Crystalline covalent triazine frameworks manipulated by aliphatic amine modulator
Crystallization is an unsolved challenge in the chemistry of covalent triazine frameworks (CTFs) due to the poorly controlled simultaneous polymerization and crystallization processes. Herein, the synthesis of crystalline CTFs via the introduction of aliphatic amine as a dynamic modulator is reporte...
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| Veröffentlicht in: | Science China. Chemistry 2023-09, Vol.66 (9), p.2676-2682 |
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| container_issue | 9 |
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| container_title | Science China. Chemistry |
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| creator | Hu, Xunliang Guo, Yantong Sun, Ruixue Wang, Xiaoyan Tan, Bien |
| description | Crystallization is an unsolved challenge in the chemistry of covalent triazine frameworks (CTFs) due to the poorly controlled simultaneous polymerization and crystallization processes. Herein, the synthesis of crystalline CTFs
via
the introduction of aliphatic amine as a dynamic modulator is reported. By optimizing the amount of aliphatic amine, the crystallization process can be controlled in an open system, resulting in the synthesis of crystalline CTFs. These crystalline CTFs exhibit much better photocatalytic hydrogen evolution performance, with highly ordered CTF-1-C3 demonstrating superior performance (10 mmol g
−1
h
−1
) compared with most reported CTF-1. This approach also allows for the preparation of various crystalline CTFs. |
| doi_str_mv | 10.1007/s11426-023-1700-9 |
| format | Article |
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via
the introduction of aliphatic amine as a dynamic modulator is reported. By optimizing the amount of aliphatic amine, the crystallization process can be controlled in an open system, resulting in the synthesis of crystalline CTFs. These crystalline CTFs exhibit much better photocatalytic hydrogen evolution performance, with highly ordered CTF-1-C3 demonstrating superior performance (10 mmol g
−1
h
−1
) compared with most reported CTF-1. This approach also allows for the preparation of various crystalline CTFs.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-023-1700-9</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Aliphatic amines ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Crystallization ; Hydrogen evolution ; Light ; Open systems ; Oxidation ; Photocatalysis ; Synthesis</subject><ispartof>Science China. Chemistry, 2023-09, Vol.66 (9), p.2676-2682</ispartof><rights>Science China Press 2023</rights><rights>Science China Press 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-4c6eb134ba1b7f4b656c134399e654641c33757021961dc50b91ee23126d70213</citedby><cites>FETCH-LOGICAL-c316t-4c6eb134ba1b7f4b656c134399e654641c33757021961dc50b91ee23126d70213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11426-023-1700-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918528153?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,21389,21390,21391,23256,27924,27925,33530,33703,33744,34005,34314,41488,42557,43659,43787,43805,43953,44067,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Hu, Xunliang</creatorcontrib><creatorcontrib>Guo, Yantong</creatorcontrib><creatorcontrib>Sun, Ruixue</creatorcontrib><creatorcontrib>Wang, Xiaoyan</creatorcontrib><creatorcontrib>Tan, Bien</creatorcontrib><title>Crystalline covalent triazine frameworks manipulated by aliphatic amine modulator</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><description>Crystallization is an unsolved challenge in the chemistry of covalent triazine frameworks (CTFs) due to the poorly controlled simultaneous polymerization and crystallization processes. Herein, the synthesis of crystalline CTFs
via
the introduction of aliphatic amine as a dynamic modulator is reported. By optimizing the amount of aliphatic amine, the crystallization process can be controlled in an open system, resulting in the synthesis of crystalline CTFs. These crystalline CTFs exhibit much better photocatalytic hydrogen evolution performance, with highly ordered CTF-1-C3 demonstrating superior performance (10 mmol g
−1
h
−1
) compared with most reported CTF-1. This approach also allows for the preparation of various crystalline CTFs.</description><subject>Aliphatic amines</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Crystallization</subject><subject>Hydrogen evolution</subject><subject>Light</subject><subject>Open systems</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Synthesis</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1UE1LxDAQDaLgsu4P8FbwHM0kTdIcpfgFCyLoOaRpql3bpiZdZf31plTw5Fzm6703zEPoHMglECKvIkBOBSaUYZCEYHWEVlAIhaGQ5DjVQuZYUgWnaBPjjqRgjFDJV-ipDIc4ma5rB5dZ_2k6N0zZFFrzPU-aYHr35cN7zHoztOO-M5Ors-qQma4d38zU2sz0M7L39bz04QydNKaLbvOb1-jl9ua5vMfbx7uH8nqLLQMx4dwKVwHLKwOVbPJKcGFTy5RyguciB8uY5JJQUAJqy0mlwDnKgIp6nrI1ulh0x-A_9i5Oeuf3YUgndfq04LQAzhIKFpQNPsbgGj2GtjfhoIHo2Ty9mKeTeXo2T6vEoQsnJuzw6sKf8v-kH8-qcQw</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Hu, Xunliang</creator><creator>Guo, Yantong</creator><creator>Sun, Ruixue</creator><creator>Wang, Xiaoyan</creator><creator>Tan, Bien</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20230901</creationdate><title>Crystalline covalent triazine frameworks manipulated by aliphatic amine modulator</title><author>Hu, Xunliang ; Guo, Yantong ; Sun, Ruixue ; Wang, Xiaoyan ; Tan, Bien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-4c6eb134ba1b7f4b656c134399e654641c33757021961dc50b91ee23126d70213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aliphatic amines</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Crystallization</topic><topic>Hydrogen evolution</topic><topic>Light</topic><topic>Open systems</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Xunliang</creatorcontrib><creatorcontrib>Guo, Yantong</creatorcontrib><creatorcontrib>Sun, Ruixue</creatorcontrib><creatorcontrib>Wang, Xiaoyan</creatorcontrib><creatorcontrib>Tan, Bien</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Xunliang</au><au>Guo, Yantong</au><au>Sun, Ruixue</au><au>Wang, Xiaoyan</au><au>Tan, Bien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystalline covalent triazine frameworks manipulated by aliphatic amine modulator</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>66</volume><issue>9</issue><spage>2676</spage><epage>2682</epage><pages>2676-2682</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>Crystallization is an unsolved challenge in the chemistry of covalent triazine frameworks (CTFs) due to the poorly controlled simultaneous polymerization and crystallization processes. Herein, the synthesis of crystalline CTFs
via
the introduction of aliphatic amine as a dynamic modulator is reported. By optimizing the amount of aliphatic amine, the crystallization process can be controlled in an open system, resulting in the synthesis of crystalline CTFs. These crystalline CTFs exhibit much better photocatalytic hydrogen evolution performance, with highly ordered CTF-1-C3 demonstrating superior performance (10 mmol g
−1
h
−1
) compared with most reported CTF-1. This approach also allows for the preparation of various crystalline CTFs.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-023-1700-9</doi><tpages>7</tpages></addata></record> |
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| issn | 1674-7291 1869-1870 |
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| source | ProQuest Central Essentials; ProQuest Central (Alumni Edition); ProQuest Central Student; ProQuest Central Korea; ProQuest Central UK/Ireland; Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Aliphatic amines Chemistry Chemistry and Materials Science Chemistry/Food Science Crystallization Hydrogen evolution Light Open systems Oxidation Photocatalysis Synthesis |
| title | Crystalline covalent triazine frameworks manipulated by aliphatic amine modulator |
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