A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation
A novel 3D Ag(I)-containing polyoxometalate-based MOF of H 17 [Ag 9 (AgH 8 W 11 O 44 ) 2 (BPY) 9 ]·2.5H 2 O ( WAg – BPY ; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) an...
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| Veröffentlicht in: | Journal of cluster science 2020-09, Vol.31 (5), p.983-988 |
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| creator | Cui, Chaojie Shi, Dongying Nie, Zhouhuan Song, Lubin Ren, Ahao Liu, Chunsen |
| description | A novel 3D Ag(I)-containing polyoxometalate-based MOF of H
17
[Ag
9
(AgH
8
W
11
O
44
)
2
(BPY)
9
]·2.5H
2
O (
WAg
–
BPY
; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction.
WAg
–
BPY
exhibits highly efficient photocatalytic O
2
production (964 μmol g
−1
in the first 10 min) under visible-light irradiation. More interestingly, transient photocurrent experiments confirm the charge separation and transfer process for the possible mechanism in the photocatalytic reaction. The high photocatalytic efficiency, high stability and good recyclability of the catalyst
WAg
–
BPY
demonstrates that Ag(I)-containing polyoxometalate units are crucial factor for water oxidation over heterogeneous systems. The successful synthesis of
WAg
–
BPY
not only enriches polyoxometalate-based hybrid materials, but also represents the advantages of the Ag(I)-containing complexes for the potential applications such as heterogeneous photocatalysis and so on. |
| doi_str_mv | 10.1007/s10876-019-01703-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2918292947</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2918292947</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-952984d23a2ae36b2570aa08fae55c3c49b8ff9d6897aaad74bb11c262e8dbaf3</originalsourceid><addsrcrecordid>eNp9kD1PwzAURS0EEqXwB5gsscBg8EcS22MpFCoVysDHwGA5iRNcpXGx06r99xiCxMbw9N5w7n3SAeCU4EuCMb8KBAueIUxkHI4ZEntgQFJOkRAZ3Y83TjDilItDcBTCAmMsBWMD8D6Cj25jGjiqz6cXaOzaTtvWtjV8cs3Obd3SdLrRnUHXOpgSPswnsHIevtpg88agma0_OnTj7ca08C1yHs63ttSdde0xOKh0E8zJ7x6Cl8nt8_gezeZ30_FohgpGZIdkSqVISso01YZlOU051hqLSps0LViRyFxUlSwzIbnWuuRJnhNS0IwaUea6YkNw1veuvPtcm9CphVv7Nr5UVBJBJZUJjxTtqcK7ELyp1MrbpfY7RbD6lqh6iSpKVD8SlYgh1odChNva-L_qf1Jfh6x0VQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2918292947</pqid></control><display><type>article</type><title>A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation</title><source>ProQuest Central Essentials</source><source>ProQuest Central (Alumni Edition)</source><source>ProQuest Central Student</source><source>ProQuest Central Korea</source><source>ProQuest Central UK/Ireland</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Cui, Chaojie ; Shi, Dongying ; Nie, Zhouhuan ; Song, Lubin ; Ren, Ahao ; Liu, Chunsen</creator><creatorcontrib>Cui, Chaojie ; Shi, Dongying ; Nie, Zhouhuan ; Song, Lubin ; Ren, Ahao ; Liu, Chunsen</creatorcontrib><description>A novel 3D Ag(I)-containing polyoxometalate-based MOF of H
17
[Ag
9
(AgH
8
W
11
O
44
)
2
(BPY)
9
]·2.5H
2
O (
WAg
–
BPY
; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction.
WAg
–
BPY
exhibits highly efficient photocatalytic O
2
production (964 μmol g
−1
in the first 10 min) under visible-light irradiation. More interestingly, transient photocurrent experiments confirm the charge separation and transfer process for the possible mechanism in the photocatalytic reaction. The high photocatalytic efficiency, high stability and good recyclability of the catalyst
WAg
–
BPY
demonstrates that Ag(I)-containing polyoxometalate units are crucial factor for water oxidation over heterogeneous systems. The successful synthesis of
WAg
–
BPY
not only enriches polyoxometalate-based hybrid materials, but also represents the advantages of the Ag(I)-containing complexes for the potential applications such as heterogeneous photocatalysis and so on.</description><identifier>ISSN: 1040-7278</identifier><identifier>EISSN: 1572-8862</identifier><identifier>DOI: 10.1007/s10876-019-01703-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alternative energy sources ; Catalysis ; Charge transfer ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Geometry ; Inorganic Chemistry ; Ligands ; Light irradiation ; Nanochemistry ; Nitrogen ; Original Paper ; Oxidation ; Photocatalysis ; Photoelectric effect ; Physical Chemistry ; Polyoxometallates ; Recyclability ; Single crystals ; Solar energy ; Vibration ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Journal of cluster science, 2020-09, Vol.31 (5), p.983-988</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-952984d23a2ae36b2570aa08fae55c3c49b8ff9d6897aaad74bb11c262e8dbaf3</citedby><cites>FETCH-LOGICAL-c319t-952984d23a2ae36b2570aa08fae55c3c49b8ff9d6897aaad74bb11c262e8dbaf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10876-019-01703-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918292947?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21387,21388,21389,21390,23255,27923,27924,33529,33702,33743,34004,34313,41487,42556,43658,43786,43804,43952,44066,51318,64384,64388,72240</link.rule.ids></links><search><creatorcontrib>Cui, Chaojie</creatorcontrib><creatorcontrib>Shi, Dongying</creatorcontrib><creatorcontrib>Nie, Zhouhuan</creatorcontrib><creatorcontrib>Song, Lubin</creatorcontrib><creatorcontrib>Ren, Ahao</creatorcontrib><creatorcontrib>Liu, Chunsen</creatorcontrib><title>A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation</title><title>Journal of cluster science</title><addtitle>J Clust Sci</addtitle><description>A novel 3D Ag(I)-containing polyoxometalate-based MOF of H
17
[Ag
9
(AgH
8
W
11
O
44
)
2
(BPY)
9
]·2.5H
2
O (
WAg
–
BPY
; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction.
