Nanopatterning of substrates by self-assembly in supramolecular block copolymer monolayer films
Many technological applications require templates with nanoscale patterns.Block copolymer self-assembly is a method of choice for obtaining a large variety of such patterns,with greatest flexibility achieved when combined with a supramolecular approach.One of the ways to fabricate block copolymer te...
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Veröffentlicht in: | Science China. Chemistry 2013, Vol.56 (1), p.48-55 |
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description | Many technological applications require templates with nanoscale patterns.Block copolymer self-assembly is a method of choice for obtaining a large variety of such patterns,with greatest flexibility achieved when combined with a supramolecular approach.One of the ways to fabricate block copolymer templates is the Langmuir-Blodgett (LB) technique.Here,we briefly summarize recent work with LB films of polystyrene-poly(4-vinyl pyridine) (PS-P4VP) mixed with 3-n-pentade cylphenol (PDP),illustrating the different types of patterns possible and the principles governing them.One interesting pattern that can be easily achieved with this system is the so-called "nanostrand network",which,when used as a template for gold deposition,can produce double striped lines of gold.Here,we show how this pattern can be modified by acetone swelling to give rise to gold monolayer ribbons with internal structure.The results also suggest new insights into the early stages of morphology formation at the air/water interface. |
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Géraldine</creatorcontrib><description>Many technological applications require templates with nanoscale patterns.Block copolymer self-assembly is a method of choice for obtaining a large variety of such patterns,with greatest flexibility achieved when combined with a supramolecular approach.One of the ways to fabricate block copolymer templates is the Langmuir-Blodgett (LB) technique.Here,we briefly summarize recent work with LB films of polystyrene-poly(4-vinyl pyridine) (PS-P4VP) mixed with 3-n-pentade cylphenol (PDP),illustrating the different types of patterns possible and the principles governing them.One interesting pattern that can be easily achieved with this system is the so-called "nanostrand network",which,when used as a template for gold deposition,can produce double striped lines of gold.Here,we show how this pattern can be modified by acetone swelling to give rise to gold monolayer ribbons with internal structure.The results also suggest new insights into the early stages of morphology formation at the air/water interface.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-012-4776-6</identifier><language>eng</language><publisher>Heidelberg: SP Science China Press</publisher><subject>Block copolymers ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Gold ; Langmuir-Blodgett films ; Monolayers ; Polystyrene resins ; Polyvinyl pyridine ; Self-assembly ; Substrates ; 乙烯基吡啶 ; 单层薄膜 ; 嵌段共聚物 ; 水界面 ; 空气 ; 聚苯乙烯 ; 自组装 ; 衬底 ; 超分子</subject><ispartof>Science China. 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Géraldine</creatorcontrib><title>Nanopatterning of substrates by self-assembly in supramolecular block copolymer monolayer films</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><description>Many technological applications require templates with nanoscale patterns.Block copolymer self-assembly is a method of choice for obtaining a large variety of such patterns,with greatest flexibility achieved when combined with a supramolecular approach.One of the ways to fabricate block copolymer templates is the Langmuir-Blodgett (LB) technique.Here,we briefly summarize recent work with LB films of polystyrene-poly(4-vinyl pyridine) (PS-P4VP) mixed with 3-n-pentade cylphenol (PDP),illustrating the different types of patterns possible and the principles governing them.One interesting pattern that can be easily achieved with this system is the so-called "nanostrand network",which,when used as a template for gold deposition,can produce double striped lines of gold.Here,we show how this pattern can be modified by acetone swelling to give rise to gold monolayer ribbons with internal structure.The results also suggest new insights into the early stages of morphology formation at the air/water interface.</description><subject>Block copolymers</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Gold</subject><subject>Langmuir-Blodgett films</subject><subject>Monolayers</subject><subject>Polystyrene resins</subject><subject>Polyvinyl pyridine</subject><subject>Self-assembly</subject><subject>Substrates</subject><subject>乙烯基吡啶</subject><subject>单层薄膜</subject><subject>嵌段共聚物</subject><subject>水界面</subject><subject>空气</subject><subject>聚苯乙烯</subject><subject>自组装</subject><subject>衬底</subject><subject>超分子</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9UMlOwzAQjRBIVKUfwC2Is8F7kiOq2KQKLnC2HC8lxYlTOznk73GUCm7MZZ40b9G8LLtG8A5BWNxHhCjmACIMaFFwwM-yFSp5BVBZwPOEeUFBgSt0mW1iPMA0hEBcsFUm3mTnezkMJnRNt8-9zeNYxyHIwcS8nvJonAUyRtPWbsqbLp37IFvvjBqdDHntvPrOle-9m1oT8tZ33skpIdu4Nl5lF1a6aDanvc4-nx4_ti9g9_78un3YAUUoHoCmxMqSKYiU1ZogVnBSaY0s0YxpW2MFa015jTUupWEMWWq4hgpWHJa15WSd3S6-ffDH0cRBHPwYuhQp0t8lKxlkMwstLBV8jMFY0YemlWESCIq5SrFUKVKVYq5SzBq8aGLidnsT_pz_E92cgr58tz8m3W8SpZQRSiH5AcLsg7k</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>Perepichka, Iryna I.</creator><creator>Chen, XiMin</creator><creator>Bazuin, C. Géraldine</creator><general>SP Science China Press</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>2013</creationdate><title>Nanopatterning of substrates by self-assembly in supramolecular block copolymer monolayer films</title><author>Perepichka, Iryna I. ; Chen, XiMin ; Bazuin, C. 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China Chem</stitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>2013</date><risdate>2013</risdate><volume>56</volume><issue>1</issue><spage>48</spage><epage>55</epage><pages>48-55</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>Many technological applications require templates with nanoscale patterns.Block copolymer self-assembly is a method of choice for obtaining a large variety of such patterns,with greatest flexibility achieved when combined with a supramolecular approach.One of the ways to fabricate block copolymer templates is the Langmuir-Blodgett (LB) technique.Here,we briefly summarize recent work with LB films of polystyrene-poly(4-vinyl pyridine) (PS-P4VP) mixed with 3-n-pentade cylphenol (PDP),illustrating the different types of patterns possible and the principles governing them.One interesting pattern that can be easily achieved with this system is the so-called "nanostrand network",which,when used as a template for gold deposition,can produce double striped lines of gold.Here,we show how this pattern can be modified by acetone swelling to give rise to gold monolayer ribbons with internal structure.The results also suggest new insights into the early stages of morphology formation at the air/water interface.</abstract><cop>Heidelberg</cop><pub>SP Science China Press</pub><doi>10.1007/s11426-012-4776-6</doi><tpages>8</tpages></addata></record> |
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subjects | Block copolymers Chemistry Chemistry and Materials Science Chemistry/Food Science Gold Langmuir-Blodgett films Monolayers Polystyrene resins Polyvinyl pyridine Self-assembly Substrates 乙烯基吡啶 单层薄膜 嵌段共聚物 水界面 空气 聚苯乙烯 自组装 衬底 超分子 |
title | Nanopatterning of substrates by self-assembly in supramolecular block copolymer monolayer films |
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