Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors
Electrochromic supercapacitors have drawn enormous attention due to their ability to monitor the charge and discharge processes through color changes of electroactive materials. However, there are few work on small organic molecules as active materials for all-solid-state electrochromic supercapacit...
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| Veröffentlicht in: | Science China. Chemistry 2020-11, Vol.63 (11), p.1632-1644 |
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| creator | Zhuang, Yanling Zhao, Weiwei Wang, Longlu Li, Feiyang Wang, Weikang Liu, Shujuan Huang, Wei Zhao, Qiang |
| description | Electrochromic supercapacitors have drawn enormous attention due to their ability to monitor the charge and discharge processes through color changes of electroactive materials. However, there are few work on small organic molecules as active materials for all-solid-state electrochromic supercapacitors. Herein, we reported two novel multifunctional symmetric viologens (TPA-bpy and CZ-bpy), which showed different solvatochromic, electrochromic, electroluminochromic and energy storage behaviors despite their similar chemical structures. The different performances between these two viologens were attributed to the difference in the intramolecular charge transfer capability and the solubility in organic solvents. Devices containing TPA-bpy displayed faster response time and higher coloration efficiency due to the introduction of packing-disruptive and three-dimensional triarylamine groups. Moreover, devices containing TPA-bpy also showed energy storage characteristics with an obvious color change from purple to yellow. It showed a wide voltage window (2.0 V), long discharge time (230.3 s at 0.01 mA cm
−2
), and excellent cycling stability with 90% capacitance retention after 6,000 cycles. The work provides a new and convenient strategy towards the development of novel electrochromic capacitive materials. |
| doi_str_mv | 10.1007/s11426-020-9789-9 |
| format | Article |
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−2
), and excellent cycling stability with 90% capacitance retention after 6,000 cycles. The work provides a new and convenient strategy towards the development of novel electrochromic capacitive materials.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-020-9789-9</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Charge transfer ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Color ; Discharge ; Electroactive materials ; Electrochromism ; Energy storage ; Organic chemistry ; Solid state ; Supercapacitors</subject><ispartof>Science China. Chemistry, 2020-11, Vol.63 (11), p.1632-1644</ispartof><rights>Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-5b5a5c9a110138f4f5b25a8b5ef8c35cfd89db9b9ed79de3388daf7631c316b83</citedby><cites>FETCH-LOGICAL-c316t-5b5a5c9a110138f4f5b25a8b5ef8c35cfd89db9b9ed79de3388daf7631c316b83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11426-020-9789-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918520743?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21368,21369,21370,21371,23236,27903,27904,33509,33682,33723,33984,34293,41467,42536,43638,43766,43784,43932,44046,51297,64361,64365,72215</link.rule.ids></links><search><creatorcontrib>Zhuang, Yanling</creatorcontrib><creatorcontrib>Zhao, Weiwei</creatorcontrib><creatorcontrib>Wang, Longlu</creatorcontrib><creatorcontrib>Li, Feiyang</creatorcontrib><creatorcontrib>Wang, Weikang</creatorcontrib><creatorcontrib>Liu, Shujuan</creatorcontrib><creatorcontrib>Huang, Wei</creatorcontrib><creatorcontrib>Zhao, Qiang</creatorcontrib><title>Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><description>Electrochromic supercapacitors have drawn enormous attention due to their ability to monitor the charge and discharge processes through color changes of electroactive materials. However, there are few work on small organic molecules as active materials for all-solid-state electrochromic supercapacitors. Herein, we reported two novel multifunctional symmetric viologens (TPA-bpy and CZ-bpy), which showed different solvatochromic, electrochromic, electroluminochromic and energy storage behaviors despite their similar chemical structures. The different performances between these two viologens were attributed to the difference in the intramolecular charge transfer capability and the solubility in organic solvents. Devices containing TPA-bpy displayed faster response time and higher coloration efficiency due to the introduction of packing-disruptive and three-dimensional triarylamine groups. Moreover, devices containing TPA-bpy also showed energy storage characteristics with an obvious color change from purple to yellow. It showed a wide voltage window (2.0 V), long discharge time (230.3 s at 0.01 mA cm
