An Eicosanuclear Heterothiometallic Mo/S/Cu Cluster: Synthesis and Third-Order Nonlinear Optical Property
A potassium-crownether host–guest cation-templated synthetic method was used to build a heterothiometallic Mo/S/Cu cluster {[(K ⊂ dibenzo-18-crown-6)(NMP) 2 ] 2 [(K ⊂ dibenzo-18-crown-6)(NMP)] 2 [Mo 8 S 32 Cu 12 ]·H 2 O} ( 1 ). 1 was structurally determined by X-ray single crystal and powder diffrac...
Gespeichert in:
| Veröffentlicht in: | Journal of cluster science 2018-03, Vol.29 (2), p.385-390 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 390 |
|---|---|
| container_issue | 2 |
| container_start_page | 385 |
| container_title | Journal of cluster science |
| container_volume | 29 |
| creator | Zhang, Jinfang Feng, Jiaoyang Tang, Guodong Wu, Junjie Luo, Fuming Xu, Bin Zhang, Chi |
| description | A potassium-crownether host–guest cation-templated synthetic method was used to build a heterothiometallic Mo/S/Cu cluster {[(K ⊂ dibenzo-18-crown-6)(NMP)
2
]
2
[(K ⊂ dibenzo-18-crown-6)(NMP)]
2
[Mo
8
S
32
Cu
12
]·H
2
O} (
1
).
1
was structurally determined by X-ray single crystal and powder diffractions. The anionic Mo/S/Cu cluster [Mo
8
S
32
Cu
12
]
4−
exhibits a unique octameric eicosanuclear supra-cubane-like architecture. Potassium-crownether cations show “satellite-receiver”-shaped and hexagonal-pyramidal configurations. Moreover, the third-order nonlinear optical (NLO) property was studied through Z-scan method (532 nm, 4 ns pulses), which reveals that
1
possesses effective NLO absorptive and refractive properties. |
| doi_str_mv | 10.1007/s10876-018-1341-2 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2918291310</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2918291310</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-75dcb7684b6bc285327d153d47e6f09438d43da3c8c361fa6d140c7c70ef67db3</originalsourceid><addsrcrecordid>eNp1kE1LwzAYx4soOKcfwFvAc1xe2iTzNsp0wnTC5jmkSeoyuqYm6WHf3o4Knjw8PA88_xf4Zdk9Ro8YIT6LGAnOIMICYppjSC6yCS44gUIwcjncKEeQEy6us5sYDwihuaB0krlFC5ZO-6jaXjdWBbCyyQaf9s4fbVJN4zR487PtrOxB2fRxeD6B7alNextdBKo1YLd3wcBNMDaAd982rj3nbLrktGrAR_CdDel0m13Vqon27ndPs8_n5a5cwfXm5bVcrKGmmCXIC6MrzkResUoTUVDCDS6oybllNZrnVJicGkW10JThWjGDc6S55sjWjJuKTrOHMbcL_ru3McmD70M7VEoyx2IYitGgwqNKBx9jsLXsgjuqcJIYyTNRORKVA1F5JirJ4CGjJw7a9suGv-T_TT_1WnlB</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2918291310</pqid></control><display><type>article</type><title>An Eicosanuclear Heterothiometallic Mo/S/Cu Cluster: Synthesis and Third-Order Nonlinear Optical Property</title><source>ProQuest Central Essentials</source><source>ProQuest Central (Alumni Edition)</source><source>ProQuest Central Student</source><source>ProQuest Central Korea</source><source>ProQuest Central UK/Ireland</source><source>SpringerLink Journals - AutoHoldings</source><source>ProQuest Central</source><creator>Zhang, Jinfang ; Feng, Jiaoyang ; Tang, Guodong ; Wu, Junjie ; Luo, Fuming ; Xu, Bin ; Zhang, Chi</creator><creatorcontrib>Zhang, Jinfang ; Feng, Jiaoyang ; Tang, Guodong ; Wu, Junjie ; Luo, Fuming ; Xu, Bin ; Zhang, Chi</creatorcontrib><description>A potassium-crownether host–guest cation-templated synthetic method was used to build a heterothiometallic Mo/S/Cu cluster {[(K ⊂ dibenzo-18-crown-6)(NMP)
2
]
2
[(K ⊂ dibenzo-18-crown-6)(NMP)]
2
[Mo
8
S
32
Cu
12
]·H
2
O} (
1
).
