Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy
The development of preparation methods for XOFs, as a new class of organic frameworks, plays a crucial role in shaping their structures, functions, and potential applications. In this study, we presented the construction of chiral supramolecular 2D halogen-bonded organic frameworks (XOFs) through a...
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| Veröffentlicht in: | Science China. Chemistry 2023-11, Vol.66 (11), p.3169-3177 |
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| creator | Xia, Ning Zhao, Jiahao Gong, Guanfei Dong, Hongqiang Li, Haohu Wang, Jike Wang, Lu Chen, Shigui |
| description | The development of preparation methods for XOFs, as a new class of organic frameworks, plays a crucial role in shaping their structures, functions, and potential applications. In this study, we presented the construction of chiral supramolecular 2D halogen-bonded organic frameworks (XOFs) through a post-synthetic modification strategy. A linear halogen-bonded organic polymer (XOP),
XOP-DPBA
, decorated with aldehyde groups, was initially prepared to validate the feasibility of post-synthetic modification for XOF construction and functionalization.
XOP-DPBA
exhibited excellent reactivity with amines, forming imine bonds. By utilizing this reactivity, a series of cross-linked 2D XOFs were efficiently prepared through post-synthetic modified cross-linking reactions. Furthermore, we successfully introduced chiral α/β-cyclodextrins (α/β-CD) into the XOF skeletons
via
host-guest interactions, resulting in the fabrication of chiral supramolecular 2D XOFs. These chiral XOFs displayed the induced circular dichroism (ICD) signals and assembled them into helical fibers. The post-synthetic modification strategy demonstrated its versatility and simplicity for the construction and functionalization of XOFs. |
| doi_str_mv | 10.1007/s11426-023-1829-8 |
| format | Article |
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XOP-DPBA
, decorated with aldehyde groups, was initially prepared to validate the feasibility of post-synthetic modification for XOF construction and functionalization.
XOP-DPBA
exhibited excellent reactivity with amines, forming imine bonds. By utilizing this reactivity, a series of cross-linked 2D XOFs were efficiently prepared through post-synthetic modified cross-linking reactions. Furthermore, we successfully introduced chiral α/β-cyclodextrins (α/β-CD) into the XOF skeletons
via
host-guest interactions, resulting in the fabrication of chiral supramolecular 2D XOFs. These chiral XOFs displayed the induced circular dichroism (ICD) signals and assembled them into helical fibers. The post-synthetic modification strategy demonstrated its versatility and simplicity for the construction and functionalization of XOFs.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-023-1829-8</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Aldehydes ; Amines ; Bonding ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Crosslinking ; Cyclodextrins ; Dichroism ; Materials science ; Microscopy ; NMR ; Nuclear magnetic resonance</subject><ispartof>Science China. Chemistry, 2023-11, Vol.66 (11), p.3169-3177</ispartof><rights>Science China Press 2023</rights><rights>Science China Press 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-b839663e596c383655174d5498400ff06a462f8f0f40634d07738b040151ae853</citedby><cites>FETCH-LOGICAL-c316t-b839663e596c383655174d5498400ff06a462f8f0f40634d07738b040151ae853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11426-023-1829-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918579445?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,21388,21389,21390,23255,27923,27924,33529,33702,33743,34004,34313,41487,42556,43658,43786,43804,43952,44066,51318,64384,64388,72240</link.rule.ids></links><search><creatorcontrib>Xia, Ning</creatorcontrib><creatorcontrib>Zhao, Jiahao</creatorcontrib><creatorcontrib>Gong, Guanfei</creatorcontrib><creatorcontrib>Dong, Hongqiang</creatorcontrib><creatorcontrib>Li, Haohu</creatorcontrib><creatorcontrib>Wang, Jike</creatorcontrib><creatorcontrib>Wang, Lu</creatorcontrib><creatorcontrib>Chen, Shigui</creatorcontrib><title>Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><description>The development of preparation methods for XOFs, as a new class of organic frameworks, plays a crucial role in shaping their structures, functions, and potential applications. In this study, we presented the construction of chiral supramolecular 2D halogen-bonded organic frameworks (XOFs) through a post-synthetic modification strategy. A linear halogen-bonded organic polymer (XOP),
XOP-DPBA
, decorated with aldehyde groups, was initially prepared to validate the feasibility of post-synthetic modification for XOF construction and functionalization.