−2
), and excellent cycling stability with 90% capacitance retention after 6,000 cycles. The work provides a new and convenient strategy towards the development of novel electrochromic capacitive materials.</description><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Color</subject><subject>Discharge</subject><subject>Electroactive materials</subject><subject>Electrochromism</subject><subject>Energy storage</subject><subject>Organic chemistry</subject><subject>Solid state</subject><subject>Supercapacitors</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kM1KxDAURoMoOOg8gLuC62jSNE2ylME_GHChrkOaJmOGtKlJKoxPb4YKrrybexfn--AeAK4wusEIsduEcVO3ENUICsYFFCdghXkrIOYMnZa7ZQ1ktcDnYJ3SHpUhBNWMroB7DX7uvKlydCoevBrcaCo7jzq7MCrvvk1fpcMwmALo6ssFH3ZmrGyIlfIepuBdD1NW2VTGG51j0B8xDIVN82SiVpPSLoeYLsGZVT6Z9e--AO8P92-bJ7h9eXze3G2hJrjNkHZUUS0UxggTbhtLu5oq3lFjuSZU256LvhOdMD0TvSGE815Z1hJ8zHecXIDrpXeK4XM2Kct9mGN5JcligNMasYYUCi-UjiGlaKycohuKAYmRPEqVi1RZpMqjVClKpl4yqbDjzsS_5v9DP3IMfSg</recordid><startdate>20201101</startdate><enddate>20201101</enddate><creator>Zhuang, Yanling</creator><creator>Zhao, Weiwei</creator><creator>Wang, Longlu</creator><creator>Li, Feiyang</creator><creator>Wang, Weikang</creator><creator>Liu, Shujuan</creator><creator>Huang, Wei</creator><creator>Zhao, Qiang</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20201101</creationdate><title>Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors</title><author>Zhuang, Yanling ; Zhao, Weiwei ; Wang, Longlu ; Li, Feiyang ; Wang, Weikang ; Liu, Shujuan ; Huang, Wei ; Zhao, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-5b5a5c9a110138f4f5b25a8b5ef8c35cfd89db9b9ed79de3388daf7631c316b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Color</topic><topic>Discharge</topic><topic>Electroactive materials</topic><topic>Electrochromism</topic><topic>Energy storage</topic><topic>Organic chemistry</topic><topic>Solid state</topic><topic>Supercapacitors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhuang, Yanling</creatorcontrib><creatorcontrib>Zhao, Weiwei</creatorcontrib><creatorcontrib>Wang, Longlu</creatorcontrib><creatorcontrib>Li, Feiyang</creatorcontrib><creatorcontrib>Wang, Weikang</creatorcontrib><creatorcontrib>Liu, Shujuan</creatorcontrib><creatorcontrib>Huang, Wei</creatorcontrib><creatorcontrib>Zhao, Qiang</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhuang, Yanling</au><au>Zhao, Weiwei</au><au>Wang, Longlu</au><au>Li, Feiyang</au><au>Wang, Weikang</au><au>Liu, Shujuan</au><au>Huang, Wei</au><au>Zhao, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><date>2020-11-01</date><risdate>2020</risdate><volume>63</volume><issue>11</issue><spage>1632</spage><epage>1644</epage><pages>1632-1644</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>Electrochromic supercapacitors have drawn enormous attention due to their ability to monitor the charge and discharge processes through color changes of electroactive materials. However, there are few work on small organic molecules as active materials for all-solid-state electrochromic supercapacitors. Herein, we reported two novel multifunctional symmetric viologens (TPA-bpy and CZ-bpy), which showed different solvatochromic, electrochromic, electroluminochromic and energy storage behaviors despite their similar chemical structures. The different performances between these two viologens were attributed to the difference in the intramolecular charge transfer capability and the solubility in organic solvents. Devices containing TPA-bpy displayed faster response time and higher coloration efficiency due to the introduction of packing-disruptive and three-dimensional triarylamine groups. Moreover, devices containing TPA-bpy also showed energy storage characteristics with an obvious color change from purple to yellow. It showed a wide voltage window (2.0 V), long discharge time (230.3 s at 0.01 mA cm
−2
), and excellent cycling stability with 90% capacitance retention after 6,000 cycles. The work provides a new and convenient strategy towards the development of novel electrochromic capacitive materials.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-020-9789-9</doi><tpages>13</tpages></addata></record> |
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| subjects | Charge transfer Chemistry Chemistry and Materials Science Chemistry/Food Science Color Discharge Electroactive materials Electrochromism Energy storage Organic chemistry Solid state Supercapacitors |
| title | Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors |
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