crystal structures of [Pd(Bpy)(Bzval-N,O)] and [Pd(en) (Bzphe-N,O)] H2O have been do termmed by X-ray diffraction analysis.The results indicate that in all the complexes hgand L1 coordinates to palladium (Ⅱ) through deprotonated amide nitrogen and carboxylic oxygen,and there are some intramolecular nonrovalent in teractions in the complexes.</description><subject>acid</subject><subject>amide</subject><subject>Amino acids</subject><subject>Anions</subject><subject>complexes</subject><subject>containing</subject><subject>deprotonated</subject><subject>Diamines</subject><subject>group</subject><subject>Infrared analysis</subject><subject>Infrared spectra</subject><subject>interaction</subject><subject>intramolecular</subject><subject>Ligands</subject><subject>molecular</subject><subject>N-benzoyl-a-amino</subject><subject>Nitrogen</subject><subject>NMR</subject><subject>noncovalent</subject><subject>Nuclear magnetic resonance</subject><subject>Palladium</subject><subject>palladium(II)</subject><subject>structure</subject><issn>1674-7291</issn><issn>1006-9291</issn><issn>1869-1870</issn><issn>1862-2771</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNptUUFOwzAQjBBIVNALL7DEBZACdhLHNjeoKCBVcADOkWM7javETu0EWu68A_E1XkKiInphL7urmZ1d7QTBEYLnCEJycT2FESU4IXQnGCGashBRAnf7OiVJSCKG9oOx9wvYRxzDiOBR8Dmx1klteKutAbkq-au2DtgCPIS5Mu92XfFaGwu40NJfgqe1aUvltQfcSOBb14m2c2oYqPVKybDS8wERtm4qtVJ-QBpeVVzqrj75_vg6BW-6Lf-TB1JzM5wxCPR1D6jDYK_glVfj33wQvExvnid34ezx9n5yNQtFRHEbMogFVCKNSITjQhCY4rwQXBGMigL2bYqlpEnOBKMFwrlkPM9ZohDkOY_TKD4Ijje6jbPLTvk2W9jOmX5l1v-NYopRgnrW2YYlnPXeqSJrnK65W2cIZoMH2daDraQorZkvtZn_sWMIEUSYERL_APCziB4</recordid><startdate>19971201</startdate><enddate>19971201</enddate><creator>龚钰秋 陈耀峰 顾建明 胡秀荣</creator><general>Springer Nature 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胡秀荣</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c285t-905c0ec627253fc7065bfcae751ff070665dd84b9c98f15bd9abb94e10aba3623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>acid</topic><topic>amide</topic><topic>Amino acids</topic><topic>Anions</topic><topic>complexes</topic><topic>containing</topic><topic>deprotonated</topic><topic>Diamines</topic><topic>group</topic><topic>Infrared analysis</topic><topic>Infrared spectra</topic><topic>interaction</topic><topic>intramolecular</topic><topic>Ligands</topic><topic>molecular</topic><topic>N-benzoyl-a-amino</topic><topic>Nitrogen</topic><topic>NMR</topic><topic>noncovalent</topic><topic>Nuclear magnetic resonance</topic><topic>Palladium</topic><topic>palladium(II)</topic><topic>structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>龚钰秋 陈耀峰 顾建明 胡秀荣</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest 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Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>龚钰秋 陈耀峰 顾建明 胡秀荣</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination behavior of N-benzoylamino acids: Synthesis and structure of mixed-ligand complexes of palladium(Ⅱ) with N-benzoylamino acid dianion and diamine</atitle><jtitle>Science China. Chemistry</jtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>1997-12-01</date><risdate>1997</risdate><volume>40</volume><issue>6</issue><spage>600</spage><epage>607</epage><pages>600-607</pages><issn>1674-7291</issn><issn>1006-9291</issn><eissn>1869-1870</eissn><eissn>1862-2771</eissn><abstract>Four new mixed-ligand complexes of pailadiumt(Ⅱ) with L1(N-benzoyl-α-amino acid dianion) and L2[ethyldiamine (en),2,2’-bipyridine (Bpy) and 1,10-phenanthroline (Phen)] were synthesized.Ail the complexes have been characterized by elemental analyses,molar conductance,infrared and 1H NMR spectra and therme-gravimetric analyses.Crystal structures of [Pd(Bpy)(Bzval-N,O)] and [Pd(en) (Bzphe-N,O)] H2O have been do termmed by X-ray diffraction analysis.The results indicate that in all the complexes hgand L1 coordinates to palladium (Ⅱ) through deprotonated amide nitrogen and carboxylic oxygen,and there are some intramolecular nonrovalent in teractions in the complexes.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/BF02875478</doi><tpages>8</tpages></addata></record> |
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| subjects | acid amide Amino acids Anions complexes containing deprotonated Diamines group Infrared analysis Infrared spectra interaction intramolecular Ligands molecular N-benzoyl-a-amino Nitrogen NMR noncovalent Nuclear magnetic resonance Palladium palladium(II) structure |
| title | Coordination behavior of N-benzoylamino acids: Synthesis and structure of mixed-ligand complexes of palladium(Ⅱ) with N-benzoylamino acid dianion and diamine |
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