XOP-DPBA
exhibited excellent reactivity with amines, forming imine bonds. By utilizing this reactivity, a series of cross-linked 2D XOFs were efficiently prepared through post-synthetic modified cross-linking reactions. Furthermore, we successfully introduced chiral α/β-cyclodextrins (α/β-CD) into the XOF skeletons
via
host-guest interactions, resulting in the fabrication of chiral supramolecular 2D XOFs. These chiral XOFs displayed the induced circular dichroism (ICD) signals and assembled them into helical fibers. The post-synthetic modification strategy demonstrated its versatility and simplicity for the construction and functionalization of XOFs.</description><subject>Aldehydes</subject><subject>Amines</subject><subject>Bonding</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Crosslinking</subject><subject>Cyclodextrins</subject><subject>Dichroism</subject><subject>Materials science</subject><subject>Microscopy</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kMtOxCAUhonRxInOA7gjcY1yK9ClGa_JJG50TWgLnc50oEIbnbeXsSauZAMn5_vPIR8AVwTfEIzlbSKEU4EwZYgoWiJ1AhZEiTJXEp_mt5AcSVqSc7BMaYvzYQxTWSzA12rTRdPDNA3R7ENv66k3EdJ7uDF9aK1HVfCNbWCIrfFdDV3G7GeIuwTr4NMYp3rM7eoAh5BGlA5-3Ngxg_vQdK7LrTqGlFDf-V3nW5gTZrTt4RKcOdMnu_y9L8D748Pb6hmtX59eVndrVDMiRlQpVgrBbFGKmikmioJI3hS8VBxj57AwXFCnHHYcC8YbLCVTFeaYFMRYVbALcD3PHWL4mGwa9TZM0eeVOgtRhSw5P1Jkpn4-G63TQ-z2Jh40wfroWM-OdXasj461yhk6Z1JmfWvj3-T_Q99Ns39l</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Xia, Ning</creator><creator>Zhao, Jiahao</creator><creator>Gong, Guanfei</creator><creator>Dong, Hongqiang</creator><creator>Li, Haohu</creator><creator>Wang, Jike</creator><creator>Wang, Lu</creator><creator>Chen, Shigui</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20231101</creationdate><title>Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy</title><author>Xia, Ning ; Zhao, Jiahao ; Gong, Guanfei ; Dong, Hongqiang ; Li, Haohu ; Wang, Jike ; Wang, Lu ; Chen, Shigui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-b839663e596c383655174d5498400ff06a462f8f0f40634d07738b040151ae853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aldehydes</topic><topic>Amines</topic><topic>Bonding</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Crosslinking</topic><topic>Cyclodextrins</topic><topic>Dichroism</topic><topic>Materials science</topic><topic>Microscopy</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xia, Ning</creatorcontrib><creatorcontrib>Zhao, Jiahao</creatorcontrib><creatorcontrib>Gong, Guanfei</creatorcontrib><creatorcontrib>Dong, Hongqiang</creatorcontrib><creatorcontrib>Li, Haohu</creatorcontrib><creatorcontrib>Wang, Jike</creatorcontrib><creatorcontrib>Wang, Lu</creatorcontrib><creatorcontrib>Chen, Shigui</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xia, Ning</au><au>Zhao, Jiahao</au><au>Gong, Guanfei</au><au>Dong, Hongqiang</au><au>Li, Haohu</au><au>Wang, Jike</au><au>Wang, Lu</au><au>Chen, Shigui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>66</volume><issue>11</issue><spage>3169</spage><epage>3177</epage><pages>3169-3177</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>The development of preparation methods for XOFs, as a new class of organic frameworks, plays a crucial role in shaping their structures, functions, and potential applications. In this study, we presented the construction of chiral supramolecular 2D halogen-bonded organic frameworks (XOFs) through a post-synthetic modification strategy. A linear halogen-bonded organic polymer (XOP),
XOP-DPBA
, decorated with aldehyde groups, was initially prepared to validate the feasibility of post-synthetic modification for XOF construction and functionalization.
XOP-DPBA
exhibited excellent reactivity with amines, forming imine bonds. By utilizing this reactivity, a series of cross-linked 2D XOFs were efficiently prepared through post-synthetic modified cross-linking reactions. Furthermore, we successfully introduced chiral α/β-cyclodextrins (α/β-CD) into the XOF skeletons
via
host-guest interactions, resulting in the fabrication of chiral supramolecular 2D XOFs. These chiral XOFs displayed the induced circular dichroism (ICD) signals and assembled them into helical fibers. The post-synthetic modification strategy demonstrated its versatility and simplicity for the construction and functionalization of XOFs.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-023-1829-8</doi><tpages>9</tpages></addata></record> |
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| subjects | Aldehydes Amines Bonding Chemistry Chemistry and Materials Science Chemistry/Food Science Crosslinking Cyclodextrins Dichroism Materials science Microscopy NMR Nuclear magnetic resonance |
| title | Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy |
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