1
was structurally determined by X-ray single crystal and powder diffractions. The anionic Mo/S/Cu cluster [Mo
8
S
32
Cu
12
]
4−
exhibits a unique octameric eicosanuclear supra-cubane-like architecture. Potassium-crownether cations show “satellite-receiver”-shaped and hexagonal-pyramidal configurations. Moreover, the third-order nonlinear optical (NLO) property was studied through Z-scan method (532 nm, 4 ns pulses), which reveals that
1
possesses effective NLO absorptive and refractive properties.</description><identifier>ISSN: 1040-7278</identifier><identifier>EISSN: 1572-8862</identifier><identifier>DOI: 10.1007/s10876-018-1341-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Absorptivity ; Catalysis ; Cations ; Chemistry ; Chemistry and Materials Science ; Clusters ; Copper ; Crystal structure ; Cubane ; Dependent sample ; Inorganic Chemistry ; Lasers ; Molybdenum ; Nanochemistry ; Nonlinear optics ; Optical properties ; Original Paper ; Physical Chemistry ; Potassium ; Radiation ; Single crystals ; Solvents</subject><ispartof>Journal of cluster science, 2018-03, Vol.29 (2), p.385-390</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-75dcb7684b6bc285327d153d47e6f09438d43da3c8c361fa6d140c7c70ef67db3</citedby><cites>FETCH-LOGICAL-c316t-75dcb7684b6bc285327d153d47e6f09438d43da3c8c361fa6d140c7c70ef67db3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10876-018-1341-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2918291310?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,21389,21390,21391,23256,27924,27925,33530,33703,33744,34005,34314,41488,42557,43659,43787,43805,43953,44067,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Zhang, Jinfang</creatorcontrib><creatorcontrib>Feng, Jiaoyang</creatorcontrib><creatorcontrib>Tang, Guodong</creatorcontrib><creatorcontrib>Wu, Junjie</creatorcontrib><creatorcontrib>Luo, Fuming</creatorcontrib><creatorcontrib>Xu, Bin</creatorcontrib><creatorcontrib>Zhang, Chi</creatorcontrib><title>An Eicosanuclear Heterothiometallic Mo/S/Cu Cluster: Synthesis and Third-Order Nonlinear Optical Property</title><title>Journal of cluster science</title><addtitle>J Clust Sci</addtitle><description>A potassium-crownether host–guest cation-templated synthetic method was used to build a heterothiometallic Mo/S/Cu cluster {[(K ⊂ dibenzo-18-crown-6)(NMP)
2
]
2
[(K ⊂ dibenzo-18-crown-6)(NMP)]
2
[Mo
8
S
32
Cu
12
]·H
2
O} (
1
).
1
was structurally determined by X-ray single crystal and powder diffractions. The anionic Mo/S/Cu cluster [Mo
8
S
32
Cu
12
]
4−
exhibits a unique octameric eicosanuclear supra-cubane-like architecture. Potassium-crownether cations show “satellite-receiver”-shaped and hexagonal-pyramidal configurations. Moreover, the third-order nonlinear optical (NLO) property was studied through Z-scan method (532 nm, 4 ns pulses), which reveals that
1
possesses effective NLO absorptive and refractive properties.</description><subject>Absorptivity</subject><subject>Catalysis</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Clusters</subject><subject>Copper</subject><subject>Crystal structure</subject><subject>Cubane</subject><subject>Dependent sample</subject><subject>Inorganic Chemistry</subject><subject>Lasers</subject><subject>Molybdenum</subject><subject>Nanochemistry</subject><subject>Nonlinear optics</subject><subject>Optical properties</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Potassium</subject><subject>Radiation</subject><subject>Single crystals</subject><subject>Solvents</subject><issn>1040-7278</issn><issn>1572-8862</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kE1LwzAYx4soOKcfwFvAc1xe2iTzNsp0wnTC5jmkSeoyuqYm6WHf3o4Knjw8PA88_xf4Zdk9Ro8YIT6LGAnOIMICYppjSC6yCS44gUIwcjncKEeQEy6us5sYDwihuaB0krlFC5ZO-6jaXjdWBbCyyQaf9s4fbVJN4zR487PtrOxB2fRxeD6B7alNextdBKo1YLd3wcBNMDaAd982rj3nbLrktGrAR_CdDel0m13Vqon27ndPs8_n5a5cwfXm5bVcrKGmmCXIC6MrzkResUoTUVDCDS6oybllNZrnVJicGkW10JThWjGDc6S55sjWjJuKTrOHMbcL_ru3McmD70M7VEoyx2IYitGgwqNKBx9jsLXsgjuqcJIYyTNRORKVA1F5JirJ4CGjJw7a9suGv-T_TT_1WnlB</recordid><startdate>20180301</startdate><enddate>20180301</enddate><creator>Zhang, Jinfang</creator><creator>Feng, Jiaoyang</creator><creator>Tang, Guodong</creator><creator>Wu, Junjie</creator><creator>Luo, Fuming</creator><creator>Xu, Bin</creator><creator>Zhang, Chi</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20180301</creationdate><title>An