Synthesis,structure and nonlinear optical properties of two novel two-photon absorption chromophores

Two triphenylamine-based derivatives that can be used as two-photon absorption chromophore,tris{4-[4-(3-trifluoromethyl-3-oxopanoyl)]phenyl}amine (1) and tris{4-[4-(3-phenyl-3-oxopanoyl)] phenyl} amine (2) were successfully synthesized and fully characterized by elemental analysis,IR,1H NMR and MS....

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Veröffentlicht in:Science China. Chemistry 2009-04, Vol.52 (4), p.529-534
Hauptverfasser: Cheng, LeHua, Li, Lin, Sun, PingPing, Zhou, HongPing, Tian, YuPeng, Tang, HuoHong
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container_end_page 534
container_issue 4
container_start_page 529
container_title Science China. Chemistry
container_volume 52
creator Cheng, LeHua
Li, Lin
Sun, PingPing
Zhou, HongPing
Tian, YuPeng
Tang, HuoHong
description Two triphenylamine-based derivatives that can be used as two-photon absorption chromophore,tris{4-[4-(3-trifluoromethyl-3-oxopanoyl)]phenyl}amine (1) and tris{4-[4-(3-phenyl-3-oxopanoyl)] phenyl} amine (2) were successfully synthesized and fully characterized by elemental analysis,IR,1H NMR and MS. The single crystal X-ray diffraction analysis showed that the molecules possess D-(π-A)3 structures. One-and two-photon absorption and fluorescence in various solvents were experimentally investigated. A data recording experiment proved the potential application of these chromophores.
doi_str_mv 10.1007/s11426-009-0026-y
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subjects absorption
Chemical analysis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
chromophore
Chromophores
crystal
Data recording
derivative
NMR
Nonlinear optics
Nuclear magnetic resonance
Optical properties
Photon absorption
Photons
Single crystals
structure
triphenylamine
two-photon
title Synthesis,structure and nonlinear optical properties of two novel two-photon absorption chromophores
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