WAg
–
BPY
exhibits highly efficient photocatalytic O
2
production (964 μmol g
−1
in the first 10 min) under visible-light irradiation. More interestingly, transient photocurrent experiments confirm the charge separation and transfer process for the possible mechanism in the photocatalytic reaction. The high photocatalytic efficiency, high stability and good recyclability of the catalyst
WAg
–
BPY
demonstrates that Ag(I)-containing polyoxometalate units are crucial factor for water oxidation over heterogeneous systems. The successful synthesis of
WAg
–
BPY
not only enriches polyoxometalate-based hybrid materials, but also represents the advantages of the Ag(I)-containing complexes for the potential applications such as heterogeneous photocatalysis and so on.</description><subject>Alternative energy sources</subject><subject>Catalysis</subject><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Geometry</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Light irradiation</subject><subject>Nanochemistry</subject><subject>Nitrogen</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Photoelectric effect</subject><subject>Physical Chemistry</subject><subject>Polyoxometallates</subject><subject>Recyclability</subject><subject>Single crystals</subject><subject>Solar energy</subject><subject>Vibration</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kD1PwzAURS0EEqXwB5gsscBg8EcS22MpFCoVysDHwGA5iRNcpXGx06r99xiCxMbw9N5w7n3SAeCU4EuCMb8KBAueIUxkHI4ZEntgQFJOkRAZ3Y83TjDilItDcBTCAmMsBWMD8D6Cj25jGjiqz6cXaOzaTtvWtjV8cs3Obd3SdLrRnUHXOpgSPswnsHIevtpg88agma0_OnTj7ca08C1yHs63ttSdde0xOKh0E8zJ7x6Cl8nt8_gezeZ30_FohgpGZIdkSqVISso01YZlOU051hqLSps0LViRyFxUlSwzIbnWuuRJnhNS0IwaUea6YkNw1veuvPtcm9CphVv7Nr5UVBJBJZUJjxTtqcK7ELyp1MrbpfY7RbD6lqh6iSpKVD8SlYgh1odChNva-L_qf1Jfh6x0VQ</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Cui, Chaojie</creator><creator>Shi, Dongying</creator><creator>Nie, Zhouhuan</creator><creator>Song, Lubin</creator><creator>Ren, Ahao</creator><creator>Liu, Chunsen</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20200901</creationdate><title>A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation</title><author>Cui, Chaojie ; Shi, Dongying ; Nie, Zhouhuan ; Song, Lubin ; Ren, Ahao ; Liu, Chunsen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-952984d23a2ae36b2570aa08fae55c3c49b8ff9d6897aaad74bb11c262e8dbaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alternative energy sources</topic><topic>Catalysis</topic><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Geometry</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Light irradiation</topic><topic>Nanochemistry</topic><topic>Nitrogen</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Photoelectric effect</topic><topic>Physical Chemistry</topic><topic>Polyoxometallates</topic><topic>Recyclability</topic><topic>Single crystals</topic><topic>Solar energy</topic><topic>Vibration</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cui, Chaojie</creatorcontrib><creatorcontrib>Shi, Dongying</creatorcontrib><creatorcontrib>Nie, Zhouhuan</creatorcontrib><creatorcontrib>Song, Lubin</creatorcontrib><creatorcontrib>Ren, Ahao</creatorcontrib><creatorcontrib>Liu, Chunsen</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cui, Chaojie</au><au>Shi, Dongying</au><au>Nie, Zhouhuan</au><au>Song, Lubin</au><au>Ren, Ahao</au><au>Liu, Chunsen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation</atitle><jtitle>Journal of cluster science</jtitle><stitle>J Clust Sci</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>31</volume><issue>5</issue><spage>983</spage><epage>988</epage><pages>983-988</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>A novel 3D Ag(I)-containing polyoxometalate-based MOF of H
17
[Ag
9
(AgH
8
W
11
O
44
)
2
(BPY)
9
]·2.5H
2
O (
WAg
–
BPY
; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction.
WAg
–
BPY
exhibits highly efficient photocatalytic O
2
production (964 μmol g
−1
in the first 10 min) under visible-light irradiation. More interestingly, transient photocurrent experiments confirm the charge separation and transfer process for the possible mechanism in the photocatalytic reaction. The high photocatalytic efficiency, high stability and good recyclability of the catalyst
WAg
–
BPY
demonstrates that Ag(I)-containing polyoxometalate units are crucial factor for water oxidation over heterogeneous systems. The successful synthesis of
WAg
–
BPY
not only enriches polyoxometalate-based hybrid materials, but also represents the advantages of the Ag(I)-containing complexes for the potential applications such as heterogeneous photocatalysis and so on.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10876-019-01703-8</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 1040-7278 |
| ispartof | Journal of cluster science, 2020-09, Vol.31 (5), p.983-988 |
| issn | 1040-7278 1572-8862 |
| language | eng |
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| source | ProQuest Central Essentials; ProQuest Central (Alumni Edition); ProQuest Central Student; ProQuest Central Korea; ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Alternative energy sources Catalysis Charge transfer Chemistry Chemistry and Materials Science Crystal structure Geometry Inorganic Chemistry Ligands Light irradiation Nanochemistry Nitrogen Original Paper Oxidation Photocatalysis Photoelectric effect Physical Chemistry Polyoxometallates Recyclability Single crystals Solar energy Vibration X ray powder diffraction X-ray diffraction |
| title | A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation |
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