Eicosanuclear Heterothiometallic Mo/S/Cu Cluster: Synthesis and Third-Order Nonlinear Optical Property</title><author>Zhang, Jinfang ; Feng, Jiaoyang ; Tang, Guodong ; Wu, Junjie ; Luo, Fuming ; Xu, Bin ; Zhang, Chi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-75dcb7684b6bc285327d153d47e6f09438d43da3c8c361fa6d140c7c70ef67db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Absorptivity</topic><topic>Catalysis</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Clusters</topic><topic>Copper</topic><topic>Crystal structure</topic><topic>Cubane</topic><topic>Dependent sample</topic><topic>Inorganic Chemistry</topic><topic>Lasers</topic><topic>Molybdenum</topic><topic>Nanochemistry</topic><topic>Nonlinear optics</topic><topic>Optical properties</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Potassium</topic><topic>Radiation</topic><topic>Single crystals</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Jinfang</creatorcontrib><creatorcontrib>Feng, Jiaoyang</creatorcontrib><creatorcontrib>Tang, Guodong</creatorcontrib><creatorcontrib>Wu, Junjie</creatorcontrib><creatorcontrib>Luo, Fuming</creatorcontrib><creatorcontrib>Xu, Bin</creatorcontrib><creatorcontrib>Zhang, Chi</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of cluster science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Jinfang</au><au>Feng, Jiaoyang</au><au>Tang, Guodong</au><au>Wu, Junjie</au><au>Luo, Fuming</au><au>Xu, Bin</au><au>Zhang, Chi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Eicosanuclear Heterothiometallic Mo/S/Cu Cluster: Synthesis and Third-Order Nonlinear Optical Property</atitle><jtitle>Journal of cluster science</jtitle><stitle>J Clust Sci</stitle><date>2018-03-01</date><risdate>2018</risdate><volume>29</volume><issue>2</issue><spage>385</spage><epage>390</epage><pages>385-390</pages><issn>1040-7278</issn><eissn>1572-8862</eissn><abstract>A potassium-crownether host–guest cation-templated synthetic method was used to build a heterothiometallic Mo/S/Cu cluster {[(K ⊂ dibenzo-18-crown-6)(NMP)
2
]
2
[(K ⊂ dibenzo-18-crown-6)(NMP)]
2
[Mo
8
S
32
Cu
12
]·H
2
O} (
1
).
1
was structurally determined by X-ray single crystal and powder diffractions. The anionic Mo/S/Cu cluster [Mo
8
S
32
Cu
12
]
4−
exhibits a unique octameric eicosanuclear supra-cubane-like architecture. Potassium-crownether cations show “satellite-receiver”-shaped and hexagonal-pyramidal configurations. Moreover, the third-order nonlinear optical (NLO) property was studied through Z-scan method (532 nm, 4 ns pulses), which reveals that
1
possesses effective NLO absorptive and refractive properties.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10876-018-1341-2</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1040-7278 |
| ispartof | Journal of cluster science, 2018-03, Vol.29 (2), p.385-390 |
| issn | 1040-7278 1572-8862 |
| language | eng |
| recordid | cdi_proquest_journals_2918291310 |
| source | ProQuest Central Essentials; ProQuest Central (Alumni Edition); ProQuest Central Student; ProQuest Central Korea; ProQuest Central UK/Ireland; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | Absorptivity Catalysis Cations Chemistry Chemistry and Materials Science Clusters Copper Crystal structure Cubane Dependent sample Inorganic Chemistry Lasers Molybdenum Nanochemistry Nonlinear optics Optical properties Original Paper Physical Chemistry Potassium Radiation Single crystals Solvents |
| title | An Eicosanuclear Heterothiometallic Mo/S/Cu Cluster: Synthesis and Third-Order Nonlinear Optical Property |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T01%3A18%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20Eicosanuclear%20Heterothiometallic%20Mo/S/Cu%20Cluster:%20Synthesis%20and%20Third-Order%20Nonlinear%20Optical%20Property&rft.jtitle=Journal%20of%20cluster%20science&rft.au=Zhang,%20Jinfang&rft.date=2018-03-01&rft.volume=29&rft.issue=2&rft.spage=385&rft.epage=390&rft.pages=385-390&rft.issn=1040-7278&rft.eissn=1572-8862&rft_id=info:doi/10.1007/s10876-018-1341-2&rft_dat=%3Cproquest_cross%3E2918291310%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2918291310&rft_id=info:pmid/&rfr_iscdi=true |